Energizer EVENH12BP4, EVENH35BP2 User Manual

Nickel Metal Hydride Batteries
PRODUCT NAME: Energizer Rechargeable Battery
Type No.:
Volts:
TRADE NAMES: ENERGIZER Nickel Metal Hydride Battery
Approximate Weight:
CHEMICAL SYSTEM: Nickel Metal Hydride
Designed for Recharge: Yes
Document Number: 12006-B
SECTION 1 - MANUFACTURER INFORMATION
Manufactured for: Energizer Battery Manufacturing, Inc.
Telephone Number for Information: 800-383-7323 (USA / CANADA)
1359 Columbia Rd. Westlake, OH 44145
SECTION 2 – HAZARDS IDENTIFICATION
SECTION 3 - INGREDIENTS
MATERIAL OR INGREDIENT
PEL (OSHA)
TLV (ACGIH)
%/wt.
fraction)
< 2
(CAS# 1307-96-6)
2.5-6.0
Page 1 of 5
January 2017
Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. Batteries are articles as defined under the GHS and exempt from GHS classification criteria (Section 1.3.2.1.1 of the GHS). The information and recommendations set forth herein are made in good faith, for information only, and are believed to be accurate as of the date of preparation. However, ENERGIZER BATTERY MANUFACTURING, INC. MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FRO M RE F E RE NC E ON IT .
Date Prepared: January 2017
GHS classification: N/A Signal Word: N/A Hazard Classification: N/A
Under normal conditions of use, the battery is hermetically sealed. Ingestion: Swallowing a battery can be harmful. Contents of an open battery can cause serious chemical burns of mouth, esophagus, and
gastrointestinal tract.
Inhalation: Contents of an open battery can cause respiratory irritation. Hypersensitivity to nickel can cause allergic pulmonary asthma. Skin Contact: Contents of an open battery can cause skin irritation and/or chemical burns. Nickel, nickel compounds, cobalt and cobalt compounds can cause skin sensitization and an aller gic contact dermatitis. Eye Contact: Contents of an open battery can cause severe irritation and chemical burns. Note: Nickel, nickel compounds, cobalt and cobalt compounds are listed as possible carcinogens by the International Agency for Research on
Cancer (IARC) or National Toxicology Program (NTP).
IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients c ontained within or their combustion products could be harmful.
Aluminum (CAS# 7429-90-5)
Cobalt as cobalt metal (CAS# 7440-48-4) as cobalt oxide
©2017 Energizer
15 mg/m3 TWA (total dust) 5 mg/m3 TWA (respirable
0.1 mg/m3 TWA (as Co) 0.02 mg/m3 TWA (as Co)
10 mg/m3 TWA
as cobalt hydroxide (CAS# 21041-93-0)
(CAS# 1310-65-2)
None established
None established
0-4 (CAS# 7439-96-5)
< 3 respirable fraction)
< 13
as nickel powder (CAS# 7440-02-0)
1.5 mg/m3 TWA
30-50
Potassium Hydroxide (CAS# 1310-58-3)
None established
< 7 (CAS# 1310-73-2)
0-4 fraction: zinc oxide)
< 3 Non-Hazardous Components
Water, Paper, Plastic and Other
None established
None established
Balance
SECTION 4 – FIRST AID MEASURES
SECTION 5 - FIRE FIGHTING MEASURES
If fire or explosion occurs when batteries are on cha rge, shut off power to charger.
form an explosive mixture. In this situation , smothering agents are recommended.
Lithium Hydroxide
Page 2 of 5
Nickel Metal Hydride Batteries
January 2017
Manganese
Mischmetal including: Lanthanum (CAS# 7439-91-0) Cerium (CAS# 7440-45-1) Neodymium (CAS# 7440-00-8) Praseodymium (CAS# 7440-10-0)
Nickel as nickel hydroxide (CAS# 12054-48-7) as nickel oxide (CAS# 1313-99-1)
Sodium Hydroxide
Zinc as zinc metal (CAS# 7440-66-6) as zinc oxide (CAS# 1314-13-2) as zinc hydroxide (CAS# 20427-58-1)
Steel (iron CAS# 65997-19-5)
5 mg/m3 Ceiling 0.2 mg/m3 TWA (as Mn)
15 mg/m3 TWA (particulates not otherwise regulated-total dust)
5 mg/m3 TWA (particulates not otherwise regulated-
1 mg/m3 TWA (as Ni)
2 mg/m3 TWA 2 mg/m3 Ceiling
15 mg/m3 TWA (total dust: zinc oxide)
5 mg/m3 TWA (respirable
None established
10 mg/m3 TWA (particulates not otherwise classified­inhalable)
3 mg/m3 TWA (particulates not otherwise classified-respirable)
(as inhalable Ni)
0.2 mg/m3 TWA (as inhalable Ni, insoluble compounds)
2 mg/m3 Ceiling
10 mg/m3 TWA (total dust: zinc oxide)
None established
14 - 18
Ingestion: Do not induce vomiting or give food or drink. Seek medical attention immediately. CALL NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up (202-625-3333) collect day or night.
Inhalation: Provide fresh air and seek medical attention. Skin Contact: Remove contaminated clothing and wash skin with soap and water. If a chemical burn occurs or if irritation persists, seek medical attention. Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the
chemical remains. Seek medical attention.
In case of fire where nickel metal hydride batteries are present, apply a smothering agent such as METL-X, sand, dry ground dolomite, or soda ash, or flood the area with water. A smothering agent will ex tinguish burning nickel metal hydride batteries. Water may not extinguish burning batteries but will cool the adjacent batteries and contr ol the spread of fire. Burning batteries will burn themselves out. Virtually all fires involving nickel metal hydride batteries can be controlled with water. When water is used, however, hydrogen gas may evolv e . In a confined space, hydrogen gas can
©2017 Energizer
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