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SAFETY DATA SHEET
Revision Date 03-Sep-2014 Revision Number 2Issuing Date 24-Apr-2013
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The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name Krazy Glue Advanced Gel/Liquid Series
Other means of identification
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Supplier Name
Supplier Address
Supplier Phone Number
Supplier Email
Emergency telephone number
Company Emergency Phone
Number
None
Glue
No information available
Elmer's Products, Inc.
1000 Kingsmill Parkway
Columbus
Ohio
43229
US
Phone:888-516-2502
Fax:614-985-2648
Contact Phone614-985-2704
brumschlag@elmers.com
888-516-2502
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
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Skin sensitization Category 1
Carcinogenicity Category 2
Specific target organ toxicity (single exposure) Category 3
Flammable liquids
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Warning
Hazard Statements
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
Suspected of causing cancer
May cause respiratory irritation. May cause drowsiness or dizziness
Combustible liquid
Category 4
.
Appearance Clear Physical state Liquid Odor Stinging
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep cool
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Skin
IF ON SKIN: Wash with plenty of soap and water
Take off contaminated clothing and wash before reuse
If skin irritation or rash occurs: Get medical advice/attention
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
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Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
11.012 % of the mixture consists of ingredient(s) of unknown toxicity
Other information
Very toxic to aquatic life with long lasting effects
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION
Interactions with Other Chemicals
No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
.
Chemical Name CAS No
Ethyl cyanoacrylate 7085-85-0 60 - 100 *
Hydroquinone 123-31-9 0.1 - 1 *
*The exact percentage (concentration) of composition has been withheld as a trade secret
Weight-% Trade Secret
4. FIRST AID MEASURES
First aid measures
General Advice
Eye contact
Skin contact
Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the
eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Remove contact lenses,
if present and easy to do. Continue rinsing. Do not rub affected area.
In the case of skin irritation or allergic reactions see a physician. May cause an allergic skin
reaction. Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. Do not remove clothing if adhering to skin. If skin has
bonded to clothing or other skin NEVER pull the area apart. Consult a physician if
necessary.
Inhalation
Remove to fresh air. If symptoms persist, call a physician. Get medical attention
immediately if symptoms occur.
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Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Never give
anything by mouth to an unconscious person. Call a physician.
Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section 8).
Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, take precautions to protect themselves and prevent spread of contamination.
Burning sensation. Itching. Rashes. Hives.
Treat symptomatically. May cause sensitization in susceptible persons.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Dry chemical. Carbon
dioxide (CO2). Water spray. Alcohol resistant foam.
Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical
Product is or contains a sensitizer. May cause sensitization by skin contact. Keep product and empty container away from heat and
sources of ignition. In the event of fire, cool tanks with water spray.
Uniform Fire Code
Hazardous Combustion Products
Carbon oxides.
Physical/Chemical Reaction
Properties
Explosion Data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
Combustible Liquid: III-A
Irritant: Liquid
Polymerization can occur.
No.
Yes.
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6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required. Evacuate personnel to safe areas. See section 8 for
more information. Take precautionary measures against static discharges. Do not touch or
walk through spilled material.
Other Information
Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental precautions
Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so.
Methods and material for containment and cleaning up
Methods for containment
Prevent further leakage or spillage if safe to do so. Do not touch or walk through spilled
material. Dike far ahead of liquid spill for later disposal.
Methods for cleaning up
Take precautionary measures against static discharges. Dam up. Soak up with inert
absorbent material. Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Do not breathe dust/fume/gas/mist/vapors/spray.
Conditions for safe storage, including any incompatibilities
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep in properly labeled containers. Store in accordance with the particular
national regulations. Store in accordance with local regulations.
Incompatible Products
Strong acids. Strong oxidizing agents. Strong bases.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Ethyl cyanoacrylate
7085-85-0
Hydroquinone
123-31-9
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health
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TWA: 0.2 ppm -
TWA: 1 mg/m
3
TWA: 2 mg/m
(vacated) TWA: 2 mg/m
3
3
IDLH: 50 mg/m
Ceiling: 2 mg/m3 15 min
3
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Other Exposure Guidelines
Appropriate engineering controls
Engineering Measures
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
Hygiene Measures
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992) See section 15 for national exposure control parameters
Showers
Eyewash stations
Ventilation systems
None required for consumer use. If splashes are likely to occur:. Tight sealing safety
goggles.
Wear protective gloves and protective clothing. Long sleeved clothing. Impervious gloves.
No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Handle in accordance with good industrial hygiene and safety practice. Take off
contaminated clothing and wash before reuse. Avoid contact with skin, eyes or clothing.
Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this
product. Wash hands before breaks and immediately after handling the product.
Contaminated work clothing should not be allowed out of the workplace. Regular cleaning
of equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical state
Appearance
Color
Property
pH
Melting / freezing point
Boiling point / boiling range
Flash Point
Evaporation Rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit
Lower flammability limit
Vapor pressure
Vapor density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Liquid
Clear
No information available
Values
UNKNOWN
No data available
62 °C / 144 °F
83 C / 181 F
No data available None known
No data available
No data available
No data available
No data available
No data available
1.09
Negligible
No data available
No data available
No data available
No data available
No data available
No data available None known
No data available
No data available
Odor
Odor Threshold
Remarks Method
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
Stinging
No information available
Other Information
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Softening Point
VOC Content (%)
Particle Size
Particle Size Distribution
No data available
No data available
No data available
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Strong acids. Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Eye contact
Skin contact
Ingestion
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Hydroquinone
123-31-9
Information on toxicological effects
Symptoms
Product does not present an acute toxicity hazard based on known or supplied information.
.
Specific test data for the substance or mixture is not available. May cause irritation of
respiratory tract.
Specific test data for the substance or mixture is not available. Expected to be an irritant
based on components. Irritating to eyes. May cause redness, itching, and pain. May cause
temporary eye irritation.
Specific test data for the substance or mixture is not available. Expected to be an irritant
based on components. Irritating to skin. Prolonged contact may cause redness and
irritation.
Specific test data for the substance or mixture is not available. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea.
= 320 mg/kg ( Rat ) > 900 mg/kg ( Rat ) -
Erythema (skin redness). May cause redness and tearing of the eyes. Itching. Rashes.
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Hives.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Mutagenic Effects
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
Hydroquinone
123-31-9
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 3 - Not Classifiable as to Carcinogenicity in Humans
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Chronic Toxicity
Target Organ Effects
Aspiration Hazard
May cause sensitization in susceptible persons. May cause sensitization by skin contact.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
A3 Group 3
No information available.
No information available.
No information available.
Contains a known or suspected carcinogen.
Respiratory system. Eyes. Skin. Gastrointestinal tract (GI).
No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
Not applicable
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12. ECOLOGICAL INFORMATION
Ecotoxicity
Very toxic to aquatic life with long lasting effects.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to
Hydroquinone
123-31-9
72h EC50: = 0.335 mg/L
(Pseudokirchneriella
subcapitata) 120h EC50: =
13.5 mg/L (Desmodesmus
subspicatus)
96h LC50: = 0.044 mg/L
(Oncorhynchus mykiss) 96h
LC50: = 0.044 mg/L
(Pimephales promelas) 96h
LC50: 0.1 - 0.18 mg/L
(Pimephales promelas) 96h
LC50: = 0.17 mg/L
(Brachydanio rerio)
EC50 = 0.038 mg/L 15 min
EC50 = 0.0382 mg/L 30 min
EC50 = 0.042 mg/L 5 min
EC50 = 23.75 mg/L 60 min
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
Hydroquinone
123-31-9
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Microorganisms
0.5
Daphnia Magna (Water
Flea)
48h EC50: = 0.29 mg/L
Disposal methods
This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Contaminated Packaging
California Hazardous Waste Codes
Dispose of contents/containers in accordance with local regulations.
281
14. TRANSPORT INFORMATION
DOT
Proper Shipping Name
Hazard Class
TDG
MEX
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NOT REGULATED
NON REGULATED
N/A
Not regulated
Not regulated
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ICAO
IATA
Proper Shipping Name
Hazard Class
IMDG/IMO
Hazard Class
RID
ADR
ADN
Not regulated
Not regulated
NON REGULATED
N/A
Not regulated
N/A
Not regulated
Not regulated
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name CAS No Weight-% SARA 313 - Threshold
Hydroquinone - 123-31-9 123-31-9 0.1 - 1 1.0
Values %
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden release of pressure hazard
Reactive Hazard
Yes
Yes
Yes
No
No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances
Hydroquinone
123-31-9
100 lb 100 lb RQ 100 lb final RQ
RQs
RQ
RQ 45.4 kg final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals.
Chemical Name California Proposition 65
Sulfur dioxide - 7446-09-5 Developmental
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U.S. State Right-to-Know Regulations
.
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois
Silica fume (amorphous)
69012-64-2
Ethyl cyanoacetate
105-56-6
Hydroquinone
123-31-9
Sulfur dioxide
7446-09-5
X X
X X X
X X X X X
X X X X
International Regulations
Mexico
National occupational exposure limits
Component Carcinogen Status Exposure Limits
Hydroquinone
123-31-9 ( 0.1 - 1 )
Mexico - Occupational Exposure Limits - Carcinogens
A3 - Confirmed Animal Carcinogen
Canada
WHMIS Hazard Class
Not determined
A3 Mexico: TWA 2 mg/m
3
16. OTHER INFORMATION
NFPA
HMIS
Chronic Hazard Star Legend * = Chronic Health Hazard
Prepared By
Issuing Date
Revision Date
Revision Note
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
Health Hazards 2 Flammability 2
Health Hazards 2 * Flammability 2
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
24-Apr-2013
03-Sep-2014
No information available
End of Safety Data Sheet
Instability 1 Physical and
Chemical Hazards -
Physical Hazard 1 Personal Protection
X
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