Elmer's B1613452 User Manual

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MSDS - 00229810

Material Safety Data Sheet
Material Name: ELMER'S NO-WRINKLE RUBBER CEMENT
MSDS ID: 00229810
Issue Date: 12/16/10
Revision 1.0400
Other Sections
* * * Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name: ELMER'S NO-WRINKLE RUBBER CEMENT Manufacturer Information
Elmer's Products, Inc. 1 Easton Oval Columbus, OH 43219 Emergency Phone Number: Poison Control Center 1-888-516-2502 For additional product information, access our website at www.elmers.com or call 1-888-435-6377. To place an order, call 1-800-848-9400.
Trade Names/Synonyms
E904; E905; 231; 232; 233; 60818; 61518
Product Use
adhesives
* * * Section 2 - HAZARDS IDENTIFICATION * * *
NFPA Ratings: Health: 2 Fire: 3 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
EMERGENCY OVERVIEW Physical Form: liquid Odor: mild odor, solvent odor Major Health Hazards: potentially fatal if swallowed, respiratory tract irritation, skin irritation, eye irritation, central
nervous system depression, allergic reactions
Physical Hazards: Flammable liquid and vapor. Vapor may cause flash fire. POTENTIAL HEALTH EFFECTS
Inhalation Short Term: irritation, changes in blood pressure, nausea, vomiting, stomach pain, chest pain, difficulty breathing,
irregular heartbeat, headache, drowsiness, dizziness, disorientation, emotional disturbances, hallucinations, loss of coordination, suffocation, internal bleeding, kidney damage, unconsciousness, coma
Long Term: no information on significant adverse effects Skin
Short Term: irritation, allergic reactions, absorption may occur, changes in blood pressure, nausea, vomiting, irregular
heartbeat, headache, drowsiness, dizziness, loss of coordination
Long Term: irritation Eye
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Short Term: irritation, eye damage
Long Term: irritation Ingestion
Short Term: potentially fatal if swallowed, irritation, changes in blood pressure, nausea, vomiting, diarrhea, stomach
pain, difficulty breathing, irregular heartbeat, headache, drowsiness, dizziness, disorientation, emotional disturbances, hallucinations, loss of coordination, internal bleeding, kidney damage, unconsciousness, coma
Long Term: no information on significant adverse effects
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS Component Percent
142-82-5 HEPTANE >70 67-63-0 ISOPROPYL ALCOHOL 1-5
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information identified as the following: Heptane isomers.
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.
Skin
If bonding occurs, immerse the bonded surfaces in warm soapy water. Peel or roll the surfaces apart using a blunt edge, such as a spatula or spoon handle. Do not pull surfaces apart with a direct opposing action. If burns occur, treat as thermal burns. Get medical attention, if needed.
Eyes
If bonding to tissues occurs, wash with large amounts of warm water. Cover both eyes with sterile, dry bandages. The eye will open without further action. Do not pull surfaces apart with a direct opposing action. If burns occur, treat as thermal burns. Get medical attention.
Ingestion
Wet lips with water. Peel or roll the surfaces apart using a blunt edge, such as a spatula or spoon handle. Do not pull surfaces apart with a direct opposing action. If a lump forms in the mouth, turn head to side. If burns occur, treat as thermal burns. Get medical attention.
Note to Physicians
Mineral oil, vegetable oil, or petroleum jelly may help soften the bonding between skin surfaces. For skin contact, consider acetone or nitromethane.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
Flammable Properties
Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive.
Extinguishing Media
carbon dioxide, regular dry chemical, regular foam, water
Fire Fighting Measures
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
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* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Occupational spill/release
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal.
* * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store in a tightly closed container. Store in a well-ventilated area. Avoid heat, flames, sparks and other sources of ignition. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. See original container for storage recommendations. Keep separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits HEPTANE (142-82-5)
ACGIH: 400 ppm TWA
500 ppm STEL
NIOSH: 85 ppm TWA; 350 mg/m3 TWA
440 ppm Ceiling (15 min); 1800 mg/m3 Ceiling (15 min)
OSHA: 500 ppm TWA; 2000 mg/m3 TWA OSHA
500 ppm STEL; 2000 mg/m3 STEL
(Vacated):
400 ppm TWA; 1600 mg/m3 TWA
ISOPROPYL ALCOHOL (67-63-0)
ACGIH: 200 ppm TWA
400 ppm STEL
NIOSH: 400 ppm TWA; 980 mg/m3 TWA
500 ppm STEL; 1225 mg/m3 STEL
OSHA: 400 ppm TWA; 980 mg/m3 TWA OSHA
500 ppm STEL; 1225 mg/m3 STEL
(Vacated):
400 ppm TWA; 980 mg/m3 TWA
Ventilation
Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT Eyes/Face
Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
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Glove Recommendations
Wear appropriate chemical resistant gloves.
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive­pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Physical State: Liquid Appearance: opaque Physical Form: liquid Odor: mild odor, solvent odor Odor Threshold: Not available pH: Not available Melting/Freezing Point: Not available Boiling Point: 90 °C
Flash Point: -4 °C (TCC)
Evaporation Rate:
<1 (ether=1)>
OSHA Flammability Class: IB Vapor Pressure: Not available Vapor Density (air = 1): >1 Density: Not available Specific Gravity (water = 1): 0.71 Water Solubility: almost insoluble Coeff. Water/Oil Dist: Not available Viscosity: Not available Volatility: 90 %
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure.
Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers.
Materials to Avoid
acids, bases, amines, oxidizing materials
Decomposition Products
oxides of carbon
Possibility of Hazardous Reactions
Will not polymerize.
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* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:
HEPTANE (142-82-5)
Inhalation LC50 Rat 103 g/m3 4 h; Oral LD50 Mouse 5000 mg/kg; Dermal LD50 Rabbit 3000 mg/kg
ISOPROPYL ALCOHOL (67-63-0)
Inhalation LC50 Rat 72.6 mg/L 4 h; Oral LD50 Rat 4396 mg/kg; Dermal LD50 Rat 12800 mg/kg; Dermal LD50 Rabbit 12870 mg/kg
RTECS Acute Toxicity (selected)
The components of this material have been reviewed, and RTECS publishes the following endpoints:
HEPTANE (142-82-5)
Inhalation: 103 gm/m3/4 hour Inhalation Rat LC50; 48000 ppm/4 hour Inhalation Rat
LC50; >29290 mg/m3 Inhalation Rat LC50
ISOPROPYL ALCOHOL (67-63-0)
Inhalation: 16000 ppm/8 hour Inhalation Rat LC50; 72600 mg/m3 Inhalation Rat
LC50
Oral: 5000 mg/kg Oral Rat LD50; 5045 mg/kg Oral Rat LD50 Skin: 12800 mg/kg Skin Rabbit LD50
Acute Toxicity Level HEPTANE (142-82-5)
Slightly
inhalation.
Toxic:
ISOPROPYL ALCOHOL (67-63-0)
Moderately
inhalation, ingestion.
Toxic: Slightly
dermal absorption.
Toxic:
Component Carcinogenicity ISOPROPYL ALCOHOL (67-63-0)
ACGIH: A4 - Not Classifiable as a Human Carcinogen IARC: Monograph 71 [1999]; Supplement 7 [1987]; Monograph 15 [1977]
(Group 3 (not classifiable))
RTECS Irritation
The components of this material have been reviewed, and RTECS publishes the following endpoints:
ISOPROPYL ALCOHOL (67-63-0)
10 mg Eyes Rabbit moderate; 100 mg/24 hour Eyes Rabbit moderate; 100 mg Eyes Rabbit severe; 500 mg Skin Rabbit mild
Local Effects HEPTANE (142-82-5)
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Irritant: inhalation, skin, eye.
ISOPROPYL ALCOHOL (67-63-0)
Irritant: inhalation, eye.
Target Organs HEPTANE (142-82-5)
central nervous system.
ISOPROPYL ALCOHOL (67-63-0)
central nervous system.
Medical Conditions Aggravated by Exposure
respiratory disorders, kidney disorders, skin disorders and allergies, liver disorders
RTECS Tumorigenic
The components of this material have been reviewed, and RTECS publishes data for one or more components.
RTECS Mutagenic
The components of this material have been reviewed, and RTECS publishes data for one or more components.
RTECS Reproductive Effects
The components of this material have been reviewed, and RTECS publishes data for one or more components.
Additional Data
Stimulants such as epinephrine may induce ventricular fibrillation.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity HEPTANE (142-82-5)
Fish: 96 Hr LC50 Cichlid fish: 375.0 mg/L Invertebrate: 24 Hr EC50 Daphnia magna: >10 mg/L
ISOPROPYL ALCOHOL (67-63-0)
Fish: 96 Hr LC50 Pimephales promelas: 9640 mg/L [flow-through]; 96 Hr LC50
Pimephales promelas: 11130 mg/L [static]; 96 Hr LC50 Lepomis macrochirus: >1400000 µg/L
Algae: 96 Hr EC50 Desmodesmus subspicatus: >1000 mg/L; 72 Hr EC50
Desmodesmus subspicatus: >1000 mg/L
Invertebrate: 48 Hr EC50 Daphnia magna: 13299 mg/L
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information Shipping Name: Consumer commodity Hazard Class: ORM-D Required Label(s): None
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TDG Information: No Classification assigned.
* * * Section 15 - REGULATORY INFORMATION * * *
U.S. Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan.
HEPTANE (142-82-5)
TSCA 12b: Section 4, 1 %
ISOPROPYL ALCOHOL (67-63-0)
SARA 313: 1.0 % de minimis concentration (only if manufactured by the strong acid
process, no supplier notification)
SARA 311/312 Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactive: No U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component CAS CA MA MN NJ PA RI
HEPTANE 142-82-5 Yes Yes Yes Yes Yes Yes ISOPROPYL ALCOHOL 67-63-0 Yes Yes Yes Yes Yes Yes
Not regulated under California Proposition 65
Canada WHMIS
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
HEPTANE (142-82-5)
1 %
ISOPROPYL ALCOHOL (67-63-0)
1 %
WHMIS Classification
D2B, B2.
Canadian Inventory
All components of this product are listed on the DSL.
U.S. Inventory (TSCA)
All the components of this substance are listed on or are exempt from the inventory.
Component Analysis - Inventory
Component CAS US CA
HEPTANE 142-82-5 Yes DSL ISOPROPYL ALCOHOL 67-63-0 Yes DSL
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU ­Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL -
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Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing
Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO ­International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK ­Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise.
“RTECS®” is a United States trademark owned and licensed under authority of the U.S. Government, by and through Symyx Software, Inc. Portions ©Copyright 2010, U.S. Government. All rights reserved.
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