Elmer's B1613186 User Manual

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Material Safety Data Sheet

Material Name: ELMER'S NO-WRINKLE RUBBER CEMENT

MSDS ID: 00229810

Issue Date: 05/31/13

Revision 1.1201

Other Sections

03 04 05 06 07 08 09 10 11 12 13 14 15 16

02

* * * Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION* * *

Material Name: ELMER'S NO-WRINKLE RUBBER CEMENT

Manufacturer Information

Elmer's Products, Inc.
460 Polaris Parkway
Westerville, OH 43082
Emergency Phone Number:
Poison Control Center
1-888-516-2502
For additional product information, access our website at www.elmers.com or call 1-888-435-6377. To place
an order, call 1-800-848-9400.

Trade Names/Synonyms

E141; E904; 231, 232, 233, 61518; E63231T

Product Use

adhesives

* * * Section 2 - HAZARDS IDENTIFICATION* * *

NFPA Ratings:
Health: 2 Fire: 3 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe

EMERGENCY OVERVIEW
Physical Form: liquid
Odor: mild odor, solvent odor
Major Health Hazards: potentially fatal if swallowed, respiratory tract irritation, skin irritation, eye

irritation, central nervous system depression, allergic reactions

Physical Hazards: Flammable liquid and vapor. Vapor may cause flash fire.
POTENTIAL HEALTH EFFECTS

Inhalation
Short Term: irritation, changes in blood pressure, nausea, vomiting, stomach pain, chest pain, difficulty

breathing, irregular heartbeat, headache, drowsiness, dizziness, disorientation, emotional disturbances,
hallucinations, loss of coordination, suffocation, internal bleeding, kidney damage, unconsciousness, coma

Long Term: no information on significant adverse effects

Skin
Short Term: irritation, allergic reactions, absorption may occur, changes in blood pressure, nausea, vomiting,

irregular heartbeat, headache, drowsiness, dizziness, loss of coordination

Long Term: irritation

Eye
Short Term

irritation, eye damage

y

.

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Long Term: irritation

Ingestion
Short Term: potentially fatal if swallowed, irritation, changes in blood pressure, nausea, vomiting, diarrhea,

stomach pain, difficulty breathing, irregular heartbeat, headache, drowsiness, dizziness, disorientation,
emotional disturbances, hallucinations, loss of coordination, internal bleeding, kidney damage,
unconsciousness, coma

Long Term: no information on significant adverse effects

* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS* * *

CAS Component Percent

142-82-5 HEPTANE >70

67-63-0 ISOPROPYL ALCOHOL 1-5

Component Related Regulatory Information

This product may be regulated, have exposure limits or other information identified as the following: Heptane
isomers.

* * * Section 4 - FIRST AID MEASURES* * *

Inhalation

If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get
immediate medical attention.

Skin

If bonding occurs, immerse the bonded surfaces in warm soapy water. Peel or roll the surfaces apart using a
blunt edge, such as a spatula or spoon handle. Do not pull surfaces apart with a direct opposing action. If
burns occur, treat as thermal burns. Get medical attention, if needed.

Eyes

If bonding to tissues occurs, wash with large amounts of warm water. Cover both eyes with sterile, dry
bandages. The eye will open without further action. Do not pull surfaces apart with a direct opposing action.
If burns occur, treat as thermal burns. Get medical attention.

Ingestion

Wet lips with water. Peel or roll the surfaces apart using a blunt edge, such as a spatula or spoon handle. Do
not pull surfaces apart with a direct opposing action. If a lump forms in the mouth, turn head to side. If burns
occur, treat as thermal burns. Get medical attention.

Note to Physicians

Mineral oil, vegetable oil, or petroleum jelly may help soften the bonding between skin surfaces. For skin
contact, consider acetone or nitromethane.

* * * Section 5 - FIRE FIGHTING MEASURES* * *

See Section 9 for Flammability Properties

Flammable Properties

Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and
flash back. Vapor/air mixtures are explosive.

Extinguishing Media

carbon dioxide, regular dry chemical, regular foam, water

Fire Fighting Measures

Move container from fire area if it can be done without risk. Cool containers with water spray until well after
the fire is out. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams.
Avoid inhalation of material or combustion b

-products. Stay upwind and keep out of low areas

g

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* * * Section 6 - ACCIDENTAL RELEASE MEASURES* * *

Occupational spill/release

Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible without personal risk. Reduce
vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled
material in appropriate container for disposal.

* * * Section 7 - HANDLING AND STORAGE* * *

Storage Procedures

Store and handle in accordance with all current regulations and standards. Store in a cool, dry place. Store in a
tightly closed container. Store in a well-ventilated area. Avoid heat, flames, sparks and other sources of
ignition. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. See
original container for storage recommendations. Keep separated from incompatible substances.

* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION* * *

Component Exposure Limits
HEPTANE (142-82-5)

ACGIH: 400 ppm TWA

500 ppm STEL

NIOSH: 85 ppm TWA; 350 mg/m3 TWA

440 ppm Ceiling (15 min); 1800 mg/m3 Ceiling (15 min)

OSHA: 500 ppm TWA; 2000 mg/m3 TWA

OSHA
(Vacated):

ISOPROPYL ALCOHOL (67-63-0)

ACGIH: 200 ppm TWA

NIOSH: 400 ppm TWA; 980 mg/m3 TWA

OSHA: 400 ppm TWA; 980 mg/m3 TWA

OSHA
(Vacated):

Ventilation

Ventilation equipment should be explosion-resistant if explosive concentrations of material are present.
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure
limits.

PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face

Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick
drench shower in the immediate work area.

Protective Clothin

500 ppm STEL; 2000 mg/m3 STEL

400 ppm TWA; 1600 mg/m3 TWA

400 ppm STEL

500 ppm STEL; 1225 mg/m3 STEL

500 ppm STEL; 1225 mg/m3 STEL

400 ppm TWA; 980 mg/m3 TWA

poly

.

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Wear appropriate chemical resistant clothing.

Glove Recommendations

Wear appropriate chemical resistant gloves.

Respiratory Protection

Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Respiratory protection is ranked in order from minimum to maximum.
Consider warning properties before use.
Any chemical cartridge respirator with organic vapor cartridge(s).
Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s).
Any air-purifying respirator with a full facepiece and an organic vapor canister.

For Unknown Concentrations or Immediately Dangerous to Life or Health -

Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive­pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure­demand or other positive-pressure mode.
Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other
positive-pressure mode.

* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES* * *

Physical State: Liquid Appearance: opaque

Physical Form: liquid Odor: mild odor, solvent odor

Odor Threshold: Not available pH: Not available

Melting/Freezing Point: Not available Boiling Point: 90 °C

Flash Point: -4 °C TCC

OSHA Flammability Class: IB Vapor Pressure: Not available

Vapor Density (air = 1): >1 Density: Not available

Specific Gravity (water = 1): 0.71 Water Solubility: almost insoluble

Coeff. Water/Oil Dist: Not available Viscosity: Not available

Volatility: 90 %

* * * Section 10 - STABILITY AND REACTIVITY* * *

Chemical Stability

Stable at normal temperatures and pressure.

Conditions to Avoid

Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to
heat. Keep out of water supplies and sewers.

Materials to Avoid

acids, bases, amines, oxidizing materials

Decomposition Products

oxides of carbon

Evaporation Rate:

<1 ether=1>

Possibility of Hazardous Reactions

Will not

merize

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* * * Section 11 - TOXICOLOGICAL INFORMATION* * *

Component Analysis - LD50/LC50

The components of this material have been reviewed in various sources and the following selected endpoints
are published:

HEPTANE (142-82-5)

Oral LD50 Mouse 5000 mg/kg; Dermal LD50 Rabbit 3000 mg/kg;
Inhalation LC50 Rat 103 g/m3 4 h

ISOPROPYL ALCOHOL (67-63-0)

Oral LD50 Rat 4396 mg/kg; Dermal LD50 Rabbit 12800 mg/kg; Inhalation
LC50 Rat 16000 ppm 8 h

RTECS Acute Toxicity (selected)

The components of this material have been reviewed, and RTECS publishes the following endpoints:

HEPTANE (142-82-5)

Inhalation: 48000 ppm/4 hour Inhalation Rat LC50; 103 gm/m3/4 hour Inhalation Rat

LC50; >29290 mg/m3 Inhalation Rat LC50

ISOPROPYL ALCOHOL (67-63-0)

Inhalation: 16000 ppm/8 hour Inhalation Rat LC50; 72600 mg/m3 Inhalation Rat LC50

Oral: 5045 mg/kg Oral Rat LD50; 5000 mg/kg Oral Rat LD50

Skin: 12800 mg/kg Skin Rabbit LD50

Acute Toxicity Level
HEPTANE (142-82-5)

Slightly
Toxic:

ISOPROPYL ALCOHOL (67-63-0)

Moderately
Toxic:

Slightly
Toxic:

Component Carcinogenicity
ISOPROPYL ALCOHOL (67-63-0)

ACGIH: A4 - Not Classifiable as a Human Carcinogen

IARC: Monograph 71 [1999]; Supplement 7 [1987]; Monograph 15 [1977] (Group

RTECS Irritation

The components of this material have been reviewed, and RTECS publishes the following endpoints:

ISOPROPYL ALCOHOL (67-63-0)

inhalation

inhalation, ingestion

dermal absorption

3 (not classifiable))

10 mg Eyes Rabbit moderate; 100 mg/24 hour Eyes Rabbit moderate; 100
mg Eyes Rabbit severe; 500 mg Skin Rabbit mild

Local Effects
HEPTANE (142-82-5)

Irritant: inhalation, skin, eye

)

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ISOPROPYL ALCOHOL (67-63-0

Irritant: inhalation, eye

Target Organs
HEPTANE (142-82-5)

central nervous system

ISOPROPYL ALCOHOL (67-63-0)

central nervous system

Medical Conditions Aggravated by Exposure

respiratory disorders, kidney disorders, skin disorders and allergies, liver disorders

RTECS Tumorigenic

The components of this material have been reviewed, and RTECS publishes data for one or more components.

RTECS Mutagenic

The components of this material have been reviewed, and RTECS publishes data for one or more components.

RTECS Reproductive Effects

The components of this material have been reviewed, and RTECS publishes data for one or more components.

Additional Data

Stimulants such as epinephrine may induce ventricular fibrillation.

* * * Section 12 - ECOLOGICAL INFORMATION* * *

Component Analysis - Aquatic Toxicity
HEPTANE (142-82-5)

Fish: 96 Hr LC50 Cichlid fish: 375.0 mg/L

Invertebrate: 24 Hr EC50 Daphnia magna: >10 mg/L

ISOPROPYL ALCOHOL (67-63-0)

Fish: 96 Hr LC50 Pimephales promelas: 9640 mg/L [flow-through]; 96 Hr LC50

Pimephales promelas: 11130 mg/L [static]; 96 Hr LC50 Lepomis
macrochirus: >1400000 µg/L

Algae: 96 Hr EC50 Desmodesmus subspicatus: >1000 mg/L; 72 Hr EC50

Desmodesmus subspicatus: >1000 mg/L

Invertebrate: 48 Hr EC50 Daphnia magna: 13299 mg/L

* * * Section 13 - DISPOSAL CONSIDERATIONS* * *

Disposal Methods

Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262.
Hazardous Waste Number(s): D001.

Component Waste Numbers

The U.S. EPA has not published waste numbers for this product's components.

* * * Section 14 - TRANSPORT INFORMATION* * *

US DOT Information
Shipping Name: Heptanes, Mixture
Hazard Class: 3
UN/NA #: UN1206
Packing Group: II

uired Label(s): 3

Re

N

5

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Additional Info.: 1 Liter (0.3 gallons) and less may be shipped as Limited Quantity.
TDG Information
Shipping Name: Heptanes, Mixture
Hazard Class: 3
UN #: UN1206
Packing Group: II
Required Label(s): 3
Additional Info.: 1 Liter (0.3 gallons) and less may be shipped as Limited Quantity.

* * * Section 15 - REGULATORY INFORMATION* * *

U.S. Federal Regulations

This material contains one or more of the following chemicals required to be identified under SARA Sections
302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA
12(b), and/or require an OSHA process safety plan.

HEPTANE (142-82-5)

TSCA 12b: Section 4, 1 % de minimus concentration

ISOPROPYL ALCOHOL (67-63-0)

SARA 313: 1.0 % de minimis concentration (only if manufactured by the strong acid

process, no supplier notification)

SARA 311/312
Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactive: No
U.S. State Regulations

The following components appear on one or more of the following state hazardous substances lists:

Component CAS CA MA MN NJ PA

HEPTANE 142-82-5 Yes Yes Yes Yes Yes

ISOPROPYL ALCOHOL 67-63-0 Yes Yes Yes Yes Yes

ot regulated under California Proposition 6

Canada WHMIS

The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure
List:

HEPTANE (142-82-5)

1 %

ISOPROPYL ALCOHOL (67-63-0)

1 %

WHMIS Classification

D2B, B2.

Canadian Inventory

All components of this product are listed on the DSL.

U.S. Inventory (TSCA)

All the components of this substance are listed on or are exempt from the inventory.

Component Analysis - Inventory

Component CAS US CA

HEPTANE 142-82-5 Yes DSL

ISOPROPYL ALCOHOL 67-63-0 Yes DSL

N

N

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* * * Section 16 - OTHER INFORMATION* * *

Key / Legend

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport;
AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts
Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China;
CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of
Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS ­European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency;
EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA ­International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient
Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime
Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive
Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK - Maximum Concentration
Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency;

IOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry;

TP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health
Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail
Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments
and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods;
TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US ­United States

Other Information

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE
PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE,
except that the product shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind shall be greater in
amount than the purchase price of the quantity of product in respect of which damages are
claimed. In no event shall Seller be liable for incidental or consequential damages, whether
Buyer's claim is based on contract, breach of warranty, negligence or otherwise.

"RTECS®" is a United States trademark owned and licensed under authority of the U.S. Government, by and
through Accelrys, Inc. Portions ©Copyright 2013, U.S. Government. All rights reserved.