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SAFETY DATA SHEET
Skin sensitization
Category 1
Issuing Date No data available Revision Date 25-Nov-2014 Revision Number 1
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
Product identifier
Product Name (PL9448) Heavy Duty Floor Cleaner Concentrate
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use General Purpose Cleaner - Non-aerosol
Uses advised against No information available
Details of the supplier of the safety data sheet
Supplier Name VENUS LABORATORIES
Supplier Address 111 S ROHLWING ROAD
Supplier Phone Number Phone: 800-592-1900
Emergency telephone number Chemtrec: 800-424-9300
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
1.
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
ADDISON
IL
60101
US
2.
HAZARDS IDENTIFICATION
Category 1
GHS Label elements, including precautionary statements
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1192482 – (PL 9448) Heavy Duty Floor Cleaner Concentrate
Revision Date 25-Nov-2014
Signal word
Warning
Emergency Overview
Hazard Statements
May cause skin irritation
May cause eye damage
Appearance Clear to light yellow Physical State Liquid Odor Citrus
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Remove the contaminated clothing and wash.
Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label)
Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If irritation persists consult a doctor/physician.
Skin IF ON SKIN: N o adverse rea ction ex pected. Wash with soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention
Precautionary Statements - Storage Store locked up
Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity
26.36% of the mixture consists of ingredient(s) of unknown toxicity
Other information
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1192482 – (PL 9448) Heavy Duty Floor Cleaner Concentrate
Revision Date 25-Nov-2014
Chemical Name
CAS No.
Weight-%
Trade Secret
Cocamidopropylamine oxide
68155-09-9
10 - 30
*
Cocamide dea
68603-42-9
5 - 10
*
Ethyl alcohol
64-17-5
1 - 5
*
Harmful to aquatic life with long lasting effects Interactions with Other Chemicals
Use of alcoholic beverages may enhance toxic effects.
3.
.
COMPOSITION/INFORMATION ON INGREDIENTS
First aid measures
*The exact percentage (concentration) of composition has been withheld as a trade secret
4.
FIRST AID MEASURES
General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical
attention is required.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and If
irritation persists consult a doctor/physician.
Skin Contact
Wash off immediately with soap and plenty of water for at least 15 minutes. May
cause an allergic skin reaction. In the case of skin irritation or allergic reactions
see a physician.
Inhalation
Remove to fresh air. Get medical attention immediately if symptoms occur.
Ingestion
Rinse mouth immediately and drink plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
Self-protection of the first aider
Avoid contact with skin, eyes or clothing. Use personal protective equipment as
required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Effects
Indication of any immediate medical attention and special treatment needed
Burning sensation.
Notes to Physician
Treat symptomatically.
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1192482 – (PL 9448) Heavy Duty Floor Cleaner Concentrate
Revision Date 25-Nov-2014
5.
FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical
No information available.
Uniform Fire Code Irritant: Liquid
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge No.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6.
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental Precautions
Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
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1192482 – (PL 9448) Heavy Duty Floor Cleaner Concentrate
Revision Date 25-Nov-2014
Chemical Name
ACGIH TLV
OSHA PEL
NIOSH IDLH
7.
Precautions for safe handling
HANDLING AND STORAGE
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Take off
contaminated clothing and wash before reuse.
Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
Keep out of the reach of children.
Incompatible Products Strong acids. Strong oxidizing agents. Strong bases.
8.
Control parameters
EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Ethyl alcohol
64-17-5
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health
STEL: 1000 ppm
TWA: 1000 ppm
TWA: 1900 mg/m
(vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mg/m
3
IDLH: 3300 ppm 10% LEL
TWA: 1000 ppm
3
TWA: 1900 mg/m
3
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992) See section 15 for national exposure control parameters
Appropriate engineering controls
Engineering Measures Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection Tight sealing safety goggles.
Skin and Body Protection Wear protective gloves and protective clothing. Long sleeved clothing. Impervious gloves.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Avoid contact with skin, eyes or clothing. Wear suitable
gloves and eye/face protection. Wash hands before breaks and immediately after handling
the product.
9.
PHYSICAL AND CHEMICAL PROPERTIES
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1192482 – (PL 9448) Heavy Duty Floor Cleaner Concentrate
Revision Date 25-Nov-2014
Physical State
Liquid
Appearance
Clear to light yellow
Odor
Citrus
Flammability (solid, gas)
No data available
None known
Flammability Limit in Air
Upper flammability limit
Vapor pressure
No data available
Vapor density
Solubility in other solvents
No data available
No data available
None known
None known
Partition coefficient: n-octanol/waterNo data available None known
Autoignition temperature
No data available
None known
Particle Size Distribution
Physical and Chemical Properties
Color
Propert
y pH
Melting / freezing point
Boiling point / boiling range
Flash Point
Evaporation Rate
Lower flammability limit
Specific Gravity
Water Solubility
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing Properties
Other Information
Softening Point
VOC Content (%)
Particle Size
No information available
Values
8
No data available
212°F
94° C / 201° F
No data available
No data available
No data available
No data available
Soluble in water
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
Odor Threshold
Remarks/ Method
None known
None known
None known
None known
None known
No information available
None known
None known
None known
None known
None known
None known
Reactivity No data available. Chemical stability
Stable under recommended storage conditions. Possibility of Hazardous Reactions
None under normal processing. Hazardous Polymerization
Hazardous polymerization does not occur. Conditions to avoid
None known based on information supplied. Incompatible materials
Strong acids. Strong oxidizing agents. Strong bases. Hazardous Decomposition Products
Carbon oxides.
10.
STABILITY AND REACTIVITY
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1192482 – (PL 9448) Heavy Duty Floor Cleaner Concentrate
Revision Date 25-Nov-2014
Chemical Name
Oral LD50
Dermal LD50
Inhalation LC50
64-17-5
-
Chemical Name
ACGIH
IARC
NTP
OSHA
Ethyl alcohol 64-17-
A3
Group 1
Known
X
11.
TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available. May cause irritation of
respiratory tract.
Eye Contact Specific test data for the substance or mixture is not available. Expected to be an irritant
based on components. May Cause Eye Irritation. May cause burns.
Skin Contact Specific test data for the substance or mixture is not available. Not expected to be a
skin irritant based on components. Prolonged contact may cause redness and irritation.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea.
Component Information
Ethyl alcohol
Information on toxicological effects
-
= 124.7 mg/L ( Rat ) 4 h
Symptoms Erythema (skin redness). May cause redness and tearing of the eyes. May cause
blindness. Burning.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Ethanol has been shown to be carcinogenic in long-term studies only when consumed as
alcoholic beverage.
Cocamide dea 68603-42-
9
5
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
Group 2B - Possibly Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Group 2B
X
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1192482 – (PL 9448) Heavy Duty Floor Cleaner Concentrate
Revision Date 25-Nov-2014
Microorganisms
Flea)
Cocamide dea
96h LC50: = 3.6 mg/L
EC50 = 6000 mg/L 16 h
24h EC50: = 4.2 mg/L
Ethyl alcohol
96h LC50: > 100 mg/L
EC50 = 34634 mg/L 30 min
48h LC50: 9268 - 14221
Chemical Name
Log Pow
5
Reproductive Toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
12.
ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic life with long lasting effects.
Chemical Name
Toxicity to Algae
Toxicity to Fish
Toxicity to
Daphnia Magna (Water
68603-42-9
64-17-5
Persistence and Degradability No information available.
Bioaccumulation
Ethyl alcohol 64-17-
Other adverse effects
No information available.
(Brachydanio rerio)
(Pimephales promelas) 96h
LC50: 13400 - 15100 mg/L
(Pimephales promelas) 96h
LC50: 12.0 - 16.0 mL/L
(Oncorhynchus mykiss)
EC50 = 35470 mg/L 5 min
-0.32
mg/L 48h EC50: = 2 mg/L
24h EC50: = 10800 mg/L
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Revision Date 25-Nov-2014
Chemical Name
California Hazardous Waste
Ethyl alcohol 64-17-
5
Toxic
Ignitable
13.
Waste treatment methods
DISPOSAL CONSIDERATIONS
Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Contaminated Packaging Dispose of contents/containers in accordance with local regulations.
California Hazardous Waste Codes 561
This product contains one or more substances that are listed with the State of California as a hazardous waste.
14.
TRANSPORT INFORMATION
DOT NOT REGULATED
Proper Shipping Name NON REGULATED
Hazard Class N/A
TDG Not regulated
MEX Not regulated
ICAO Not regulated
IATA Not regulated
Proper Shipping Name NON REGULATED
Hazard Class N/A
IMDG/IMO Not regulated
Hazard Class N/A
RID Not regulated
ADR Not regulated
ADN Not regulated
International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
15.
REGULATORY INFORMATION
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
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1192482 – (PL 9448) Heavy Duty Floor Cleaner Concentrate
Revision Date 25-Nov-2014
Component
Carcinogen Status
Exposure Limits
Ethyl alcohol
Mexico: TWA 1000 ppm
Chemical Name
California Proposition 65
Cocamide dea - 68603-42-9
Carcinogen
Developmental
Chemical Name
New Jersey
Massachusetts
Pennsylvania
Rhode Island
Illinois
Cocamide dea
X
Ethyl alcohol
X
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals. Ethyl alcohol is only a considered a Proposition 65 developmental
hazard when it is ingested as an alcoholic beverage.
Ethyl alcohol - 64-17-5
U.S. State Right-to-Know Regulations .
68603-42-9
International Regulations
64-17-5
Mexico
National occupational exposure limits
Mexico - Occupational Exposure Limits - Carcinogens
64-17-5 ( 1 - 5 )
Canada
WHMIS Hazard Class
D2A - Very toxic materials
D2B - Toxic materials
Carcinogen
16.
OTHER INFORMATION
Mexico: TWA 1900 mg/m
3
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1192482 – (PL 9448) Heavy Duty Floor Cleaner Concentrate
Revision Date 25-Nov-2014
NFPA Health Hazards 1 Flammability 1 Instability 0 Physical and
Chemical Hazards -
HMIS Health Hazards 1 Flammability 1
Physical Hazard 0 Personal Protection
X
Revision Date
Revision Note
25-Nov-2014
No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
End of Safety Data Sheet
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