Energizer ECR2032 User Manual

Coin/Button Lithium Manganese Dioxide Batteries

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January 2017

PRODUCT SAFETY DATA SHEET

PRODUCT NAME: Energizer Battery Type No.: Volts: 3.0
TRADE NAMES: Coin/Button Lithium Manganese Dioxide Batteries Approximate Weight: 0.6 – 7.0 g
CHEMICAL SYSTEM: Lithium Manganese Dioxide

Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. Batteries are
articles as defined under the GHS and exempt from GHS classification criteria (Section 1.3.2.1.1 of the GHS). The information and recommendations set
forth herein are made in good faith, for information only, and are believed to be accurate as of the date of preparation. However, ENERGIZER BATTERY
MANUFACTURING, INC. MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL
LIABILITY FROM REFERENCE ON IT.

SECTION 1- MANUFACTURER INFORMATION

Manufactured for
Energizer Battery Manufacturing, Inc. Telephone Number for Information:
25225 Detroit Rd.
Westlake, OH 44145
Date Prepared: January 2017

SECTION 2 – HAZARDS IDENTIFICATION

GHS classification: N/A
Signal Word: N/A
Hazard Classification: N/A

Under normal conditions of use, the battery is h ermetically sealed.
Ingestion: Swallowing may lead to serious injury or death in as little as 2 hours due to chemical burns and potential perforation of the

esophagus. Immediately see doctor; have doctor phone [phone]. Do not induce vomiting or give food or drink.

Inhalation: Contents of an open battery can cause respiratory irritation.
Skin Contact: Contents of an open battery can cause skin irritation.
Eye Contact: Contents of an open battery can cause severe irritation.

SECTION 3 - INGREDIENTS

IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be

harmful.

MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.

Carbon Black
(CAS# 1333-86-4)

1,2-Dimethoxyethane
(CAS# 110-71-4)

1,3-Dioxolane
(CAS# 646-06-0)

Graphite
(CAS# 7782-42-5)

Lithium or Lithium Alloy
(CAS# 7439-93-2)

800-383-7323 (USA / CANADA)

3.5 mg/m3 TWA 3.5 mg/m3 TWA 0-1

None established None established 0-6

None established None established 0-8

15 mg/m3 TWA (total dust)

3

5 mg/m
None established None established 1-6

TWA (respirable fraction)

Designed for Recharge: No Document Number: 12005-A

3

2 mg/m

TWA (respirable fraction) 0-3

©2017 Energizer

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Coin/Button Lithium Manganese Dioxide Batteries

Lithium Perchlorate
(CAS# 7791-03-9)

Lithium Trifluoromethanesulfonate
(CAS# 33454-82-9)

Lithium Trifluoromethanesulfonimide
(CAS# 90076-65-6)

Manganese Dioxide
(CAS# 1313-13-9)

Propylene Carbonate
(CAS# 108-32-7)

Non-Hazardous Components:
Steel

(iron CAS# 65997-19-5)
Plastic and Other

SECTION 4 – FIRST AID MEASURES

Ingestion: Swallowing may lead to serious injury or death in as little as 2 hours due to chemical burns and potential perforation of the
esophagus. Immediately see doctor; have doctor phone [phone]. Do not induce vomiting or give food or drink.

Inhalation: Provide fresh air and seek medical attention.
Skin Contact: Remove contaminated clothing and wash skin with soap and water.
Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the

chemical remains. Seek medical attention.

Note: Carbon black is listed as a possible carcinogen by International Agency for Research on Cancer (IARC).

SECTION 5- FIRE FIGHTING MEASURES

In case of fire where lithium batteries are present, flood area with water or smother with a Class D fire extinguishant appropriate for lithium metal, such
as Lith-X. Water may not extinguish burning batteries but will cool the adjacent batteries and con trol the spread of fire. Burning batteries will burn
themselves out. Virtually all fires involving lithium batteries can be controlled by flooding with water. However, the contents of the battery will react with
water and form hydrogen gas. In a confined space, hydrogen gas can form an explosive mixture. In this situation, smothering agents are
recommended. A smothering agent will extinguis h burning lithium batteries.

Emergency Responders should wear self-contained breathing apparatus. Burning lithium manganese dioxide batteries produce toxic and corrosive
lithium hydroxide fumes.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

To cleanup leaking batteries:

Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries.
Respiratory Protection: Avoid exposure to electrolyte fumes from open or leaking batteries.
Eye Protection: Wear safety glasses with side shields if hand li ng an open or leaking battery.
Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery.
Battery materials should be collected in a leak-pro of container.

SECTION 7 - HANDLING AND STORAGE

Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life. In locations that ha ndle large quantities of

lithium batteries, such as warehouses, lithium batteries should be isolated from unnecessary combustibles.
Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Energizer Battery

Manufacturing, Inc. representative for precautionary suggestions. Do not obstruct safety release vents on batteries. Encapsulation of batteries
will not allow cell venting and can cause high pressure rupture.

None established None established 0-3

None established None established 0-3

None established None established 0-3

5 mg/m3 Ceiling (as Mn) 0.2 mg/m3 TWA (as Mn) 12-42

None established None established 0-8

None established

None established

None established

None established

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January 2017

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Balance

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Coin/Button Lithium Manganese Dioxide Batteries

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January 2017

Handling: Accidental short circuit for a few seconds w il l no t seriously affect the battery. Prolonged short circuit will cause the battery to lose energy,
generate significant heat and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal
jewelry, metal covered tables or metal belts used for assembly of batteries into devices. Damaging a lithium battery may result in an internal short
circuit.

The contents of an open battery, including a vented battery, when exposed to wa ter, may result in a fire and/or explosion.
Crushed or damaged batteries may result in a fire.

If soldering or welding to the battery is required , consult your Energizer representative for proper precautions to prevent seal
damage or short circuit.

Charging: This battery is manufactured in a charged state. It is not designed for recharging. Recharging can cause battery leakage or, in
some cases, high pressure rupture. Inadvertent charging can occur if a battery is installed backwards.

Labeling: If the Energizer label or package warnings are not visible, it is important to provide a package and/or device label stating:

WARNING: Battery can explode or leak and cause burns if installed backwards, disassembled, charged, or exposed to water, fire or
high temperature.

Where accidental ingestion of small batterie s is possible, the label should include:

(1) KEEP OUT OF REACH OF CHILDREN. Swallowing may lead to serious injur y or d eath in as little as 2 hours due to chemical
burns and potential perforation of the esophagus. Immediately see doctor; have doctor phone [phone]. Keep in
original package until ready to use. Dispose of used batteries immediately.

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

Ventilation Requirements: Not necessary under normal conditions.
Respiratory Protection: Not necessary under normal conditions.
Eye Protection: Not necessary under normal conditions.
Gloves: Not necessary under normal conditions.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

Appearance (physical state, color, etc.): Solid object

Upper Explosive Limits: Not applicable for an Article

Lower Explosive Limits Not applicable for an Article

Odor No odor

Vapor Pressure (mm Hg @ 25°C) Not applicable for an Article

Odor Threshold No odor

Vapor Density (Air = 1) Not applicable for an Article

pH Not applicable for an Article

©2017 Energizer

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Coin/Button Lithium Manganese Dioxide Batteries

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January 2017

Density (g/cm3) 2.0-3.0

Melting point/Freezing Point Not applicable for an Article

Solubility in Water (% by weight) Not applicable for an Article

Boiling Point @ 760 mm Hg (°C) Not applicable for an Article

Flash Point Not applicable for an Article

Evaporation Rate (Butyl Acetate = 1) Not applicable for an Article

Flammability Not applicable for an Article

Partition Coefficient Not applicable for an Article

Auto-ignition Temperature Not applicable for an Article

Decomposition Temperature Not applicable for an Article

Viscosity Not applicable for an Article

SECTION 10 – STABILITY AND REACTIVITY

Lithium manganese dioxide batteries contain no su lfid es or cyanides and they do not meet any other reactivity criteria including “reacts
violently with water” and therefore do not meet any of the criteria established in 40 CFR 261.2 for reactivity.

SECTION 11 – TOXICOLOGICAL INFORMATION

Under normal conditions of use, lithium manganese dioxide batterie s are non -toxic.

SECTION 12 – ECOLOGICAL INFORMATION

Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles.

SECTION 13 – DISPOSAL CONSIDERATIONS

LiMnO2 batteries are not hazardous waste per the United States Resource Conservation and Recovery Act(RCRA) - 40 CFR Part 261 Subpart C.
Dispose of in accordance with all applicable federal, state and local regulations.

SECTION 14 – TRANSPORT INFORMATION

In general, all batteries in all forms of transportat ion (ground, air, or ocean) must be packaged in a safe and responsible manner. Regulatory concerns
from all agencies for safe packaging require that batteries be packaged in a manner that prevents short circuits and be contained in “strong outer
packaging” that prevents spillage of contents. All original packaging for Energizer lithium batteries are compliant with these regulatory concerns.

Energizer lithium coin batteries are exempt from the classification as dangerous goods as they meet the requirements of the special provisions listed
below. (Essentially, they are properly packaged and labeled, contain less than 1 gram of lithium and pass the tests defined in UN model regulation
section 38.3).

Regulatory Body Special Provisions

ADR 188, 230, 310, 636, 656

IMDG 188, 230, 310, 957

UN UN 3090, UN 3091

US DOT 29, A54, A100, A101

IATA 58th Edition, ICAO Packaging Instructions 968 - 970

©2017 Energizer

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Coin/Button Lithium Manganese Dioxide Batteries

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January 2017

Energizer is registered with CHEMTREC. In the event of an incident during transport call 1-800-424-9300 (North America) or 1-703-527-3887
(International).

A global lithium label chart is provided b elow to summarize the current global labeling requirements.

Label Summary Chart

Shipping
Mode

Li content

Net quantity wt.
of batteries per
package

Battery Type

0.3g to <1g/cell

0.3g to <2g/

<2.5 kg

L91, L92, L522 YES YES YES

battery

AIR

<0.3g/cell <2.5kg

<0.3g/cell >2.5kg

All Li Coin and
2L76

All Li Coin and
2L76

NO YES YES

YES YES YES

Land/
Sea only

All All All NO YES YES

SECTION 15 - REGULATORY INFORMATION

Outside of the transportation requirements no ted in Section 14, lithium manganese dioxide batteries ma rketed by Energizer Battery Manufacturing, Inc.
are not regulated.

SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To­Know Act.

SECTION 16 - OTHER INFORMATION

None.

©2017 Energizer

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