ECOS PL9868/04 User Manual

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SAFETY DATA SHEET
Skin /irritation
Category 1
Serious eye irritation
Category 1
Issuing Date No data available Revision Date 25-Nov-2014 Revision Number 1

Product identifier

Product Name ECOS PRO HD White Board Cleaner (PL9868)
Other means of identification Synonyms None
Recommended use of the chemical and restrictions on use Recommended Use Whiteboard Cleaner - Non-aerosol Uses advised against No information available Details of the supplier of the safety data sheet Supplier Name VENUS LABORATORIES
Supplier Address 111 S. ROHLWING ROAD ADDISON IL,
Supplier Phone Number Phone:800-592-1900 Emergency telephone number Chemtrec: 800-424-9300
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
1.
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
60101
US
2.
HAZARDS IDENTIFICATION

GHS Label elements, including precautionary statements

Emergency Overview
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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014
Signal word Warning Hazard Statements
May cause skin irritation May cause eye irritation
Appearance Creamy Physical State Cream Liquid Odor Lemon

Precautionary Statements - Prevention

Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray
Remove the contaminated clothing and wash.

Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label)

Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If irritation persists consult a doctor/physician.

Skin IF ON SKIN: N o adverse rea ction ex pected. Wash with soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention

Precautionary Statements - Storage Store in a well-ventilated place. Keep cool

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity

38.05% of the mixture consists of ingredient(s) of unknown toxicity Other information Toxic to aquatic life with long lasting effects

PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION Interactions with Other Chemicals

No information available.
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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014
Chemical Name
CAS No
Weight-%
Trade Secret
Limestone
1317-65-3
15 - 40
*
Cocamidopropyl betaine
61789-40-0
7 - 13
*
3.
.

COMPOSITION/INFORMATION ON INGREDIENTS

First aid measures

*The exact percentage (concentration) of composition has been withheld as a trade secret
4.

FIRST AID MEASURES

General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical attention is required.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and If irritation persists consult a doctor/physician.
Skin Contact
Wash off immediately with soap and plenty of water for at least 15 minutes. May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a physician.
Inhalation
Remove to fresh air. Get medical attention immediately if symptoms occur.
Ingestion
Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician.
Self-protection of the first aider
Avoid contact with skin, eyes or clothing. Use personal protective equipment as

required. Wear personal protective clothing (see section 8).

Most important symptoms and effects, both acute and delayed
Most Important Symptoms and Effects
Indication of any immediate medical attention and special treatment needed
Burning sensation.
Notes to Physician
May cause sensitization of susceptible persons. Treat symptomatically.
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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014
5.

FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam.

Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.

Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. In the event of fire, cool tanks with water spray.

Uniform Fire Code Sensitizer: Liquid

Hazardous Combustion Products

Carbon oxides.
Explosion Data Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge Yes. Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6.

ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required.
Other Information Refer to protective measures listed in Sections 7 and 8. Environmental Precautions

Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage

if safe to do so.

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Soak up with inert absorbent material. Pick up and transfer to properly labeled

containers.
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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014
Chemical Name
ACGIH TLV
OSHA PEL
NIOSH IDLH
Limestone
-
TWA: 15 mg/m
(vacated) TWA: 5 mg/m
TWA: 5 mg/m3 respirable dust
7.

Precautions for safe handling

HANDLING AND STORAGE

Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product.

Conditions for safe storage, including any incompatibilities

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
Keep out of the reach of children.
.
Incompatible Products Strong acids. Strong oxidizing agents. Strong bases.
8.

Control parameters

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
3
3
1317-65-3
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health
TWA: 5 mg/m
(vacated) TWA: 15 mg/m
3
3
TWA: 10 mg/m
3
total dust
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992) See section 15 for national exposure control parameters

Appropriate engineering controls

Engineering Measures Showers
Eyewash stations Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/Face Protection None required for consumer use. If splashes are likely to occur:. Tight sealing safety
goggles.
Skin and Body Protection Wear protective gloves and protective clothing. Long sleeved clothing. Impervious gloves. Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product.
9.

PHYSICAL AND CHEMICAL PROPERTIES

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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014
Physical State
Cream, Liquid
Appearance
Creamy
Odor
Lemon
Flammability Limit in Air
Upper flammability limit
Vapor pressure
No data available
None known
Vapor density
No data available
None known
Physical and Chemical Properties
Color Propert
y pH Melting / freezing point Boiling point / boiling range Flash Point Evaporation Rate Flammability (solid, gas)
Lower flammability limit
Specific Gravity Water Solubility Solubility in other solvents Partition coefficient: n-octanol/waterNo data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive properties No data available Oxidizing Properties No data available
No information available Values
8 No data available 212°F 94° C / 201° F No data available No data available
No data available No data available
No data available Soluble in water No data available
Odor Threshold Remarks Method
None known None known None known None known None known None known
None known None known None known
Other Information Softening Point No data available

VOC Content (%) No data available Particle Size No data available Particle Size Distribution

No information available
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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014
10.
Reactivity

No data available. Chemical stability

Stable under recommended storage conditions. Possibility of Hazardous Reactions

None under normal processing.
STABILITY AND REACTIVITY

Hazardous Polymerization

Hazardous polymerization does not occur. Conditions to avoid

Heat, flames and sparks. Incompatible materials

Strong acids. Strong oxidizing agents. Strong bases. Hazardous Decomposition Products

Carbon oxides.
11.

TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information .
Inhalation Specific test data for the substance or mixture is not available. No irr itation ex pected. Eye Contact Specific test data for the substance or mixture is not available. Not expected to be an
irritant based on components. May Cause Eye Irritation. May cause burns.
Skin Contact Specific test data for the substance or mixture is not available. Not expected to be a
skin irritant based on components. Prolonged contact may cause redness and irritation.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Component Information

Information on toxicological effects
Symptoms Erythema (skin redness). May cause redness and tearing of the eyes.
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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity Contains no ingredient listed as a carcinogen.
Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available.
Chronic Toxicity No known effect based on information supplied. Target Organ Effects Respiratory system. Eyes. Skin.
Aspiration Hazard No information available. Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral)
25,046.00 mg/kg
12.

ECOLOGICAL INFORMATION

Ecotoxicity

Toxic to aquatic life with long lasting effects.
Chemical Name
Cocamidopropyl betaine
61789-40-0

Persistence and Degradability No information available.

Toxicity to Algae
72h EC50: 1.0 - 10.0 mg/L
(Desmodesmus
subspicatus) 96h EC50: =
0.55 mg/L (Desmodesmus subspicatus)
Toxicity to Fish
96h LC50: 1.0 - 10.0 mg/L
(Brachydanio rerio) 96h
LC50: = 2 mg/L
(Brachydanio rerio)

Bioaccumulation No information available

Other adverse effects No information available.

Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
48h EC50: = 6.5 mg/L
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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014
13.

Waste treatment methods

DISPOSAL CONSIDERATIONS

Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local
Contaminated Packaging Dispose of contents/containers in accordance with local regulations.
regulations for additional requirements.

California Hazardous Waste Codes 561

14.

TRANSPORT INFORMATION

DOT NOT REGULATED
Proper Shipping Name NON REGULATED
Hazard Class N/A TDG Not regulated MEX Not regulated ICAO Not regulated IATA Not regulated
Proper Shipping Name NON REGULATED
Hazard Class N/A IMDG/IMO Not regulated
Hazard Class N/A RID Not regulated ADR Not regulated ADN Not regulated
International Inventories
TSCA Complies DSL All components are listed either on the DSL or NDSL.
15.
REGULATORY INFORMATION
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

US Federal Regulations

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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014
Component
Carcinogen Status
Exposure Limits
Limestone
Mexico: TWA= 10 mg/m
Chemical Name
New Jersey
Massachusetts
Pennsylvania
Rhode Island
Illinois
X X
X X

SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

Acute Health Hazard Yes
Chronic Health Hazard No
Fire Hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

US State Regulations

California Proposition 65

This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations .

Limestone 1317-65-3
2-phenoxyethanol

International Regulations

122-99-6
Mexico National occupational exposure limits
Mexico - Occupational Exposure Limits - Carcinogens
1317-65-3 ( 15 - 40 )
Canada WHMIS Hazard Class
D2B - Toxic materials
X
X
3
3
16.

OTHER INFORMATION

Mexico: STEL= 20 mg/m
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ECOS PRO HD Whiteboard Cleaner (PL9868)
Revision Date 25-Nov-2014

NFPA Health Hazards 1 Flammability 1 Instability 0 Physical and

Chemical Hazards -
HMIS Health Hazards 1 Flammability 1 Physical Hazard 0 Personal Protection
X
Revision Date Revision Note
25-Nov-2014 No information available

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet
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