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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
1
Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier: 11407
·
Trade name: Endust® For Electronics 10Oz
·
Article number: 11407 (2 x 10oz)
·
CAS Number:
75-37-6
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EC number:
200-866-1
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1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture Surface cleaning
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1.3 Details of the supplier of the Safety Data Sheet
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Manufacturer/Supplier:
Norazza, Inc.
3938 Broadway St
Buffalo, NY 14227
Phone: (716) 706-1160
Website: www.norazza.com
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +01 (813)248-0585
2
Hazards identification
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2.1 Classification of the substance or mixture
Press. Gas H280 Contains gas under pressure; may explode if heated.
·
Classification according to Regulation (EC) No 1272/2008
flame
Flam. Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Not applicable.
F+; Extremely flammable
R12: Extremely flammable.
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Information concerning particular hazards for human and environment:
Warning! Pressurized container.
Asphyxiant gas.
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2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
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(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
Trade name: Endust® For Electronics 10Oz
·
Hazard pictograms
(Contd. of page 1)
GHS02
·
Signal word Danger
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Hazard statements
H280 Contains gas under pressure; may explode if heated.
H222-H229 Extremely flammable aerosol. Pressurized container: May burst if heated.
·
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P251 Do not pierce or burn, even after use.
P211 Do not spray on an open flame or other ignition source.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
·
Hazard description:
·
WHMIS-symbols:
B5 - Flammable aerosol
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NFPA ratings (scale 0 - 4)
4
0 3
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY 3
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HMIS Long Term Health Hazard Substances
Health = 0
Fire = 4
Reactivity = 3
0
Health = 0
4
Fire = 4
Reactivity = 3
Substance is not listed.
·
2.3 Other hazards
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Results of PBT and vPvB assessment
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PBT: Not applicable.
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vPvB: Not applicable.
3
Composition/information on ingredients
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3.1 Substances
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CAS No. Description
75-37-6 1,1-difluoroethane
38.0
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
Trade name: Endust® For Electronics 10Oz
·
Identification number(s)
·
38.0
EC number: 200-866-1
4
First aid measures
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4.1 Description of first aid measures
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General information: Take affected persons out into the fresh air.
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After inhalation:
Supply fresh air; consult doctor in case of complaints.
Provide oxygen treatment if affected person has difficulty breathing.
In case of irregular breathing or respiratory arrest provide artificial respiration.
·
After skin contact:
In cases of frost bites, rinse with plenty of water. Do not remove clothing.
If skin irritation continues, consult a doctor.
Seek immediate medical help for blistering or open wounds.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
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After swallowing:
Unlikely route of exposure.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Headache
Coughing
Dizziness
Disorientation
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Hazards Danger of impaired breathing.
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4.3 Indication of any immediate medical attent ion and special treatment needed
Treat frost-bitten areas appropriately.
If necessary oxygen respiration treatment.
5
Firefighting measures
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5.1 Extinguishing media
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Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
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For safety reasons unsuitable extinguishing agents: None.
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5.2 Special hazards arising from the substance or mixture
Danger of receptacles bursting because of high vapor pressure when heated.
During heating or in case of fire poi sonous gases are produced.
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5.3 Advice for firefighters
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Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
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Additional information
Cool endangered receptacles with water fog or haze.
(Contd. of page 2)
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
Trade name: Endust® For Electronics 10Oz
38.0
Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
6
Accidental release measures
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6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources.
Protect from heat.
·
6.2 Environmental precautions: No special measures required.
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6.3 Methods and material for containment and cleaning up: Allow to evaporate.
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6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7
Handling and storage
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7.1 Precautions for safe handling
Avoid splashes or spray in enclosed areas.
Use only in well ventilated areas.
Keep away from heat and direct sunlight.
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Information about fire - and explosion protection:
Do not spray onto a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Pressurized container: protect from sunlight an d do not expose to temperatures exceeding 50 °C, i.e.
electric lights. Do not pierce or burn, even after use.
Emergency cooling must be available in case of nearby fire.
Prevent impact and friction.
Flammable gas-air mixtures may form in empty receptacles.
·
7.2 Conditions for safe storage, including any incompatibilities
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Storage:
·
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packaging with pressurized containers.
Avoid storage near extreme heat, ignition sources or open flame.
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Information about storage in one common storage facility: Store away from oxidizing agents.
·
Further information about storage conditions:
Protect from heat and direct sunlight.
Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting.
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7.3 Specific end use(s) No further relevant information available.
(Contd. of page 3)
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
Trade name: Endust® For Electronics 10Oz
(Contd. of page 4)
8
Exposure controls/personal protection
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Additional information about design of technical facilities: No further data; see item 7.
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8.1 Control parameters
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Ingredients with limit values that require monitoring at the workplace: Not required.
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DNELs No further relevant information available.
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PNECs No further relevant information available.
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Additional information: The lists valid during the making were used as basis.
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8.2 Exposure controls
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Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
·
Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
For spills, respiratory protection may be advisable.
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Protection of hands:
Gloves not required under normal conditions of use.
Wear protective gloves to handle contents of damaged or leaking units.
Gloves should provide protection from freezing temperatures.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
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Eye protection:
·
Body protection:
Not required under normal conditions of use.
Safety glasses
Protection may be required for spills.
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Limitation and super vision of exposure into the environment
No further relevant information available.
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Risk management measures
See Section 7 for additional information.
No further relevant information available.
9
Physical and chemical properties
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9.1 Information on basic physical and chemical properties
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General Information
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Appearance:
Form: Aerosol
Color: Colorless
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(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
Trade name: Endust® For Electronics 10Oz
·
Odor: Ether-like
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Odor threshold: Not determined.
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pH-value: Not determined.
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Change in condition
Melting point/Melting range: -153 °F/ -117 °C (Literature)
Boiling point/Boiling range: -13 °F / -25 °C
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Flash point: -58 °F / -50 °C
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Flammability (solid, gaseous): Not applicable.
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Ignition temperature: Not determined.
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Decomposition temperature: Not determined.
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Self-igniting: Not determined.
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Danger of explosion: Product is not explosive. However, formation of explosive air/
vapor mixtures are possible.
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Explosion limits:
Lower: 3,9 Vol %
Upper: 16,9 Vol %
·
Vapor pressure at 20 °C: 530 kPa (62.5 psig)
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Density at 20 °C: 0,909 g/cm³
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Relative density Not determined.
·
Vapor density at 25 °C 2,4 (AIR = 1)
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Evaporation rate at 20 °C >1 (Butyl acetate = 1)
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Solubility in / Miscibility with
water at 20 °C: <5,0 g/l (Negligible)
·
Partition coefficient (n-octanol/water): Not determined.
·
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
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9.2 Other information No further relevant information available.
(Contd. of page 5)
10
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10.1 Reactivity
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10.2 Chemical stability
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Thermal decomposition / conditions to be avoided:
Stability and reactivity
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Flammable.
Danger of receptacles bursting because of high vapor pressure when heated.
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomized.
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(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
Trade name: Endust® For Electronics 10Oz
·
LD/LC50 values relevant for classification:
75-37-6 1,1-difluoroethane
Inhalative
LC50/4h
977 mg/l (mouse)
(Contd. of page 6)
Can react violently with oxygen rich (oxidizing) material. Danger of Explosion.
Used empty containers may contain product gases which form explosive mixtures with air.
Toxic fumes may be released if heated above the decomposition point.
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10.4 Conditions to avoid
Keep ignition sources away - Do not smoke.
Store away from oxidizing agents.
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10.5 Incompatible materials: No further relevant information available.
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10.6 Hazardous decomposition products: Danger of toxic fluorine based pyrolysis products.
11
Toxicological information
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11.1 Information on toxicological effects
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Acute toxicity:
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Primary irritant effect:
·
on the skin: No irritant effect.
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on the eye: No irritating effect.
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Sensitization: No sensitizing effects known.
·
Additional toxicological information: Asphyxiant gas.
12
Ecological information
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12.1 Toxicity
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Aquatic toxicity: No further relevant information available.
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12.2 Persistence and degradability No further relevant information available.
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12.3 Bioaccumulative potential Does not accumulate in organisms.
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12.4 Mobility in soil No further relevant information available.
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Additional ecological information:
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General notes: Generally not hazardous for water
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12.5 Results of PBT and vPvB assessment
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PBT: Not applicable.
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vPvB: Not applicable.
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12.6 Other adverse effects No further relevant information available.
13
Disposal considerations
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13.1 Waste treatment methods
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Recommendation
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
38.0
(Contd. on page 8)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
Trade name: Endust® For Electronics 10Oz
·
14.1 UN-Number
·
DOT, ADR, IMDG, IATA
UN1950
·
14.2 UN proper shipping name
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DOT
Aerosols, flammable
·
ADR
1950 AEROSOLS. FLAMMABLE
·
IMDG, IATA
AEROSOLS, FLAMMABLE
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14.3 Transport hazard class(es)
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DOT
·
Class
2.1
·
Label
2.1
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ADR
·
Class
2.1 5F
·
Label
2.1
·
IMDG, IATA
·
Class
2.1
·
Label
2.1
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14.4 Packing group
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DOT, ADR, IMDG, IATA
Not Regulated
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14.5 Environmental hazards:
·
Marine pollutant:
No
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14.6 Special precautions for user
Not applicable.
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Danger code (Kemler):
20
·
EMS Number:
F-D,S-U
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Uncleansed packaging:
·
Recommendation: Disposal must be made according to official regulations.
(Contd. of page 7)
14
Transport information
38.0
(Contd. on page 9)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
Trade name: Endust® For Electronics 10Oz
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
Not applicable.
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Transport/Additional information:
·
ADR
·
Limited quantities (LQ)
1L
·
UN "Model Regulation":
UN1950, AEROSOLS, FLAMMABLE, 2.1
·
Section 355 (extremely hazardous substances):
Substance is not listed.
·
Section 313 (Specific toxic chemical listings):
Substance is not listed.
·
TSCA (Toxic Substances Control Act):
Substance is listed.
·
Chemicals known to cause cancer:
Substance is not listed.
·
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
·
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
·
Chemicals known to cause developmental toxicity:
Substance is not listed.
·
EPA (Environmental Protection Agency)
Substance is not listed.
·
IARC (International Agency for Research on Cancer)
Substance is not listed.
·
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
(Contd. of page 8)
15
Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Proposition 65 (California):
·
Carcinogenic Categories
38.0
(Contd. on page 10)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Revision: 05.2015
Trade name: Endust® For Electronics 7Oz, 8Oz & 10Oz
·
Canadian Domestic Substances List (DSL)
Substance is listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
Substance is not listed.
·
Canadian Ingredient Disclosure list (limit 1%)
Substance is not listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.
·
Canada
·
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16
Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
38.0
(Contd. of page 9)
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