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SAFETY DATA SHEET
Issuing Date No data available Revision Date 02-Feb-2015 Revision Number 1
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name UniTab Plus Blue (3626)
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Toilet/Urinal Care Product - Non-aerosol
Uses advised against No information available
Details of the supplier of the safety data sheet
Supplier Name VENUS LABORATORIES dba Earth Friendly Products
Supplier Address 111 S ROHLWING ROAD
ADDISON
IL
60101
US
Supplier Phone Number Phone: 800-592-1900
Emergency telephone number Chemtrec: 800-424-9300
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin irritation Category 1
Eye irritation Category 1
GHS Label elements, including precautionary statements
Signal word Warning
Emergency Overview
Hazard Statements
May cause skin irritation
May cause eye irritation
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Appearance Blue
Physical State Solid Odor N/A
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Remove the contaminated clothing and wash.
Precautionary Statements - Response
Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If irritation persists consult a doctor/physician.
Skin
IF ON SKIN: No adverse reaction expected. Wash with soap and water
Take off contaminated clothing and wash before reuse
If skin irritation or rash occurs: Get medical advice/attention
Ingestion
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
25.8391% of the mixture consists of ingredient(s) of unknown toxicity
Other information
Toxic to aquatic life
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons
.
3. COMPOSITION/INFORMATION ON INGREDIENTS
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.
Chemical Name CAS No Weight-% Trad e Secret
Ethylene oxide-Nonylphenol polymer 9016-45-9 40 - 70 *
Maize starch 9005-25-8 10 - 30 *
Phosphoric acid 7664-38-2 3 - 7 *
Subtilisins (proteolytic enzymes) 9014-01-1 1 - 5 *
Didecyldimethylammonium chloride 7173-51-5 1 - 5 *
Ethanol 64-17-5 0.1 - 1 *
*The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
First aid measures
General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical
attention is required.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and
If irritation persists consult a doctor/physician.
Skin Contact
Wash off immediately with soap and plenty of water for at least 15 minutes. May
cause an allergic skin reaction. In the case of skin irritation or allergic reactions
see a physician.
Inhalation
Remove to fresh air. Get medical attention immediately if symptoms occur.
Ingestion
Rinse mouth immediately and drink plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
Self-protection of the first aider
Avoid contact with skin, eyes or clothing. Use personal protective equipment as
required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and Effects
Burning sensation. Itching. Rashes. Hives.
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically. May cause sensitization of susceptible persons.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
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CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases
and vapors. Product is or contains a sensitizer. May cause sensitization by inhalation and skin contact. In the event of fire and/or
explosion do not breathe fumes.
Uniform Fire Code Sensitizer: Solid
Irritant: Solid
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge No.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Wear self contained breathing apparatus for fire fighting if necessary.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required.
.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental Precautions
Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers. Use personal protective equipment as
required. Cover powder spill with plastic sheet or tarp to minimize spreading and keep
powder dry. Avoid generation of dust. Clean contaminated surface thoroughly. Soak up with
inert absorbent material. Dam up. Sweep up and shovel into suitable containers for
disposal. After cleaning, flush away traces with water.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
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Keep out of the reach of children.
Incompatible Products None known.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Maize starch 9005-25-8 TWA: 10 mg/m
3
TWA: 15 mg/m
3
total dust
TWA: 5 mg/m
3
respirable
fraction (vacated) TWA: 15 mg/
m
3
total
dust
(vacated) TWA: 5 mg/m
3
respirable fraction
TWA: 10 mg/m
3
total dust
TWA: 5 mg/m
3
respirable
dust
Phosphoric acid 7664-38-2 STEL: 3 mg/m
3
TWA: 1 mg/m
3
TWA: 1 mg/m
3
(vacated) TWA: 1 mg/m
3
(vacated) STEL: 3 mg/m
3
IDLH: 1000 mg/m
3
TWA: 1 mg/m
3
STEL: 3 mg/m
3
Subtilisins (proteolytic enzymes)
9014-01-1
Ceiling: 0.00006 mg/m3 as
crystalline active enzyme
(vacated) STEL: 0.00006 mg/
m3 60 min
STEL: 0.00006 mg/m
3
60 min
Subtilisins
Ethanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm
TWA: 1900 mg/m
3
(vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mg/m
3
IDLH: 3300 ppm 10% LEL
TWA: 1000 ppm
TWA: 1900 mg/m
3
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health NIOSH IDLH
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2 d 962
(11th Cir., 1992) See section 15 for national exposure control parameters
Appropriate engineering controls
Engineering Measures Showers
Eyewash stations
Ventil atio n systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection Tight sealing safety goggles. Wear safety glasses with side shields (or goggles).
Skin and Body Protection No special protective equipment required. Protective gloves.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Take off
contaminated clothing and wash before reuse. Avoid contact with skin, eyes or clothing.
Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this
product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State Solid
Appearance Blue Odor N/A
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Color No information available Odor Threshold No information available
Property Values Remarks Method
pH No data available None known
Melting / freezing point No data available None known
Boiling point / boiling range No data available None known
Flash Point No data available None known
Evaporation Rate No data available None known
Flammability (solid, gas) No data available None known
Flammability Limit in Air
Upper flammability limit No data available
Lower flammability limit No data available
Vapor pressure
No data available None known
Vapor density Specific Gravity
Water Solubility
Solubility in other solvents
No data available No data
available Soluble in water
No data available
None known None known None known None
known
Partition coefficient: n-octanol/waterNo data available None known
Autoignition temperature No data available None known
Decomposition temperature
Kinematic viscosity Dynamic
viscosity Explosive properties
Oxidizing Properties
No data available
No data available No data
available No data
available No data
available
None known
None known None known
Other Information
Softening Point VOC Content
(%) Particle Size
No data available No data
available No data
available
Particle Size Distribution
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
None known.
Incompatible materials
None known.
Hazardous Decomposition Products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information Product does not present an acute toxicity hazard based on known or supplied information.
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Inhalation Specific test data for the substance or mixture is not available. No irritation expected.
Eye Contact Specific test data for the substance or mixture is not available. Not expected to be an irritant
based on components. May Cause Eye Irritation. May cause burns.
Skin Contact Specific test data for the substance or mixture is not available. Not expected to be a
skin irritant based on components. Prolonged contact may cause redness and
irritation.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause irritation
to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting
and diarrhea
Component Information
Information on toxicological effects
Symptoms Erythema (skin redness). Burning. May cause blindness. Coughing and/ or wheezing.
Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain, or flushing.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA
Ethanol 64-17-5 A3 Group 1 Known X
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive Toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Chronic Toxicity No known effect based on information supplied. Repeated contact may cause allergic
reactions in very susceptible persons. Avoid repeated exposure. Ethanol has been shown
to be a reproductive toxin only when consumed as an alcoholic beverage. Ethanol has been
shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage.
Target Organ Effects Eyes.Skin.
Aspiration Hazard No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
5,072.00 mg/kg
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12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxic to aquatic organisms.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
Phosphoric acid
7664-38-2
96h LC50: 3 - 3.5 mg/L
(Gambusia affinis)
12h EC50: = 4.6 mg/L
Ethanol 64-17-5 96h LC50: > 100 mg/L
(Pimephales promelas)
96h LC50: 13400 - 15100
mg/L
(Pimephales promelas)
96h LC50: 12.0 - 16.0
mL/L
(Oncorhynchus mykiss)
EC50 = 34634 mg/L 30
min
EC50 = 35470 mg/L 5
min
48h LC50: 9268 14221
mg/L 48h EC50: = 2 mg/
L 24h EC50: = 10800
mg/L
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
Ethanol 64-17-5 -0.32
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Contaminated Packaging Dispose of contents/containers in accordance with local regulations.
California Hazardous Waste Codes 331
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste
Phosphoric acid 7664-38-2 Corrosive
Ethanol 64-17-5 Toxic Ignitable
14. TRANSPORT INFORMATION
DOT NOT REGULATED
Proper Shipping Name NON REGULATED
Hazard Class N/A
TDG Not regulated
MEX Not regulated
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ICAO Not regulated
IATA Not regulated
Proper Shipping Name NON REGULATED
Hazard Class N/A
IMDG/IMO Not regulated
Hazard Class N/A
RID Not regulated
ADR Not regulated
ADN Not regulated
International Inventories
15. REGULATORY INFORMATION
1.
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Chemical Name CWA - Reportable
Quantities
CWA - Toxi c Pollutants CWA - Priority
Pollutants
CWA - Hazardous
Substances
Phosphoric acid
7664-38-2
5000 lb X
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs Extremely Hazardous
Substances RQs
RQ
Phosphoric acid
7664-38-2
5000 lb RQ 5000 lb final RQ RQ
2270 kg final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals. Ethyl alcohol is only a considered a Proposition 65 developmental
hazard when it is ingested as an alcoholic beverage.
Chemical Name California Proposition 65
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Ethanol - 64-17-5 Carcinogen Developmental
U.S. State Right-to-Know Regulations
.
Chemical Name New Jersey MassachusettsPennsylvaniaRhode
Island
Illinois
Maize starch 9005-25-8 X X
Phosphoric acid 7664-38-2 X X X X
Ethanol 64-17-5 X
International Regulations
Mexico
National occupational exposure limits
Component Carcinogen Status Exposure Limits
Phosphoric acid
7664-38-2 ( 3 - 7 )
Mexico: TWA 1 mg/m
3
Mexico: STEL 3 mg/m
3
Ethanol
64-17-5 ( 0.1 - 1 )
Mexico: TWA 1000 ppm
Mexico: TWA 1900 mg/m
3
Mexico - Occupational Exposure Limits - Carcinogens
Canada
WHMIS Hazard Class
D2A - Very toxic materials
16. OTHER INFORMATION
NFPA Health Hazards 1 Flammability 0 Instability 0 Physical and
Chemical Hazards -
HMIS Health Hazards 1 Flammability 0
Revision Date
02-Feb-2015
Revision Note
No information available
Physical Hazard 0 Personal Protection
X
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
End of Safety Data Sheet
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