ECOS 980006 User Manual

42.0
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture Classification
Skin Eye
2.2 Labelling The Hazard pictograms:
GHS07
Signal word: Warning Hazard
H315 Causes skin irritation.
(Contd. on page 2)
GB
SECTION 1: Identification of the substance/mixture and of the company/undertaking
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Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Printing date 13.06.2016 Version number 1 Revision: 17.08.2017
2015/830 and Regulation No 1272/2008/EC (CLP)
1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture: Cleaning Product/ Detergent For Dishwasher
1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: Venus Labs/dba Earth Friendly Products
111. S Rohlwing Rd Addison, IL 60101 Phone: 800-451-9304 Chemtrec: 800-424-9300
1.4 Emergency telephone number:
Emergency telephone number: 112
according to Regulation EC No 1272/2008 CLP:
GHS07
Irrit. 2 H315 Causes skin irritation. Irrit. 2 H319 Causes serious eye irritation.
Label elements
according to Regulation EC No 1272/2008 CLP:
product is classified and labelled according to the CLP regulation.
statements:
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 13.06.2016
Version number 1
Revision: 17.08.2017
Trade name: ECOS 4x Laundry Lavender
(Contd. of page 1)
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H319 Causes serious eye irritation. Precautionary
P102 P264 P302+P352 P305+P351+P338
P332+P313 P337+P313 Additional EUH208 Contains lavender oil. May produce an allergic reaction.
2.3 Other hazards Results PBT: vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
3.2 Chemical characterisation: Mixtures Description: Mixture of substances listed below with nonhazardous additions.
Additional information:
(Contd. on page 3)
GB
Regulation (EC) No 648/2004 on detergents / Labelling for contents
anionic surfactants
5 - 15%
non-ionic surfactants, amphoteric surfactants, soap
< 5%
preservation agents (PHENOXYETHANOL, 2-methyl-2H-isothiazol-3-one), perfumes Ingredients according Regulation (EU) 830/2015:
CAS: 97375-27-4
Sodium Coco-Sulfate
2.5-<10%
Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319
CAS: 110615-47-9
D-Glucopyranose, oligomeric, C10-16-alkyl glycosid e s
2.5-<10%
Eye Dam. 1, H318; Skin Irrit. 2, H315
CAS: 61789-40-0
Cocoamidopropyl Betaine
0.1-<2.5%
Eye Dam. 1, H318
CAS: 61789-30-8
Potassium Cocoate
0.1-<2.5%
Skin Irrit. 2, H315; Eye Irrit. 2, H319
CAS: 8000-28-0
lavender oil
0.1-<1%
Asp. Tox. 1, H304; Skin Irrit. 2, H315; Eye Irrit. 2, H319;
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Keep out of reach of children. Wash thoroughly after handling.
statements
IF ON SKIN: Wash with plenty of water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention.
information:
(LINALOOL)
of PBT and vPvB assessment
Not applicable.
EC number: 306-683-4
EINECS: 263-058-8
Skin Sens. 1, H317
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 13.06.2016
Version number 1
Revision: 17.08.2017
Trade name: ECOS 4x Laundry Lavender
(Contd. of page 2)
42.0
SECTION 4: First aid measures
SECTION 5: Firefighting measures
SECTION 6: Accidental release measures
SECTION 7: Handling and storage
7.1 Precautions for safe handling No special precautions are necessary if used correctly.
(Contd. on page 4)
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Specific Concentration Limit: Lauryl Glucoside (CAS 110615-47-9) Skin Irrit. 2: C > 30%
Eye Dam. 1: C > 30% Eye Dam. 1: 12% < C ≤ 30%
4.1 Description of first aid measures General information: Take affected persons out into the fresh air. Seek immediate medical advice. After inhalation: Seek medical treatment in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for at least 15 minutes under running water. After swallowing: Drink plenty of water and provide fresh air. Call for a doctor immediately.
4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.
5.1 Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray.
5.2 Special hazards arising from the substance or mixture No further relevant information available.
5.3 Advice for firefighters Protective equipment: Self contained breathing apparatus and full protective clothing must be worn in case of fire. Additional information Collect contaminated fire fighting water separately. It must not enter the sewage system.
6.1 Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away.
6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust, silica gel).
6.4 Reference to other sections: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 13.06.2016
Version number 1
Revision: 17.08.2017
Trade name: ECOS 4x Laundry Lavender
(Contd. of page 3)
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SECTION 8: Exposure controls/personal protection
8.1 Control parameters Ingredients The at
8.2 Personal
General Keep Wash Avoid Respiratory Protection of hands:
Protective gloves
Penetration time of glove material The Therefore Eye protection:
Tightly sealed goggles
Body protection:
Protective work clothing
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep container tightly sealed.
7.3 Specific end use(s) No further relevant information available.
with limit values that require monitoring at the workplace:
product does not contain any relevant quantities of materials with critical values that have to be monitored
the workplace.
Exposure controls
protective equipment
protective and hygienic measures:
away from foodstuffs, beverages and feed.
hands before breaks and at the end of work.
contact with the eyes.
determined penetration times according to EN 374 part III are not performed under practical conditions.
protection: Not required.
a maximum wearing time, which corresponds to 50% of the penetration time, is recommended.
(Contd. on page 5)
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 13.06.2016
Version number 1
Revision: 17.08.2017
Trade name: ECOS 4x Laundry Lavender
42.0
17.08.2017
SECTION 9: Physical and chemical properties
SECTION 10: Stability and reactivity
10.1 Reactivity Stable under normal conditions
(Contd. on page 6)
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
(Contd. of page 4)
9.1 Information on basic physical and chemical properties General Information Appearance:
Form: Liquid
Colour: Whitish Odour: Characteristic Odour threshold: Not determined
pH value: 9,25-10 Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined
Flash point: Not applicable Flammability (solid, gaseous): Not applicable Auto-ignition temperature: Not determined Decomposition temperature: Not determined Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits:
Lower: Not determined
Upper: Not determined Oxidising properties Not considered as oxidising.
Vapour pressure: Not determined Density: Not determined
Relative density Not determined Vapour density Not determined Evaporation rate Not determined
Solubility in / Miscibility with
water:
Fully miscible
Partition coefficient (n-octanol/water): Not determined Viscosity:
Dynamic: Not determined
Kinematic: Not determined
9.2 Other information No further relevant information available.
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 13.06.2016
Version number 1
Revision: 17.08.2017
Trade name: ECOS 4x Laundry Lavender
(Contd. of page 5)
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SECTION 12: Ecological information
12.1 Toxicity
12.2 Persistence and degradability The down the at
12.3
12.4
7)
GB
LD/LC50 values relevant for classification:
Oral
LD50
7062 mg/kg
61789-40-0 Cocoamidopropyl Betaine
Oral
LD50
2335 mg/kg (rat)
Aquatic toxicity:
61789-40-0 Cocoamidopropyl Betaine
Toxicity to Quail
1.11 mg/kg (Fresh water fish)
SECTION 11: Toxicological information
complying with Regulation 1907/2006/EC (REACH Regulation), EU
10.2 Chemical stability Thermal decomposition / conditions to be avoided Stable at environment temperature.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials No further relevant information available.
10.6 Hazardous decomposition products No dangerous decomposition products known.
11.1 Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met.
Dermal
LD50
>2000 mg/kg (rat)
Skin corrosion/irritation Causes skin irritation. Serious eye damage/irritation Causes serious eye irritation. Respiratory or skin sensitisation Based on available data, the classification criteria are not met. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met.
surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid
in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of
competent authorities of the Member States and will be made available to them, at their direct request or
the request of a detergent manufacturer.
Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available.
(Contd. on page
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 13.06.2016
Version number 1
Revision: 17.08.2017
Trade name: ECOS 4x Laundry Lavender
(Contd. of page 6)
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SECTION 14: Transport information
(Contd. on page 8)
GB
14.1 UN-Number
ADR, ADN, IMDG, IATA
Void
14.2 UN proper shipping name
ADR, ADN, IMDG, IATA
Void
ADR, ADN, IMDG, IATA
Class
Void
14.4 Packing group
ADR, IMDG, IATA
Void
14.7 Transport in bulk according to Ann
ex II of
Marpol and the IBC Code
Not applicable.
SECTION 13: Disposal considerations
complying with Regulation 1907/2006/EC (REACH Regulation), EU
12.5 Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.
13.1 Waste treatment methods Recommendation
Dispose according to National Regulations.
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Contact manufacturer for recycling information. Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations. Packaging may be reused or recycled after cleaning.
14.3 Transport hazard class(es)
14.5 Environmental hazards: Not applicable.
14.6 Special precautions for user Not applicable.
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 13.06.2016
Version number 1
Revision: 17.08.2017
Trade name: ECOS 4x Laundry Lavender
(Contd. of page 7)
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SECTION 16: Other information
SECTION 15: Regulatory information
complying with Regulation 1907/2006/EC (REACH Regulation), EU
UN "Model Regulation": Void
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed. National regulations: Other regulations, limitations and prohibitive regulations
Substances of very high concern (SVHC) according to REACH, Article 57 It doesn't contain substances of very high concern (SVHC).
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. Training hints Suitable training on safety in handling, storing and converting the product should be given to the employees based on all the existing information.
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances
(Contd. on page 9)
GB
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Safety Data Sheet
2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 13.06.2016
Version number 1
Revision: 17.08.2017
Trade name: ECOS 4x Laundry Lavender
42.0
(Contd. of page 8)
ELINCS: European List of Notified Chemical Substances CAS: LC50: LD50: PBT: SVHC: vPvB: Acute Skin Eye Eye Skin Asp. Tox. 1: Aspiration hazard, Hazard Category 1
GB
complying with Regulation 1907/2006/EC (REACH Regulation), EU
Chemical Abstracts Service (division of the American Chemical Society)
Lethal concentration, 50 percent Lethal dose, 50 percent
Persistent, Bioaccumulative and Toxic
Substances of Very High Concern very Persistent and very Bioaccumulative Tox. 4: Acute toxicity, Hazard Category 4
Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Sens. 1: Sensitisation - Skin, Hazard Category 1
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