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SAFETY DATA SHEET
Skin irritation
Category 1
Eye irritation
Category 1
Issuing Date No data available Revision Date 02-Feb-2015 Revision Number 1
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
Product identifier
Product Name (PL 3625) Unitab Round Pink Spice
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Toilet/Urinal Care Product - Non-aerosol
Uses advised against No information available
Details of the supplier of the safety data sheet
Supplier Name W.W Grainger
Supplier Address 100 Grainger Parkway
Lake Forest
Supplier Phone Number Phone: 800-592-1900 Emergency telephone number Chemtrec: 800-424-9300
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
1.
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
IL
600455201
US
2.
HAZARDS IDENTIFICATION
GHS Label elements, including precautionary statements
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1176974 – (PL 3625) Unitab Round Pink Spice
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Signal word
Hazard Statements
May cause skin irritation
May cause eye irritation
Warning
Emergency Overview
Appearance Pink Physical State Solid Odor Spice
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Remove the contaminated clothing and wash.
Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label)
Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If irritation persists consult a doctor/physician.
Skin IF ON SKIN: N o adverse rea ction ex pected. Wash with soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention
Ingestion IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed
Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity
25.8391% of the mixture consists of ingredient(s) of unknown toxicity
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Chemical Name
CAS No
Weight-%
Trade Secret
Ethylene oxide-Nonylphenol polymer
9016-45-9
40 - 70
*
Maize starch
9005-25-8
10 - 30
*
Phosphoric acid
7664-38-2
3 - 7
*
Subtilisins (proteolytic enzymes)
9014-01-1
1 - 5
*
Didecyldimethylammonium chloride
7173-51-5
1 - 5
*
Ethanol
64-17-5
0.1 - 1
*
Other information Toxic to aquatic life
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons
.
3.
.
COMPOSITION/INFORMATION ON INGREDIENTS
First aid measures
*The exact percentage (concentration) of composition has been withheld as a trade secret
General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical
attention is required.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and
If irritation persists consult a doctor/physician.
Skin Contact
Wash off immediately with soap and plenty of water for at least 15 minutes. May
cause an allergic skin reaction. In the case of skin irritation or allergic reactions
see a physician.
Inhalation
Remove to fresh air. Get medical attention immediately if symptoms occur.
Ingestion
Rinse mouth immediately and drink plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
Self-protection of the first aider
Avoid contact with skin, eyes or clothing. Use personal protective equipment as
required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
4.
FIRST AID MEASURES
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Most Important Symptoms and
Effects
Indication of any immediate medical attention and special treatment needed
Burning sensation. Itching. Rashes. Hives.
Notes to Physician
Treat symptomatically. May cause sensitization of susceptible persons.
5.
FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical
The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases
and vapors. Product is or contains a sensitizer. May cause sensitization by inhalation and skin contact. In the event of fire and/or
explosion do not breathe fumes.
Uniform Fire Code Sensitizer: Solid
Hazardous Combustion Products
Carbon oxides.
Irritant: Solid
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge No.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Wear self contained breathing apparatus for fire fighting if necessary.
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Chemical Name
ACGIH TLV
OSHA PEL
NIOSH IDLH
6.
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required.
.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental Precautions
Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers. Use personal protective equipment as
required. Cover powder spill with plastic sheet or tarp to minimize spreading and keep
powder dry. Avoid generation of dust. Clean contaminated surface thoroughly. Soak up with
inert absorbent material. Dam up. Sweep up and shovel into suitable containers for
disposal. After cleaning, flush away traces with water.
7.
Precautions for safe handling
HANDLING AND STORAGE
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
Keep out of the reach of children.
Incompatible Products None known.
8.
Control parameters
EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
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Ethanol
STEL: 1000 ppm
TWA: 1000 ppm
(vacated) TWA: 1900 mg/m
IDLH: 3300 ppm 10% LEL
Maize starch
9005-25-8
Phosphoric acid
7664-38-2
Subtilisins (proteolytic enzymes)
9014-01-1
64-17-5
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health NIOSH IDLH
TWA: 10 mg/m
STEL: 3 mg/m
TWA: 1 mg/m
Ceiling: 0.00006 mg/m3 as
crystalline active enzyme
3
3
3
TWA: 15 mg/m
TWA: 5 mg/m
(vacated) TWA: 15 mg/m
(vacated) TWA: 5 mg/m
respirable fraction
TWA: 1 mg/m
(vacated) TWA: 1 mg/m
(vacated) STEL: 3 mg/m
(vacated) STEL: 0.00006 mg/m
TWA: 1900 mg/m
(vacated) TWA: 1000 ppm
3
total dust
3
respirable fraction
dust
60 min
3
total
3
3
TWA: 10 mg/m
TWA: 5 mg/m
3
3
3
3
STEL: 0.00006 mg/m
3
3
total dust
3
respirable dust
IDLH: 1000 mg/m
TWA: 1 mg/m
STEL: 3 mg/m
Subtilisins
TWA: 1000 ppm
TWA: 1900 mg/m
3
3
3
3
60 min
3
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992) See section 15 for national exposure control parameters
Appropriate engineering controls
Engineering Measures Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection Tight sealing safety goggles. Wear safety glasses with side shields (or goggles).
Skin and Body Protection No special protective equipment required. Protective gloves.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Take off
contaminated clothing and wash before reuse. Avoid contact with skin, eyes or clothing.
Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this
product.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State Solid
Appearance Pink Odor Spice
Color No information available Odor Threshold No information available
Property Values Remarks Method
pH No data available None known
Melting / freezing point No data available None known
Boiling point / boiling range No data available None known
Flash Point No data available None known
Evaporation Rate No data available None known
Flammability (solid, gas) No data available None known
Flammability Limit in Air
Upper flammability limit No data available
Lower flammability limit No data available
Vapor pressure No data available None known
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Solubility in other solvents
No data available
None known
Partition coefficient: n-octanol/waterNo data available None known
Autoignition temperature No data available None known
Decomposition temperature
No data available
None known
Particle Size
Particle Size Distribution
Vapor density
Specific Gravity
Water Solubility
No data available
No data available
Soluble in water
None known
None known
None known
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing Properties
Other Information
Softening Point
VOC Content (%)
Reactivity
No data available. Chemical stability
Stable under recommended storage conditions. Possibility of Hazardous Reactions
None under normal processing.
No data available
No data available
No data available
No data available
No data available
No data available
No data available
10.
STABILITY AND REACTIVITY
None known
None known
Hazardous Polymerization Hazardous polymerization does not occur.
Conditions to avoid None known.
Incompatible materials None known.
Hazardous Decomposition Products Carbon oxides.
11.
TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information Product does not present an acute toxicity hazard based on known or supplied information.
Inhalation Specific test data for the substance or mixture is not available. No irr itation ex pected.
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Chemical Name
ACGIH
IARC
NTP
OSHA
X
Eye Contact Specific test data for the substance or mixture is not available. Not expected to be an
irritant based on components. May Cause Eye Irritation. May cause burns.
Skin Contact Specific test data for the substance or mixture is not available. Not expected to be a
skin irritant based on components. Prolonged contact may cause redness and
irritation.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause irritation
to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting
and diarrhea
Component Information
Information on toxicological effects
Symptoms Erythema (skin redness). Burning. May cause blindness. Coughing and/ or wheezing.
Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain, or flushing.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Ethanol
64-17-5
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
A3
Group 1
Reproductive Toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Known
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Microorganisms
Flea)
7664-38-2
(Gambusia affinis)
Chemical Name
Log Pow
Ethanol
-0.32
Chronic Toxicity No known effect based on information supplied. Repeated contact may cause allergic
reactions in very susceptible persons. Avoid repeated exposure. Ethanol has been shown
to be a reproductive toxin only when consumed as an alcoholic beverage. Ethanol has been
shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage.
Target Organ Effects Eyes.Skin.
Aspiration Hazard No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
5,072.00 mg/kg
Ecotoxicity Toxic to aquatic organisms.
12.
ECOLOGICAL INFORMATION
Chemical Name
Phosphoric acid
Ethanol
64-17-5
Toxicity to Algae
Toxicity to Fish
96h LC50: 3 - 3.5 mg/L
96h LC50: > 100 mg/L
(Pimephales promelas) 96h
LC50: 13400 - 15100 mg/L
(Pimephales promelas) 96h
LC50: 12.0 - 16.0 mL/L
(Oncorhynchus mykiss)
EC50 = 34634 mg/L 30 min
Persistence and Degradability No information available.
Bioaccumulation
Toxicity to
EC50 = 35470 mg/L 5 min
Daphnia Magna (Water
12h EC50: = 4.6 mg/L
48h LC50: 9268 - 14221
mg/L 48h EC50: = 2 mg/L
24h EC50: = 10800 mg/L
Other adverse effects
No information available.
64-17-5
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Chemical Name
California Hazardous Waste
Phosphoric acid
Corrosive
64-17-5
Ignitable
13.
Waste treatment methods
DISPOSAL CONSIDERATIONS
Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Contaminated Packaging Dispose of contents/containers in accordance with local regulations.
California Hazardous Waste Codes 331
This product contains one or more substances that are listed with the State of California as a hazardous waste.
7664-38-2
Ethanol
14.
TRANSPORT INFORMATION
Toxic
DOT NOT REGULATED
Proper Shipping Name NON REGULATED
Hazard Class N/A
TDG Not regulated
MEX Not regulated
ICAO Not regulated
IATA Not regulated
Proper Shipping Name NON REGULATED
Hazard Class N/A
IMDG/IMO Not regulated
Hazard Class N/A
RID Not regulated
ADR Not regulated
ADN Not regulated
International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
15.
REGULATORY INFORMATION
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
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Chemical Name
CWA - Reportable
Quantities
CWA - Toxic Pollutants
CWA - Priority Pollutants
CWA - Hazardous
Substances
Phosphoric acid
5000 lb
X
Chemical Name
Hazardous Substances RQs
Extremely Hazardous Substances
RQs
RQ
Phosphoric acid 7664-38-
5000 lb
RQ 5000 lb final RQ
Chemical Name
California Proposition 65
Chemical Name
New Jersey
Massachusetts
Pennsylvania
Rhode Island
Illinois
X
7664-38-2
X X X
64-17-5
Component
Carcinogen Status
Exposure Limits
Phosphoric acid
Mexico: TWA 1 mg/m
Ethanol
Mexico: TWA 1000 ppm
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
7664-38-2
CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
2
US State Regulations
RQ 2270 kg final RQ
California Proposition 65
This product contains the following Proposition 65 chemicals. Ethyl alcohol is only a considered a Proposition 65 developmental
hazard when it is ingested as an alcoholic beverage.
Ethanol - 64-17-5
U.S. State Right-to-Know Regulations
Carcinogen
Developmental
.
Maize starch
9005-25-8
Phosphoric acid
Ethanol
International Regulations
X
X
X
Mexico
National occupational exposure limits
3
7664-38-2 ( 3 - 7 )
Mexico: STEL 3 mg/m
3
64-17-5 ( 0.1 - 1 )
Mexico: TWA 1900 mg/m
3
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Mexico - Occupational Exposure Limits - Carcinogens
Canada
WHMIS Hazard Class
D2A - Very toxic materials
16.
OTHER INFORMATION
NFPA Health Hazards 1 Flammability 0 Instability 0 Physical and
Chemical Hazards -
HMIS Health Hazards 1 Flammability 0
Physical Hazard 0 Personal Protection
X
Revision Date
Revision Note
02-Feb-2015
No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
End of Safety Data Sheet
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