ECOS PL9892/04 User Manual

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SAFETY DATA SHEET
Acute toxicity - Inhalation (Dusts/Mists)
Category 2
Eye irritation
Category 1
Issuing Date No data available Revision Date 28-Oct-2014 Revision Number 1
Product identifier Product Name (PL 9892) Oxo Brite
Other means of identification Synonyms None
Recommended use of the chemical and restrictions on use Recommended Use Laundry Pre-Wash - All Other Forms Uses advised against No information available Details of the supplier of the safety data sheet Supplier Name VENUS LABORATORIES
Supplier Address 111 S ROHLWING ROAD

Supplier Phone Number Phone:800-592-1900 Emergency telephone number Chemtrec: 800-424-9300

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
1.
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
ADDISON IL 60101 US
2.
HAZARDS IDENTIFICATION
Category 2

GHS Label elements, including precautionary statements

Emergency Overview
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Revision Date 28-Oct-2014
Signal word Danger Hazard Statements
May cause eye irritation

May cause irritation if inhaled

Appearance White Physical State Powder(s) Solid Odor None

Precautionary Statements - Prevention

Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray
Remove the contaminated clothing and wash.

Precautionary Statements – Response

Specific treatment (see supplemental first aid instructions on this label) Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If irritation persists consult a doctor/physician.

Inhalation IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing Call a doctor/physician if you feel unwell

Ingestion IF SWALLOWED: Call a or doctor/physician if you feel unwell Rinse mouth

Precautionary Statements - Storage Store locked up

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity

0% of the mixture consists of ingredient(s) of unknown toxicity Other information Toxic to aquatic life with long lasting effects Interactions with Other Chemicals

No information available.
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Chemical Name
CAS No
Weight-%
Trade Secret
Sodium percarbonate
15630-89-4
40 - 70
*
Sodium carbonate
497-19-8
15 - 40
*
3.

COMPOSITION/INFORMATION ON INGREDIENTS

First aid measures

*The exact percentage (concentration) of composition has been withheld as a trade secret
4.

FIRST AID MEASURES

General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical
attention is required.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and If irritation persists consult a doctor/physician.
Skin Contact
Wash off immediately with soap and plenty of water for at least 15 minutes. May
cause an allergic skin reaction. In the case of skin irritation or allergic reactions
see a physician.
Inhalation
Remove to fresh air. Get medical attention immediately if symptoms occur.
Ingestion
Rinse mouth immediately and drink plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
Self-protection of the first aider
Avoid contact with skin, eyes or clothing. Use personal protective equipment as
required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and Effects
Indication of any immediate medical attention and special treatment needed
Burning sensation. Coughing and/ or wheezing. Difficulty in breathing.
Notes to Physician
Treat symptomatically.
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5.

FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media

CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical

No information available.
Uniform Fire Code Oxidizer: Class 1--Solid
Irritant: Solid

Hazardous Combustion Products Carbon oxides.

Explosion Data Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge No. Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6.

ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required.
Other Information Refer to protective measures listed in Sections 7 and 8. Environmental Precautions

Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage

if safe to do so.

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers.

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7.

Precautions for safe handling

HANDLING AND STORAGE

Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Take off
contaminated clothing and wash before reuse.

Conditions for safe storage, including any incompatibilities

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
Keep out of the reach of children.
Incompatible Products Strong oxidizing agents. Strong acids. Strong bases.
8.

Control parameters

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies

Appropriate engineering controls

Engineering Measures Showers
Eyewash stations
Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/Face Protection Tight sealing safety goggles. Skin and Body Protection Wear protective gloves and protective clothing. Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Avoid contact with skin, eyes or clothing. Wear suitable
gloves and eye/face protection. Wash hands before breaks and immediately after handling
the product
9.

PHYSICAL AND CHEMICAL PROPERTIES

Physical and Chemical Properties Physical State Powder(s), Solid
Appearance White Odor None Color No information available Odor Threshold No information available
Property Values Remarks Method pH No data available None known Melting / freezing point No data available None known Boiling point / boiling range No data available None known
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Flammability (solid, gas)
No data available
None known
Flammability Limit in Air
Upper flammability limit
Vapor pressure
No data available
Vapor density
Solubility in other solvents
No data available
No data available
None known
None known
Partition coefficient: n-octanol/waterNo data available None known
Autoignition temperature
No data available
None known
Particle Size Distribution
Flash Point Evaporation Rate
No data available
No data available
None known None known
Lower flammability limit
Specific Gravity Water Solubility
Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Oxidizing Properties
Other Information Softening Point
VOC Content (%) Particle Size

Reactivity

No data available. Chemical stability

Stable under recommended storage conditions. Possibility of Hazardous Reactions

None under normal processing.
No data available
No data available
No data available
Very soluble
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
10.

STABILITY AND REACTIVITY

None known None known
None known
None known None known None known

Hazardous Polymerization Hazardous polymerization does not occur.

Conditions to avoid Excessive heat.

Incompatible materials Strong oxidizing agents. Strong acids. Strong bases.

Hazardous Decomposition Products Carbon oxides.

11.

TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information Product does not present an acute toxicity hazard based on known or supplied information.
.
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Chemical Name
Oral LD50
Dermal LD50
Inhalation LC50
-
497-19-8
Inhalation Specific test data for the substance or mixture is not available. May cause irritation of
respiratory tract.
Eye Contact Specific test data for the substance or mixture is not available. Expected to be an irritant
based on components. May Cause Eye Irritation. May cause burns.
Skin Contact Specific test data for the substance or mixture is not available. Not expected to be a skin irritant based on components. Prolonged contact may cause redness and
irritation.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea.

Component Information

Sodium percarbonate
15630-89-4
Sodium carbonate
Information on toxicological effects
= 1034 mg/kg ( Rat ) = 4090 mg/kg ( Rat )
-
-
= 2300 mg/m
3
( Rat ) 2 h

Symptoms Erythema (skin redness). May cause blindness. Burning. Coughing and/ or wheezing. Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity Contains no ingredient listed as a carcinogen.
Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available.

Chronic Toxicity No known effect based on information supplied. Target Organ Effects Eyes. Respiratory system.

Aspiration Hazard No information available. Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral)

1,444.00 mg/kg ATEmix (inhalation-dust/mist)

3.03 mg/l
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15630-89-4
(Chlorella emersonii)
(Pimephales promelas)
Chemical Name
California Hazardous Waste
497-19-8

Ecotoxicity Toxic to aquatic life with long lasting effects.

Chemical Name
Sodium percarbonate
Toxicity to Algae
240h EC50: = 70 mg/L
12.

ECOLOGICAL INFORMATION

Toxicity to Fish
96h LC50: = 70.7 mg/L
Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
48h EC50: = 4.9 mg/L
Sodium carbonate
497-19-8

Persistence and Degradability No information available.

120h EC50: = 242 mg/L
(Nitzschia)
96h LC50: = 300 mg/L
(Lepomis macrochirus) 96h
LC50: 310 - 1220 mg/L
(Pimephales promelas)
48h EC50: = 265 mg/L

Bioaccumulation No information available

Other adverse effects No information available.

13.

Waste treatment methods

DISPOSAL CONSIDERATIONS

Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Contaminated Packaging Dispose of contents/containers in accordance with local regulations.

California Hazardous Waste Codes 181

This product contains one or more substances that are listed with the State of California as a hazardous waste.
DOT NOT REGULATED
Proper Shipping Name NON REGULATED
Hazard Class N/A TDG Not regulated MEX Not regulated
Sodium percarbonate
Sodium carbonate
15630-89-4
14.

TRANSPORT INFORMATION

Ignitable
Corrosive
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ICAO Not regulated IATA Not regulated
Proper Shipping Name NON REGULATED
Hazard Class N/A IMDG/IMO Not regulated
Hazard Class N/A RID Not regulated ADR Not regulated ADN Not regulated
International Inventories
TSCA Complies DSL All components are listed either on the DSL or NDSL.
15.
REGULATORY INFORMATION
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

US Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

Acute Health Hazard Yes
Chronic Health Hazard No
Fire Hazard No
Sudden release of pressure hazard No
Reactive Hazard No CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

US State Regulations

California Proposition 65

This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated by state right-to-know regulations.

International Regulations

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Canada WHMIS Hazard Class
D2B - Toxic materials
16.

OTHER INFORMATION

NFPA Health Hazards 1 Flammability 0 Instability 1 Physical and

Chemical Hazards
OX
HMIS Health Hazards 1 Flammability 0 Physical Hazard 1 Personal Protection
X
Revision Date Revision Note
28-Oct-2014 No information available

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet
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