SAFETY DATA SHEET
Issuing Date No data available Revision Date 02-Feb-2015 Revision Number 1
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name Wave Industrial Free Clear (9440)
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Machine dishwashing products
Uses advised against No information available
Details of the supplier of the safety data sheet
Supplier Name VENUS LABORATORIES dba Earth Friendly Products
Supplier Address 111 S ROHLWING ROAD
ADDISON
IL
60101
US
Supplier Phone Number Phone:
1-800-424-9300 Fax:
630-595-1900
Supplier Phone Number Phone: 800-592-1900
Emergency telephone number Chemtrec: 800-424-9300
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Respiratory sensitization Category 1
Skin sensitization Category 1
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Danger
Hazard Statements
May cause allergy
May cause an allergic skin reaction
Appearance Clear, colorless to yellow
Physical State Liquid Odor None
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Remove the contaminated clothing and wash.
Precautionary Statements - Response
Specific treatment (see supplemental first aid instructions on this label)
Skin
IF ON SKIN: No adverse reaction expected. Wash with soap and water
Take off contaminated clothing and wash before reuse
If skin irritation or rash occurs: Get medical advice/attention
Inhalation
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing
If experiencing respiratory symptoms: Call a or doctor/physician
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
6.75% of the mixture consists of ingredient(s) of unknown toxicity
Other information
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons
Interactions with Other Chemicals
No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-% Trad e Secret
Sodium citrate 68-04-2 5 - 10 *
Citric acid 77-92-9 1 - 5 *
Amylase, .alpha.- 9000-90-2 0.1 - 1 *
Methylisothiazolinone 2682-20-4 < 0.1 *
*The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
First aid measures
General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical
attention is
required.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and
If irritation persists consult a doctor/physician.
Skin Contact
Wash off immediately with soap and plenty of water for at least 15 minutes. May
cause an allergic skin reaction. In the case of skin irritation or allergic reactions
see a physician.
Inhalation
Remove to fresh air. Get medical attention immediately if symptoms occur.
Ingestion
Rinse mouth immediately and drink plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
.
Self-protection of the first aider
Avoid contact with skin, eyes or clothing. Use personal protective equipment as
required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and Effects
May cause allergy or asthma symptoms or breathing difficulties if inhaled. Coughing and/ or wheezing.
Itching. Rashes. Hives.
Indication of any immediate medical attention and special treatment needed
Notes to Physician
May cause sensitization of susceptible persons. Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
Product is or contains a sensitizer. May cause sensitization by inhalation and skin contact.
Uniform Fire Code Sensitizer: Liquid
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge No.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required. Evacuate personnel to safe areas. Keep people away
from and upwind of spill/leak.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental Precautions
Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
Keep out of the reach of children.
Incompatible Products None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies
Appropriate engineering controls
Engineering Measures Showers
Eyewash stations
Ventil atio n systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection Wear safety glasses with side shields (or goggles).
Skin and Body Protection Wear protective gloves and protective clothing.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or
smoke when using this product. Take off contaminated clothing and wash before reuse.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State Liquid
Appearance Clear, colorless to yellow Odor None
Color No information available Odor Threshold No information available
Property Values Remarks Method
pH 5.00 None known
Melting / freezing point No data available None known
Boiling point / boiling range
212°F None known
Flash Point Evaporation Rate
Flammability (solid, gas)
5001 C / 9034 F
No data available No data
available
None known None known None known
Flammability Limit in Air
Upper flammability limit
Lower flammability limit
Vapor pressure
No data available
No data available No data
available
None known
Vapor density
Specific Gravity Water
Solubility
Solubility in other solvents
No data available
1.00
Soluble in water No data
available
None known
None known None known None known
Partition coefficient: n-octanol/waterNo data available None known
Autoignition temperature
Decomposition temperature
Kinematic viscosity Dynamic
viscosity Explosive properties
Oxidizing Properties
No data available
No data available No data
available No data available
No data available No data
available
None known
None known None known None known
Other Information
Softening Point VOC Content
(%) Particle Size
No data available No data
available No data available
Particle Size Distribution
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
None known based on information supplied.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available. No irritation expected.
Eye Contact Specific test data for the substance or mixture is not available.
Skin Contact Specific test data for the substance or mixture is not available. Not expected to be a skin
irritant based on components. Prolonged contact may cause redness and irritation.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea.
Component Information
Information on toxicological effects
Symptoms Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain, or flushing.
Coughing and/ or wheezing. Itching. Rashes. Hives.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization May cause sensitization of susceptible persons. May cause sensitization by skin contact.
May cause sensitization by inhalation.
Mutagenic Effects No information available.
Carcinogenicity Contains no ingredient listed as a carcinogen.
Reproductive Toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Chronic Toxicity Prolonged exposure may cause chronic effects. Repeated contact may cause allergic
reactions in very susceptible persons.
Target Organ Effects Respiratory system. Eyes. Skin.
Aspiration Hazard No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
7,143.00 mg/kg
12. ECOLOGICAL INFORMATION
Ecotoxicity
The environmental impact of this product has not been fully investigated.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
Sodium citrate
68-04-2
96h EC50: 18000 32000
mg/L (Chlorella vulgaris)
96h LC50: 18000 32000
mg/L (Poecilia reticulata)
EC50 1800 - 3200 mg/L 8 h48h EC50: 5600 - 10000
mg/L
Citric acid
77-92-9
96h LC50: = 1516 mg/L
(Lepomis macrochirus)
72h EC50: = 120 mg/L
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
Citric acid 77-92-9 -1.72
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal methods
This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a
hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this
material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a
hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.
Contaminated Packaging Dispose of contents/containers in accordance with local regulations.
California Hazardous Waste Codes
561
14. TRANSPORT INFORMATION
DOT NOT REGULATED
Proper Shipping Name NON REGULATED
Hazard Class N/A
TDG Not regulated
MEX Not regulated
ICAO Not regulated
IATA Not regulated
Proper Shipping Name NON REGULATED
Hazard Class N/A
IMDG/IMO Not regulated
Hazard Class N/A
RID Not regulated
ADR Not regulated
ADN Not regulated
International Inventories
15. REGULATORY INFORMATION
1.
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs Extremely Hazardous
Substances RQs
RQ
Citric acid 77-92-9 RQ Section number 180.950
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
.
Chemical Name New Jersey MassachusettsPennsylvaniaRhode
Island
Illinois
Phenoxyethanol 122-99-6 X X X X
International Regulations
Canada
WHMIS Hazard Class
D2B - Toxic materials
16. OTHER INFORMATION
1.
NFPA Health Hazards 1 Flammability 0 Instability 0 Physical and
Chemical Hazards -
HMIS Health Hazards 1 Flammability 0
Revision Date
02-Feb-2015
Revision Note
No information available
Physical Hazard 0 Personal Protection
X
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
End of Safety Data Sheet
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