43.0
SECTION 2: Hazards identification
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Page 1/8
Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Printing date 03.09.2018 Version number 1 Revision: 03.09.2018
2015/830 and Regulation No 1272/2008/EC (CLP)
1.1 Product identifier
Trade name: ECOSBreeze Fabric and Carpet Odor Eliminator, Magnolia & Lily
Description / Product Code: 9839
Registration number: Substances contained in the mixture have already (pre)-registered by the suppliers.
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
Application of the substance / the mixture: Fabric-Carpet Odor Remover/Eliminator – Non-Aerosol
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Venus Labs/dba Earth Friendly Products
111. S Rohlwing Rd Addison, IL 60101
Phone: 800-595-1900
Chemtrec: 800-424-9300
1.4 Emergency telephone number:
Emergency telephone number: 112
2.1 Classification of the substance or mixture Classification according to Regulation EC No 1272/2008 CLP:
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
2.2 Label elements Labelling according to Regulation EC No 1272/2008 CLP:
The product is classified and labelled according to the CLP regulation.
Hazard pictograms: Void Signal word: Void Hazard statements:
H412 Harmful to aquatic life with long lasting effects. Precautionary statements
P102 Keep out of reach of children.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
2.3 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.
(Contd. on page 2)
GB
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 03.09.2018
Version number 1
Revision: 03.09.2018
Trade name: ECOSBreeze Fabric and Carpet Odor Eliminator, Magnolia & Lily
43.0
SECTION 3: Composition/information on ingredients
SECTION 4: First aid measures
SECTION 5: Firefighting measures
Ingredients according Regulation (EU) 830/2015:
CAS: 64-17-5
ethanol
2.5-≤6.0%
Flam. Liq. 2, H225
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Wear
6.1.2 For emergency responders Wear protective equipment. Keep unprotected persons away.
(Contd. on page 3)
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
3.2 Chemical characterisation: Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
(Contd. of page 1)
EINECS: 200-578-6
Index number: 603-002-00-5
4.1 Description of first aid measures
General information: Take affected persons out into the fresh air.
After inhalation:
In case of unconsciousness place patient stably in side position for transportation.
Seek medical treatment in case of complaints.
After skin contact:
Remove contaminated clothing.
In case of skin irritation, consult a physician.
After eye contact: Avoid strong water jet-risk of cornea damage, consult a doctor.
After swallowing:
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Seek immediate medical advice.
Never give anything by mouth to an unconscious person.
4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5.1 Extinguishing media
Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray.
5.2 Special hazards arising from the substance or mixture No further relevant information available.
5.3 Advice for firefighters
Protective equipment: Self contained breathing apparatus and full protective clothing must be worn in case of fire.
Additional information Collect contaminated fire fighting water separately. It must not enter the sewage system.
protective equipment. Keep unprotected persons away.
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 03.09.2018
Version number 1
Revision: 03.09.2018
Trade name: ECOSBreeze Fabric and Carpet Odor Eliminator, Magnolia & Lily
43.0
SECTION 7: Handling and storage
Ingredients with limit values that require monitoring at the workplace:
64-17-5 ethanol
WEL (Great Britain)
Long-term value: 1920 mg/m³, 1000 ppm
SECTION 8: Exposure controls/personal protection
complying with Regulation 1907/2006/EC (REACH Regulation), EU
(Contd. of page 2)
6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust, silica gel).
Dispose contaminated material as waste according to item 13.
6.4 Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7.1 Precautions for safe handling No special precautions are necessary if used correctl y .
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities
Storage: Store in cool, dry conditions in well sealed receptacles.
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.
7.3 Specific end use(s) No further relevant information available.
8.1 Control parameters
DNELs
Ethanol cas number: 64-17-5
Workers long-term exposure systemic effects via inhalation route: 950 mg/m
3
Workers acute/short term exposure local effects: 1900 mg/m³
Workers systemic effects long-term exposure via dermal route: 343 mg/kg bw/day
General Population systemic effects long-term exposure via inhalation route : 114 mg/m³
General Population local effects acute/short term exposure via inhalation route : 950 mg/m³
General Population systemic effects long term exposure via dermal route : 206 mg/kg bw/day
General Population systemic effects long term exposure via oral route : 87 mg/kg bw/day
PNECs
Ethanol cas number: 64-17-5
Freshwater : 0.96 mg/l
Marine water : 0.79 mg/l
Intermittent releases : 2.75 mg/l
STP : 580 mg/l
Sediment (freshwater) : 3.6 mg/kg sediment dw
Sediment (marine water) : 2.9
Soil : 0.63 mg/kg soil dw
(Contd. on page 4)
GB
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 10.09.2016
Version number 1
Revision: 10.09.2016
Trade name: ECOSBreeze Fabric and Carpet Odor Eliminator, Magnolia & Lily
(Contd. of page 3)
43.0
SECTION 9: Physical and chemical properties
(Contd. on page 5)
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
DNEL Workers Long term exposure local effcts
Ethanol (CAS 64-17-5)
Inhlation: 1900 mg/m³
DNEL Workers Long term exposure systemic effects
Ethanol (CAS 64-17-5)
Inhalation: 950 mg/m
3
Skin Contact: 343 mg/kg bw/day
DNEL consumers Acute/short term exposure Local effects
Ethanol (CAS 64-17-5)
Inhalation : 950 mg/m³
DNEL Consumers Long-term exposure systemic effects
Ethanol (CAS 64-17-5)
Inhalation: 114 mg/m³
Skin Contact: 206 mg/kg bw/day
8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures: Wash hands before breaks and at the end of work.
Respiratory protection: Not required.
Protection of hands:
Penetration time of glove material
The determined penetration times according to EN 374 part III are not performed under practical conditions.
Therefore a maximum wearing time, which corresponds to 50% of the penetration time, is recommended.
Eye protection: In processing and repackaging where is possible the eye-contact wear safety glasses.
Body protection: Not required under normal conditions of use.
9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Colour: Clear
Odour: Characteristic of the perfume
Magnolia & Lily
Odour threshold: Not determined
pH value: 7-9
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Flash point: Not Flammable
Flammability (solid, gaseous): Not applicable
Auto-ignition temperature: Not determined
Page 5/8
Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 10.09.2016
Version number 1
Revision: 10.09.2016
Trade name: ECOSBreeze Fabric and Carpet Odor Eliminator, Magnolia & Lily
(Contd. of page 4)
43.0
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity Based on available data, the classificat io n criteria are not met.
Skin corrosion/irritation Based on available data, the classification cr iter ia are not met.
(Contd. on page 6)
GB
SECTION 10: Stability and reactivity
LD/LC50 values relevant for classification:
64-17-5 ethanol
Oral
LD50
7060 mg/kg (rat)
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Decomposition temperature: Not determined
Self-igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined
Upper: Not determined
Oxidising properties Not considered as oxidising.
Vapour pressure: Not determined
Density: 0.999
Relative density Not determined
Vapour density Not determined
Evaporation rate Not determined
Solubility in / Miscibility with
water:
Fully miscible
Partition coefficient (n-octanol/water): Not determined
Viscosity:
Dynamic: Not determined
Kinematic: Not determined
9.2 Other information No further relevant information available.
10.1 Reactivity Stable under normal conditions
10.2 Chemical stability Material is stable under normal conditions.
Thermal decomposition / conditions to be avoided Stable at environment temperature.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials No further relevant information available.
10.6 Hazardous decomposition products No dangerous decomposition products known.
Inhalative
LC50/4 h (vapour)
20000 mg/l (rat)
Page 6/8
Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 10.09.2016
Version number 1
Revision: 10.09.2016
Trade name: ECOSBreeze Fabric and Carpet Odor Eliminator, Magnolia & Lily
(Contd. of page 5)
43.0
SECTION 12: Ecological information
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation
Dispose according to National Regulations.
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 7)
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Serious eye damage/irritation Based on available data, the classification criter ia are not met.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classif ica tio n c riteria are not met.
STOT-single exposure Based on available data, the classification crit eria are not met.
STOT-repeated exposure Based on available data, the classification c rite ria are not met.
Aspiration hazard Based on available data, the classifica tion c r ite ria are not met.
12.1 Toxicity
Aquatic toxicity:
Ethanol, cas: 64-17-5
Fish toxicity LC50:> 10000 mg / l
Daphnia toxicity, CEE0:> 7800 mg / l
Bacterial toxicity (Ps putida) CEE0:> 6500 mg / l
Algal toxicity (SC. Quadricauda), CEE0:> 5000 mg / l
Algal toxicity (M. Acruginosa), CEE0:> 1450 mg / l
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Ecotoxical effects:
Remark: Harmful to fish
Additional ecological information:
General notes:
The product contains materials that are harmful to the environment.
Harmful to aquatic organisms
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 03.09.2018
Version number 1
Revision: 03.09.2018
Trade name: ECOSBreeze Fabric and Carpet Odor Eliminator, Magnolia & Lily
43.0
SECTION 14: Transport information
14.1 UN-Number
ADR, ADN, IMDG, IATA
Void
14.2 UN proper shipping name
ADR, ADN, IMDG, IATA
Void
ADR, ADN, IMDG, IATA
Class
Void
14.4 Packing group
ADR, IMDG, IATA
Void
14.5 Environmental hazards:
Marine pollutant:
No
14.7 Transport in bulk according to Ann
ex II of
Marpol and the IBC Code
Not applicable.
SECTION 15: Regulatory information
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
(Contd. of page 6)
Contact manufacturer for recycling information.
Uncleaned packaging:
Recommendation:
Disposal must be made according to official regulations.
Packaging may be reused or recycled after cleaning.
14.3 Transport hazard class(es)
14.6 Special precautions for user
UN "Model Regulation":
Not applicable.
Void
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH Regulation 1907/2006/EC
Regulation (EU) 2015/830
CLP Regulation 1272/2008/EC
Constituents of the mixture that fall within the scope of REACH Regulation 1907/2006/EC, have been (pre)registered.
Directive 98/24/EC on the protection of health and safety of workers from the risks related to chemicals agents at
work.
Council Directive 94/33/EC on the protection of young people at work, as ammended.
Directive 92/85/EEC on the introduction of measures to encourage improvements in the safety and health at work of
pregnant workers and workers who have recently given birth or are breastfeeding, as ammended
Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.
(Contd. on page 8)
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 03.09.2018
Version number 1
Revision: 03.09.2018
Trade name: ECOSBreeze Fabric and Carpet Odor Eliminator, Magnolia & Lily
43.0
SECTION 16: Other information
complying with Regulation 1907/2006/EC (REACH Regulation), EU
(Contd. of page 7)
REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
National regulations:
Other regulations, limitations and prohibitive regulations
Substances of very high concern (SVHC) according to REACH, Article 57
It doesn't contain substances of very high concern (SVHC).
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Training hints Suitable training on safety in handling, storing and converting the product should be given to the employees based on all the existing information.
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
GB
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