Page 1
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Safety Data Sheet
acc. to HCS and GHS
Printing date 01/06/2015 Reviewed on 01/06/2015
1 Identification
·
Product identifier
·
Trade name: Clear Reflections
·
Article number:
·
Application of the substance / the mixture
·
Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
ITW Pro Brands
805 East Old 56 Highway
Olathe, Kansas 66061
Phone: 1-800-224-4860
·
Emergency telephone number:
2 Hazard(s) identification
385
Glass Cleaner
Infotrac Emergency Hotline: 1-800-535-5053
·
Classification of the substance or mixture
GHS04 Gas cylinder
Press. Gas H280 Contains gas under pressure; may explode if heated.
·
Label elements
·
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
·
Hazard pictograms
GHS04
·
Signal word
·
Hazard statements
H280 Contains gas under pressure; may explode if heated.
·
Precautionary statements
P410+P403 Protect from sunlight. Store in a well-ventilated place.
·
Hazard description:
·
WHMIS-symbols:
A - Compressed gas
Warning
·
Classification system:
·
NFPA ratings (scale 0 - 4)
Health = 0
000
40.0.2
Fire = 0
Reactivity = 0
(Contd. on page 2)
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Safety Data Sheet
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Printing date 01/06/2015 Reviewed on 01/06/2015
Trade name: Clear Reflections
(Contd. of page 1)
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
·
Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
·
vPvB:
0
Health = 0
0
Fire = 0
0
Reactivity = 0
Not applicable.
Not applicable.
3 Composition/information on ingredients
·
Chemical characterization: Mixtures
·
Description:
·
Dangerous components:
74-98-6 propane
72-28-5 Isobutane
64-17-5 ethanol
111-76-2 2-butoxyethanol
Mixture of the substances listed below with nonhazardous additions.
Flam. Gas 1, H220
Press. Gas, H280
Flam. Gas 1, H220
Flam. Liq. 2, H225
Eye Irrit. 2A, H319
Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315;
Eye Irrit. 2, H319
Flam. Liq. 4, H227
2.5-10%
2.5%
2.5%
2.5%
4 First-aid measures
·
Description of first aid measures
·
General information:
·
After inhalation:
Supply fresh air; consult doctor in case of complaints.
Provide oxygen treatment if affected person has difficulty breathing.
·
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation is experienced, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Unlikely route of exposure.
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; immediately call for medical help.
40.0.2
Take affected persons out into the fresh air.
(Contd. on page 3)
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Safety Data Sheet
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Printing date 01/06/2015 Reviewed on 01/06/2015
Trade name: Clear Reflections
(Contd. of page 2)
·
Most important symptoms and effects, both acute and delayed
Headache
Breathing difficulty
Dizziness
Coughing
Nausea
Disorientation
·
Danger
·
Indication of any immediate medical attention and special treatment needed
If necessary oxygen respiration treatment.
5 Fire-fighting measures
·
Extinguishing media
·
Suitable extinguishing agents:
·
For safety reasons unsuitable extinguishing agents:
·
Special hazards arising from the substance or mixture
Danger of receptacles bursting because of high vapor pressure if heated.
Formation of toxic gases is possible during heating or in case of fire.
·
Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
Danger of impaired breathing.
Use fire fighting measures that suit the environment.
None.
No further relevant information available.
6 Accidental release measures
·
Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation.
For large spills, wear protective clothing.
For large spills, use respiratory protective device against the effects of fumes/dust/aerosol.
·
Environmental precautions:
·
Methods and material for containment and cleaning up:
No special measures required.
Absorb liquid components with liquid-binding material.
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
Send for recovery or disposal in suitable receptacles.
·
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
·
Precautions for safe handling
Keep away from heat and direct sunlight.
Use only in well ventilated areas.
(Contd. on page 4)
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Safety Data Sheet
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Printing date 01/06/2015 Reviewed on 01/06/2015
Trade name: Clear Reflections
(Contd. of page 3)
Avoid splashes or spray in enclosed areas.
·
Information about protection against explosions and fires:
·
Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressurized containers.
Provide ventilation for receptacles.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidizing agents.
·
Further information about storage conditions:
Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting.
Protect from frost.
·
Specific end use(s)
No further relevant information available.
No special measures required.
8 Exposure controls/personal protection
·
Additional information about design of technical systems:
·
Control parameters
·
Components with limit values that require monitoring at the workplace:
74-98-6 propane
PEL (USA) Long-term value: 1800 mg/m³, 1000 ppm
REL (USA) Long-term value: 1800 mg/m³, 1000 ppm
TLV (USA) refer to Appendix F
EL (Canada) Long-term value: 1000 ppm
EV (Canada) Long-term value: 1.000 ppm
LMPE (Mexico) Long-term value: 1000 ppm
64-17-5 ethanol
PEL (USA) Long-term value: 1900 mg/m³, 1000 ppm
REL (USA) Long-term value: 1900 mg/m³, 1000 ppm
TLV (USA) Short-term value: 1880 mg/m³, 1000 ppm
EL (Canada) Short-term value: 1000 ppm
EV (Canada) Long-term value: 1.900 mg/m³, 1.000 ppm
LMPE (Mexico) Long-term value: 1000 ppm
A3
111-76-2 2-butoxyethanol
PEL (USA) Long-term value: 240 mg/m³, 50 ppm
Skin
REL (USA) Long-term value: 24 mg/m³, 5 ppm
Skin
TLV (USA) Long-term value: 97 mg/m³, 20 ppm
BEI
No further data; see item 7.
(Contd. on page 5)
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Safety Data Sheet
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Printing date 01/06/2015 Reviewed on 01/06/2015
Trade name: Clear Reflections
(Contd. of page 4)
EL (Canada) Long-term value: 20 ppm
EV (Canada) Long-term value: 20 ppm
Skin
LMPE (Mexico) Long-term value: 20 ppm
A3, IBE
·
Ingredients with biological limit values:
111-76-2 2-butoxyethanol
BEI (USA) 200 mg/g creatinine
Medium: urine
Time: end of shift
Parameter: Butoxyacetic acid with hydrolysis
·
Additional information:
·
Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid close or long term contact with the skin.
Avoid contact with the eyes.
·
Breathing equipment:
Not required under normal conditions of use.
For spills, respiratory protection may be advisable.
Use suitable respiratory protective device in case of insufficient ventilation.
·
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from m anufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
·
Eye protection:
The lists that were valid during the creation were used as basis.
Safety glasses
·
Body protection:
·
Limitation and supervision of exposure into the environment
Protective work clothing
No further relevant information available.
(Contd. on page 6)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 01/06/2015 Reviewed on 01/06/2015
Trade name: Clear Reflections
(Contd. of page 5)
9 Physical and chemical properties
·
Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Color:
·
Odor:
·
Odor threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Auto-ignition temperature:
·
Decomposition temperature:
·
Auto igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapor pressure at 21 °C (70 °F):
·
Density at 20 °C (68 °F):
·
Relative density
·
Vapour density
·
Evaporation rate
·
Solubility in / Miscibility with
Water:
·
Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic:
Kinematic:
·
Solvent content:
VOC content:
·
Other information
Aerosol
Colorless
Pleasant
Not determined.
9.0 - 10.0
Not applicable, as aerosol.
Not applicable, as aerosol.
Not applicable, as aerosol.
Not applicable.
Not determined.
Not determined.
Product is not self-igniting.
Not determined.
Not determined.
Not determined.
125 psig
0.996 g/cm³ (8.312 lbs/gal)
Not determined.
> 1 (Air=1)
Not applicable.
Soluble.
Not determined.
Not determined.
Not determined.
7.38 %
No further relevant information available.
(Contd. on page 7)
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Safety Data Sheet
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Printing date 01/06/2015 Reviewed on 01/06/2015
Trade name: Clear Reflections
(Contd. of page 6)
10 Stability and reactivity
·
Reactivity
·
Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
Possibility of hazardous reactions
Toxic fumes may be released if heated above the decomposition point.
Reacts with strong acids and oxidizing agents.
·
Conditions to avoid
·
Incompatible materials:
·
Hazardous decomposition products:
Possible in traces.
Carbon monoxide and carbon dioxide
Nitrogen oxides
Keep away from heat and direct sunlight.
No further relevant information available.
11 Toxicological information
·
Information on toxicological effects
·
Acute toxicity:
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
·
Carcinogenic categories
·
IARC (International Agency for Research on Cancer)
·
NTP (National Toxicology Program)
No irritant effect.
No irritating effect.
No sensitizing effects known.
See Section 15.
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
·
Toxicity
·
Aquatic toxicity:
·
Persistence and degradability
·
Bioaccumulative potential
·
Mobility in soil
·
Additional ecological information:
·
General notes:
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
(Contd. on page 8)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 01/06/2015 Reviewed on 01/06/2015
Trade name: Clear Reflections
(Contd. of page 7)
·
vPvB:
·
Other adverse effects
13 Disposal considerations
·
Waste treatment methods
·
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Contact waste processors for recycling information.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous.
·
Waste disposal key:
·
Uncleaned packagings:
·
Recommendation:
Not applicable.
No further relevant information available.
EPA RCRA Code (USA) : D001 .
Disposal must be made according to official regulations.
14 Transport information
·
UN-Number
·
DOT, ADR, IMDG, IATA
·
UN proper shipping name
Limited Quantity for packages less than 30 kg (66 lb) and inner packagings less than 1 L (0.3
gal).
·
DOT
·
ADR
·
IMDG
·
IATA
·
Transport hazard class(es)
·
DOT
·
Class
·
Label
·
ADR
UN1950
Aerosols
1950 AEROSOLS
AEROSOLS
Aerosols, non-flammable
2 Gases
2.2
·
Class
40.0.2
2 5A Gases
(Contd. on page 9)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 01/06/2015 Reviewed on 01/06/2015
Trade name: Clear Reflections
(Contd. of page 8)
·
Label
·
IMDG
·
Class
·
Label
·
IATA
·
Class
·
Label
·
Packing group
·
DOT, ADR, IMDG, IATA
·
Environmental hazards:
·
Marine pollutant:
·
Special precautions for user
·
Danger code (Kemler):
·
EMS Number:
·
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
Transport/Additional information:
·
DOT
·
Quantity limitations
·
ADR
·
Excepted quantities (EQ)
·
IMDG
·
Limited quantities (LQ)
·
Excepted quantities (EQ)
·
UN "Model Regulation":
2.2
2 Gases
2.2
2.2
2.2
Not Regulated
No
Warning: Gases
F-D,S-U
Not applicable.
On passenger aircraft/rail: 75kg
On cargo aircraft only: 150kg
Code: E0
Not permitted as Excepted Quantity
1L
Code: E0
Not permitted as Excepted Quantity
UN1950, Aerosols, 2.2
15 Regulatory information
·
Safety, health and environmental regulations/legislation specific for the substance or mixture
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
(Contd. on page 10)
40.0.2
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Safety Data Sheet
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Trade name: Clear Reflections
(Contd. of page 9)
·
Section 313 (Specific toxic chemical listings):
111-76-2 2-butoxyethanol
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California)
·
Chemicals known to cause cancer:
Ethanol - listing refers specifically to alcoholic beverage consumption and is not applicable for product.
64-17-5 ethanol
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
Ethanol - listing refers specifically to alcoholic beverage consumption and is not applicable for product.
64-17-5 ethanol
·
Carcinogenic categories
·
EPA (Environmental Protection Agency)
111-76-2 2-butoxyethanol NL
·
IARC (International Agency for Research on Cancer)
64-17-5 ethanol 1
111-76-2 2-butoxyethanol 3
·
TLV (Threshold Limit Value established by ACGIH)
64-17-5 ethanol A3
111-76-2 2-butoxyethanol A3
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
State Right to Know Listings
None of the ingredients is listed.
·
Canadian substance listings:
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
64-17-5 ethanol
·
Canadian Ingredient Disclosure list (limit 1%)
111-76-2 2-butoxyethanol
·
Other regulations, limitations and prohibitive regulations
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the SDS contains all the information required by the Controlled Products Regulations.
(Contd. on page 11)
40.0.2
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Safety Data Sheet
acc. to HCS and GHS
Printing date 01/06/2015 Reviewed on 01/06/2015
Trade name: Clear Reflections
(Contd. of page 10)
·
Chemical safety assessment:
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Date of preparation / last revision
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agr eement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
VOC: Volatile Organic Compounds (USA, EU)
Flam. Gas 1: Flammable gases, Hazard Category 1
Press. Gas: Gases under pressure: Compressed gas
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Flam. Liq. 4: Flammable liquids, Hazard Category 4
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
A Chemical Safety Assessment has not been carried out.
01/06/2015 / -
40.0.2
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