Endust END11384 User Manual

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Safety Data Sheet

according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and

GHS

Revision: 05.2015

Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier: 11384

Trade name: Endust® For Electronics 10Oz

Article number: 11384 (10oz)

CAS Number: 75-37-6

EC number: 200-866-1

1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available.

Application of the substance / the mixture Surface cleaning

1.3 Details of the supplier of the Safety Data Sheet

Manufacturer/Supplier:

Norazza, Inc. 3938 Broadway St Buffalo, NY 14227 Phone: (716) 706-1160 Website: www.norazza.com

1.4 Emergency telephone number: ChemTel Inc. (800)255-3924, +01 (813)248-0585

Hazards identification

2.1 Classification of the substance or mixture Press. Gas H280 Contains gas under pressure; may explode if heated.

Classification according to Regulation (EC) No 1272/2008

flame

Flam. Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.

Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable.

F+; Extremely flammable

R12: Extremely flammable.

Information concerning particular hazards for human and environment: Warning! Pressurized container. Asphyxiant gas.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation.

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Hazard pictograms

(Contd. of page 1)

GHS02

Signal word Danger

Hazard statements H280 Contains gas under pressure; may explode if heated. H222-H229 Extremely flammable aerosol. Pressurized container: May burst if heated.

Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking. P251 Do not pierce or burn, even after use. P211 Do not spray on an open flame or other ignition source. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

Hazard description:

WHMIS-symbols: B5 - Flammable aerosol

NFPA ratings (scale 0 - 4)

0 3

HMIS-ratings (scale 0 - 4)

HEALTH FIRE

REACTIVITY 3

HMIS Long Term Health Hazard Substances

Health = 0 Fire = 4

Reactivity = 3

Health = 0

Fire = 4

Reactivity = 3

Substance is not listed.

2.3 Other hazards

Results of PBT and vPvB assessment

PBT: Not applicable.

vPvB: Not applicable.

Composition/information on ingredients

3.1 Substances

CAS No. Description 75-37-6 1,1-difluoroethane

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Trade name: Endust® For Electronics 10Oz

Identification number(s)

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EC number: 200-866-1

First aid measures

4.1 Description of first aid measures

General information: Take affected persons out into the fresh air.

After inhalation: Supply fresh air; consult doctor in case of complaints. Provide oxygen treatment if affected person has difficulty breathing. In case of irregular breathing or respiratory arrest provide artificial respiration.

After skin contact: In cases of frost bites, rinse with plenty of water. Do not remove clothing. If skin irritation continues, consult a doctor. Seek immediate medical help for blistering or open wounds.

After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

After swallowing: Unlikely route of exposure. Do not induce vomiting; call for medical help immediately.

4.2 Most important symptoms and effects, both acute and delayed Headache Coughing Dizziness Disorientation

Hazards Danger of impaired breathing.

4.3 Indication of any immediate medical attent ion and special treatment needed Treat frost-bitten areas appropriately. If necessary oxygen respiration treatment.

Firefighting measures

5.1 Extinguishing media

Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

For safety reasons unsuitable extinguishing agents: None.

5.2 Special hazards arising from the substance or mixture Danger of receptacles bursting because of high vapor pressure when heated. During heating or in case of fire poi sonous gases are produced.

5.3 Advice for firefighters

Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit.

Additional information Cool endangered receptacles with water fog or haze.

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Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Keep away from ignition sources. Protect from heat.

6.2 Environmental precautions: No special measures required.

6.3 Methods and material for containment and cleaning up: Allow to evaporate.

6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

Handling and storage

7.1 Precautions for safe handling Avoid splashes or spray in enclosed areas. Use only in well ventilated areas. Keep away from heat and direct sunlight.

Information about fire - and explosion protection: Do not spray onto a naked flame or any incandescent material. Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Pressurized container: protect from sunlight an d do not expose to temperatures exceeding 50 °C, i.e. electric lights. Do not pierce or burn, even after use. Emergency cooling must be available in case of nearby fire. Prevent impact and friction. Flammable gas-air mixtures may form in empty receptacles.

7.2 Conditions for safe storage, including any incompatibilities

Storage:

Requirements to be met by storerooms and receptacles: Store in a cool location. Observe official regulations on storing packaging with pressurized containers. Avoid storage near extreme heat, ignition sources or open flame.

Information about storage in one common storage facility: Store away from oxidizing agents.

Further information about storage conditions: Protect from heat and direct sunlight. Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting.

7.3 Specific end use(s) No further relevant information available.

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Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7.

8.1 Control parameters

Ingredients with limit values that require monitoring at the workplace: Not required.

DNELs No further relevant information available.

PNECs No further relevant information available.

Additional information: The lists valid during the making were used as basis.

8.2 Exposure controls

Personal protective equipment:

General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols.

Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation. For spills, respiratory protection may be advisable.

Protection of hands: Gloves not required under normal conditions of use. Wear protective gloves to handle contents of damaged or leaking units. Gloves should provide protection from freezing temperatures.

Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eye protection:

Body protection: Not required under normal conditions of use.

Safety glasses

Protection may be required for spills.

Limitation and super vision of exposure into the environment No further relevant information available.

Risk management measures See Section 7 for additional information. No further relevant information available.

Physical and chemical properties

9.1 Information on basic physical and chemical properties

General Information

Appearance:

Form: Aerosol Color: Colorless

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Odor: Ether-like

Odor threshold: Not determined.

pH-value: Not determined.

Change in condition

Melting point/Melting range: -153 °F/ -117 °C (Literature) Boiling point/Boiling range: -13 °F / -25 °C

Flash point: -58 °F / -50 °C

Flammability (solid, gaseous): Not applicable.

Ignition temperature: Not determined.

Decomposition temperature: Not determined.

Self-igniting: Not determined.

Danger of explosion: Product is not explosive. However, formation of explosive air/

vapor mixtures are possible.

Explosion limits:

Lower: 3,9 Vol % Upper: 16,9 Vol %

Vapour pressure at 20 °C: 530 kPa (62.5 psig)

Density at 20 °C: 0,909 g/cm³

Relative density Not determined.

Vapour density at 25 °C 2,4 (AIR = 1)

Evaporation rate at 20 °C >1 (Butyl acetate = 1)

Solubility in / Miscibility with

water at 20 °C: <5,0 g/l (Negligible)

Partition coefficient (n-octanol/water): Not determined.

Viscosity:

Dynamic: Not determined. Kinematic: Not determined.

9.2 Other information No further relevant information available.

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10.1 Reactivity

10.2 Chemical stability

Thermal decomposition / conditions to be avoided:

Stability and reactivity

No decomposition if used and stored according to specifications.

10.3 Possibility of hazardous reactions Flammable. Danger of receptacles bursting because of high vapor pressure when heated. Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomized.

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according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and

GHS

Trade name: Endust® For Electronics 10Oz

LD/LC50 values relevant for classification:

75-37-6 1,1-difluoroethane

Inhalative

LC50/4h

977 mg/l (mouse)

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Can react violently with oxygen rich (oxidizing) material. Danger of Explosion. Used empty containers may contain product gases which form explosive mixtures with air. Toxic fumes may be released if heated above the decomposition point.

10.4 Conditions to avoid Keep ignition sources away - Do not smoke. Store away from oxidizing agents.

10.5 Incompatible materials: No further relevant information available.

10.6 Hazardous decomposition products: Danger of toxic fluorine based pyrolysis products.

Toxicological information

11.1 Information on toxicological effects

Acute toxicity:

Primary irritant effect:

on the skin: No irritant effect.

on the eye: No irritating effect.

Sensitization: No sensitizing effects known.

Additional toxicological information: Asphyxiant gas.

Ecological information

12.1 Toxicity

Aquatic toxicity: No further relevant information available.

12.2 Persistence and degradability No further relevant information available.

12.3 Bioaccumulative potential Does not accumulate in organisms.

12.4 Mobility in soil No further relevant information available.

Additional ecological information:

General notes: Generally not hazardous for water

12.5 Results of PBT and vPvB assessment

PBT: Not applicable.

vPvB: Not applicable.

12.6 Other adverse effects No further relevant information available.

Disposal considerations

13.1 Waste treatment methods

Recommendation Can be burned with household garbage after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations.

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14.1 UN-Number

DOT, ADR, IMDG, IATA

UN1950

14.2 UN proper shipping name

DOT

Aerosols, flammable

ADR

1950 AEROSOLS. FLAMMABLE

IMDG, IATA

AEROSOLS, FLAMMABLE

14.3 Transport hazard class(es)

DOT

Class

2.1

Label

2.1

ADR

Class

2.1 5F

Label

2.1

IMDG, IATA

Class

2.1

Label

2.1

14.4 Packing group

DOT, ADR, IMDG, IATA

Not Regulated

14.5 Environmental hazards:

Marine pollutant:

14.6 Special precautions for user

Not applicable.

Danger code (Kemler):

EMS Number:

F-D,S-U

Uncleansed packaging:

Recommendation: Disposal must be made according to official regulations.

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Transport information

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according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and

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14.7 Transport in bulk according to Annex II of

MARPOL73/78 and the IBC Code

Not applicable.

Transport/Additional information:

ADR

Limited quantities (LQ)

UN "Model Regulation":

UN1950, AEROSOLS, FLAMMABLE, 2.1

Section 355 (extremely hazardous substances):

Substance is not listed.

Section 313 (Specific toxic chemical listings):

Substance is not listed.

TSCA (Toxic Substances Control Act):

Substance is listed.

Chemicals known to cause cancer:

Substance is not listed.

Chemicals known to cause reproductive toxicity for females:

Substance is not listed.

Chemicals known to cause reproductive toxicity for males:

Substance is not listed.

Chemicals known to cause developmental toxicity:

Substance is not listed.

EPA (Environmental Protection Agency)

Substance is not listed.

IARC (International Agency for Research on Cancer)

Substance is not listed.

TLV (Threshold Limit Value established by ACGIH)

Substance is not listed.

NIOSH-Ca (National Institute for Occupational Safety and Health)

Substance is not listed.

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Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

United States (USA)

SARA

Proposition 65 (California):

Carcinogenic Categories

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Canadian Domestic Substances List (DSL)

Substance is listed.

Canadian Ingredient Disclosure list (limit 0.1%)

Substance is not listed.

Canadian Ingredient Disclosure list (limit 1%)

Substance is not listed.

OSHA-Ca (Occupational Safety & Health Administration) Substance is not listed.

Canada

15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

Abbreviations and acronyms:

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent

Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com

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