SAFETY DATA SHEET
Issuing Date No data available Revision Date 25-Nov-2014 Revision Number 1
Product identifier
Product Name ECOS 4X Free & Clea r (9799)
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Laundry, Detergent
Uses advised against No information available
Details of the supplier of the safety data sheet
Supplier Name Venus Labs/dba Earth Friendly Products
Supplier Address 111. S Rohlwing Rd Addison, IL 60101
Supplier Phone Number Phone: 800-451-9304
Emergency telephone number Chemtrec: 800-424-9300
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Eye irritation Category 2A
GHS Label elements, including precautionary statements
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this
the sub
stance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
information or
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
2. HAZARDS IDENTIFICATION
Emergency Overview
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1192421 - ECOS 4X Free & Clear (9799)
Revision Date 25-Nov-2014
Signal word Warning
Hazard Statements
May cause eye irritation
Appearance Clear to light yellow Physical State Viscous Liquid Odor None
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Remove the contaminated clothing and wash.
Precautionary Statements - Response
Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If irritation persists consult a doctor/physician.
Skin
IF ON SKIN: No adverse reaction expected. Wash with soap and water
Take off contaminated clothing and wash before reuse
If skin irritation or rash occurs: Get medical advice/attention
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
35% of the mixture consists of ingredient(s) of unknown toxicity
Other information
Toxic to aquatic life with long lasting effects
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons
Interactions with Other Chemicals
No information available.
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1192421 - ECOS 4X Free & Clear (9799)
Revision Date 25-Nov-2014
Chemical Name
CAS No.
Weight-%
Trade Secret
Cocamidopropyl betaine
61789-40-0
5 - 10
*
Coco-glucoside
110615-47-9
3 - 7
*
2-Methyl-3-isothiazolone
2682-20-4
0.1 - 1
*
3. COMPOSITION/INFORMATION ON INGREDIENTS
*The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
First aid measures
General Advice
Eye Contact
Skin Contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Show this safety data sheet to the doctor in attendance. Immediate medical
attention is required.
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and
If irritation persists consult a doctor/physician.
Wash off immediately with soap and plenty of water for at least 15 minutes. May
cause an allergic skin reaction. In the case of skin irritation or allergic reactions
see a physician.
Remove to fresh air. Get medical attention immediately if symptoms occur.
Rinse mouth immediately and drink plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
Avoid contact with skin, eyes or clothing. Use personal protective equipment as
required. Wear personal protective clothing (see section 8).
Burning sensation. Itching. Rashes. Hives.
May cause sensitization of susceptible persons. Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
Product is or contains a sensitizer. May cause sensitization by skin contact.
Uniform Fire Code Irritant: Liquid
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge No.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental Precautions
Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
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Physical State
Viscous Liquid
Appearance
Clear to light yellow
Odor
None
Precautions for safe handling
7. HANDLING AND STORAGE
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.
Keep out of the reach of children.
Incompatible Products Strong acids. Strong oxidizing agents. Strong bases.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational
Appropriate engineering controls
Engineering Measures Showers Eyewash
Individual protection measures, such as personal protective equipment
Eye/Face Protection Tight sealing safety goggles.
Skin and Body Protection Wear protective gloves and protective clothing. Long sleeved clothing. Impervious gloves.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Take off
exposure limits established by the region specific regulatory bodies
stations Ventilation
systems
exceeded or irritation is experienced, ventilation and evacuation may be required.
contaminated clothing and wash before reuse. Avoid contact with skin, eyes or clothing.
Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this
product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Color
Property
pH
Melting / freezing point
Boiling point / boiling range
Pale gold
Values
9.85
No data available
212°C
Odor Threshold
Remarks/ Method
None known
None known
None known
No information available
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gas)
No data available
None known
Flammability Limit in Air
Upper flammability limit
Vapor pressure
No data available
No data available
None known
Vapor density
Solubility in other solvents
No data available
No data available
None known
None known
Partition coefficient: n-octanol/waterNo data available None known
Autoignition temperature
No data available
None known
Particle Size
No data available
Particle Size Distribution
Flash Point Evaporation
Rate Flammability (solid,
98°C / >210° F
No data available
None known
None known
Lower flammability limit
Specific Gravity
Water Solubility
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing Properties
Other Information
Softening Point
VOC Content (%)
No data available
1.026
Soluble in water
No data available
No data available
No data available
No data available
No data available
No data available
No data available
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
None known based on information supplied.
Incompatible materials
Strong acids. Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available. No irritation expected.
None known
None known
None known
None known
None known
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Chemical Name
Oral LD50
Dermal LD50
Inhalation LC50
Cocamidopropyl betaine
= 4900 mg/kg ( Rat )
-
-
Eye Contact Specific test data for the substance or mixture is not available. Expected to be an irritant
based on components. May Cause Eye Irritation. May cause burns.
Skin Contact Specific test data for the substance or mixture is not available. Not expected to be a
skin irritant based on components. Prolonged contact may cause redness and irritation.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
Component Information
61789-40-0
Information on toxicological effects
Symptoms Erythema (skin redness). May cause redness and tearing of the eyes. May cause
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization May cause sensitization of susceptible persons. May cause sensitization by skin contact.
Mutagenic Effects No information available.
Carcinogenicity Contains no ingredient listed as a carcinogen.
Reproductive Toxicity No information available.
vomiting and diarrhea.
blindness. Burning. Itching. Rashes. Hives.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Chronic Toxicity No known effect based on information supplied.
Target Organ Effects Eyes. Skin.
Aspiration Hazard No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
25,685.00 mg/kg
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Chemical Name
Toxicity to Algae
Toxicity to Fish
Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
Cocamidopropyl betaine
72h EC50: 1.0 - 10.0 mg/L
subspicatus)
96h LC50: 1.0 - 10.0 mg/L
48h EC50: = 6.5 mg/L
Ecotoxicity
Toxic to aquatic life with long lasting effects.
12. ECOLOGICAL INFORMATION
61789-40-0
Persistence and Degradability
No information available.
(Desmodesmus
subspicatus) 96h EC50: =
0.55 mg/L (Desmodesmus
(Brachydanio rerio) 96h
LC50: = 2 mg/L
(Brachydanio rerio)
Bioaccumulation
No information available
Other adverse effects
No information available.
Waste treatment methods
13. DISPOSAL CONSIDERATIONS
Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Contaminated Packaging Dispose of contents/containers in accordance with local regulations.
California Hazardous Waste Codes 561
14. TRANSPORT INFORMATION
DOT NOT REGULATED
TDG Not regulated
MEX Not regulated
ICAO Not regulated
IATA Not regulated
IMDG/IMO Not regulated
RID Not regulated
ADR Not regulated
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ADN Not regulated
International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
15. REGULATORY INFORMATION
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard No
Fire Hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
This product does not contain any substances regulated by state right-to-know regulations.
International Regulations
Canada
WHMIS Hazard Class
D2B - Toxic materials
16. OTHER INFORMATION
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Chemical Hazards -
HMIS
Health Hazards 1
Flammability 1
Physical Hazard 0
Personal
Protection
Health Hazards 1 Flammability 1 Instability 0 Physical and
NFPA
X
Revision Date
Revision Note
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
25-Nov-2014
information
No
End of Safety Data
available
Sheet
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