43.0
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification
Eye
2.2
Labelling
The
Hazard pictograms:
GHS07
Signal word: Warning
(Contd. on page 2)
GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Page 1/8
Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Printing date 28.07.2016 Version number 1 Revision: 28.07.2016
2015/830 and Regulation No 1272/2008/EC (CLP)
1.1 Product identifier
Trade name: ECOS Dishmate Free & Clear
Description / Product Code: 9721
Registration number: Substances contained in the mixture have already (pre)-registered by the suppliers.
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
Application of the substance / the mixture:
Cleaning Product/ Detergent
For Hand Dishwashing
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Venus Labs/dba Earth Friendly Products
111. S Rohlwing Rd Addison, IL 60101
Phone: 800-451-9304
Chemtrec: 800-424-9300
1.4 Emergency telephone number:
Emergency telephone number: 112
according to Regulation EC No 1272/2008 CLP:
GHS07
Irrit. 2 H319 Causes serious eye irritation.
Label elements
according to Regulation EC No 1272/2008 CLP:
product is classified and labelled according to the CLP regulation.
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 28.07.2016
Version number 1
Revision: 28.07.2016
Trade name: ECOS Dishmate Free & Clear
(Contd. of page 1)
43.0
Hazard statements:
H319
Precautionary
P102
P102
P264
P305+P351+P338
P337+P313
Additional information: National Poisoning Centre
2.3 Other hazards
Results
PBT:
vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
Regulation (EC) No 648/2004 on detergents / Labelling for contents
anionic surfactants, non-ionic surfactants, amphoteric surfactants
< 5%
preservation agents (PHENOXYETHANOL)
Ingredients according Regulation (EU) 830/2015:
CAS: 97375-27-4
Sodium Coco-Sulfate
2.5-<10%
Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319
CAS: 68155-09-9
Cocamidopropylamine oxide
0.1-≤2.5%
Eye Dam. 1, H318; Acute Tox. 4, H302; Skin Irrit. 2, H315
CAS: 1643-20-5
dodecyldimethylamine oxide
0.1-≤2.5%
Eye Dam. 1, H318; Aquatic Acute 1, H400; Aquatic Chronic 2, H411;
SECTION 4: First aid measures
4.1 Description of first aid measures
General
Take
Seek
After
After
After
Rinse
Avoid strong water jet-risk of cornea damage, consult a doctor.
(Contd. on page 3)
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Causes serious eye irritation.
statements
Keep out of reach of children.
Keep out of reach of children.
Wash thoroughly after handling.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
of PBT and vPvB assessment
Not applicable.
*
3.2 Chemical characterisation: Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
EC number: 306-683-4
EINECS: 268-938-5
EINECS: 216-700-6
Acute Tox. 4, H302; Skin Irrit. 2, H315
information:
affected persons out into the fresh air.
immediate medical advice.
inhalation: Seek medical treatment in case of complaints.
skin contact: In case of skin irritation, consult a physician.
eye contact:
opened eye for at least 15 minutes under running water.
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 28.07.2016
Version number 1
Revision: 28.07.2016
Trade name: ECOS Dishmate Free & Clear
(Contd. of page 2)
43.0
SECTION 5: Firefighting measures
SECTION 6: Accidental release measures
SECTION 7: Handling and storage
7.1 Precautions for safe handling Avoid contact with skin, eyes and clothing.
Information
7.2
Storage:
Requirements
Information
Further
7.3 Specific end use(s) No further relevant information available.
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
After swallowing:
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Seek immediate medical advice.
Never give anything by mouth to an unconscious person.
4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5.1 Extinguishing media
Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray.
5.2 Special hazards arising from the substance or mixture No further relevant information available.
5.3 Advice for firefighters
Protective equipment: Self contained breathing apparatus and full protective clothing must be worn in case of fire.
Additional information Collect contaminated fire fighting water separately. It must not enter the sewage system.
6.1 Personal precautions, protective equipment and emergency procedures:
Wear protective equipment. Keep unprotected persons away.
6.1.2 For emergency responders Wear protective equipment. Keep unprotected persons away.
6.2 Environmental precautions: No special measures required.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust, silica gel).
6.4 Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
about fire - and explosion protection: No special measures required.
Conditions for safe storage, including any incompatibilities
Store in cool, dry conditions in well sealed receptacles.
to be met by storerooms and receptacles: Store in a cool location.
about storage in one common storage facility: Not required.
information about storage conditions: Keep container tightly sealed.
(Contd. on page 4)
Page 4/8
Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 28.07.2016
Version number 1
Revision: 28.07.2016
Trade name: ECOS Dishmate Free & Clear
43.0
SECTION 9: Physical and chemical properties
(Contd. on page 5)
GB
SECTION 8: Exposure controls/personal protection
complying with Regulation 1907/2006/EC (REACH Regulation), EU
(Contd. of page 3)
*
8.1 Control parameters Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the
workplace.
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls Personal protective equipment
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Respiratory protection: Not required. Protection of hands: Not required under normal conditions of use. Penetration time of glove material
The determined penetration times according to EN 374 part III are not performed under practical conditions.
Therefore a maximum wearing time, which corresponds to 50% of the penetration time, is recommended.
Eye protection: In processing and repackaging where is possible the eye-contact wear safety glasses.
Body protection: Not required under normal conditions of use.
*
9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Colour: According to product specification
Odour: Odourless
Odour threshold: Not determined
pH value at 20 °C: 8.01-8.7
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Flash point: Not determined
Not Flammable
Flammability (solid, gaseous): Not applicable
Auto-ignition temperature: Not determined
Decomposition temperature: Not determined
Self-igniting: Product is not selfigniting.
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 28.07.2016
Version number 1
Revision: 28.07.2016
Trade name: ECOS Dishmate Free & Clear
(Contd. of page 4)
43.0
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity Based on available data, the classificat io n criteria are not met.
Skin corrosion/irritation Based on available data, the classification cr iter ia are not met.
Serious
Causes serious eye irritation.
(Contd. on page 6)
GB
SECTION 10: Stability and reactivity
LD/LC50 values relevant for classification:
ATE (Acute Toxicity Estimates)
Oral
LD50
11390 mg/kg
1643-20-5 dodecyldimethylamine oxide
Oral
LD50
2700 mg/kg (rat)
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined
Upper: Not determined
Oxidising properties Not considered as oxidising.
Vapour pressure: Not determined
Density: Not determined
Relative density Not determined
Vapour density Not determined
Evaporation rate Not determined
Solubility in / Miscibility with
water:
Fully miscible
Partition coefficient (n-octanol/water): Not determined
Viscosity:
Dynamic: Not determined
Kinematic: Not determined
9.2 Other information No further relevant information available.
10.1 Reactivity Stable under normal conditions
10.2 Chemical stability Material is stable under normal conditions.
Thermal decomposition / conditions to be avoided Stable at environment temperature.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials No further relevant information available.
10.6 Hazardous decomposition products No dangerous decomposition products known.
eye damage/irritation
Page 6/8
Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 28.07.2016
Version number 1
Revision: 28.07.2016
Trade name: ECOS Dishmate Free & Clear
(Contd. of page 5)
43.0
SECTION 12: Ecological information
SECTION 14: Transport information
(Contd. on page 7)
GB
SECTION 13: Disposal considerations
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classific a tion c rite ria are not met.
STOT-single exposure Based on available data, the classification crit eria are not met.
STOT-repeated exposure Based on available data, the classification c riteria are not met.
Aspiration hazard Based on available data, the classific ation cr ite r ia are not met.
12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.
13.1 Waste treatment methods
Recommendation
Dispose according to National Regulations.
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Contact manufacturer for recycling information.
Uncleaned packaging:
Recommendation:
Disposal must be made according to official regulations.
Packaging may be reused or recycled after cleaning.
14.1 UN-Number Void
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 28.07.2016
Version number 1
Revision: 28.07.2016
Trade name: ECOS Dishmate Free & Clear
(Contd. of page 6)
43.0
14.7 Transport in bulk according to Ann
ex II of
Marpol and the IBC Code
Not applicable.
SECTION 16: Other information
GB
SECTION 15: Regulatory information
complying with Regulation 1907/2006/EC (REACH Regulation), EU
14.2 UN proper shipping name
14.3 Transport hazard class(es)
14.4 Packing group
14.5 Environmental hazards:
14.6 Special precautions for user
Void
Void
Void
Not applicable.
Not applicable.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Detergent Regulation No. 648/2004/EC CLP Regulation No. 1272/2008/EC Regulation (EU) 2015/830 Regulation REACH (EC) 1907/2006 REACH Regulation 1907/2006/EC Regulation (EU) 2015/830 CLP Regulation 1272/2008/EC Constituents of the mixture that fall within the scope of REACH Regulation 1907/2006/EC, have been (pre)registered. Directive 98/24/EC on the protection of health and safety of workers from the risks related to chemicals agents at work. Council Directive 94/33/EC on the protection of young people at work, as ammended. Directive 92/85/EEC on the introduction of measures to encourage improvements in the safety and health at work of pregnant workers and workers who have recently given birth or are breastfeeding, as ammended
Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.
REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
National regulations:
Other regulations, limitations and prohibitive regulations
Substances of very high concern (SVHC) according to REACH, Article 57
It doesn't contain substances of very high concern (SVHC).
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
(Contd. on page 8)
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 28.07.2016
Version number 1
Revision: 28.07.2016
Trade name: ECOS Dishmate Free & Clear
(Contd. of page 7)
43.0
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Relevant phrases
H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. Training hints Suitable training on safety in handling, storing and converting the product should be given to the employees based on all the existing information.
Abbreviations and acronyms:
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 4: Acute toxicity – Category 4
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
* Data compared to the previous version altered.
GB
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