Page 1
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 11/24/2014
1 Identification
·
Product identifier
·
Trade name: Eliminator Carpet Spot Cleaner
·
Article number: 106
·
Application of the substance / the mixture Carpet Cleaner
·
Details of the supplier of the Safety Data Sheet
· Manufacturer/Supplier:
ITW Pro Brands
805 East Old 56 Highway
Olathe, Kansas 66061
Phone: 1-800-224-4860
·
Emergency telephone number: Infotrac Emergency Hotline: 1-800-535-5053
2 Hazard(s) identification
·
Classification of the substance or mixture
GHS04 Gas cylinder
Press. Gas H280 Contains gas under pressure; may explode if heated.
GHS07
Eye Irrit. 2A H319 Causes serious eye irritation.
·
Label elements
· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
GHS04 GHS07
·
Signal word Warning
·
Hazard-determining components of labeling:
2-butoxyethanol
2-(2-butoxyethoxy)ethanol
propan-2-ol
· Hazard statements
H280 Contains gas under pressure; may explode if heated.
H319 Causes serious eye irritation.
· Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P251 Pressurized container: Do not pierce or burn, even after use.
P280 Wear protective gloves / eye protection.
(Contd. on page 2)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
P264 Wash thoroughly after handling.
(Contd. of page 1)
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
· Hazard description:
· WHMIS-symbols:
A - Compressed gas
D2B - Toxic material causing other toxic effects
·
Classification system:
·
NFPA ratings (scale 0 - 4)
Health = 1
0
Fire = 0
1 0
Reactivity = 0
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
1
Health = 1
0
Fire = 0
REACTIVITY 0
Reactivity = 0
·
Other hazards
· Results of PBT and vPvB assessment
·
PBT: Not applicable.
·
vPvB: Not applicable.
3
Composition/information
on ingredients
·
Chemical characterization: Mixtures
·
Description: Mixture of the substances listed below with nonhazardous additions.
·
Dangerous components:
111-76-2
2-butoxyethanol
5-10%
Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315;
Eye Irrit. 2, H319
Flam. Liq. 4, H227
75-28-5
Isobutane
1-5%
Flam. Gas 1, H220
112-34-5
2-(2-butoxyethoxy)ethanol
1-5%
Eye Irrit. 2, H319
(Contd. on page 3)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
(Contd. of page 2)
67-63-0
propan-2-ol
1-5%
Flam. Liq. 2, H225
Eye Irrit. 2, H319; STOT SE 3, H336
74-98-6
propane
1-5%
Flam. Gas 1, H220
Press. Gas, H280
4 First-aid measures
·
Description of first aid measures
·
General information: Take affected persons out into the fresh air.
· After inhalation:
Supply fresh air; consult doctor in case of complaints.
Provide oxygen treatment if affected person has difficulty breathing.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Unlikely route of exposure.
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; immediately call for medical help.
· Most important symptoms and effects, both acute and delayed
Headache
Breathing difficulty
Dizziness
Coughing
Frostbite
Nausea
Gastric or intestinal disorders when ingested.
Irritating to eyes.
Slight irritant effect on skin and mucous membranes.
Disorientation
·
Danger Danger of impaired breathing.
· Indication of any immediate medical attention and special treatment needed
If necessary oxygen respiration treatment.
5 Fire-fighting measures
·
Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
·
For safety reasons unsuitable extinguishing agents: None.
· Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
(Contd. on page 4)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
Danger of receptacles bursting because of high vapor pressure if heated.
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Additional information
Cool endangered receptacles with water spray.
(Contd. of page 3)
6 Accidental release measures
·
Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation.
For large spills, wear protective clothing.
For large spills, use respiratory protective device against the effects of fumes/dust/aerosol.
·
Environmental precautions: No special measures required.
· Methods and material for containment and cleaning up:
Absorb liquid components with liquid-binding material.
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
Send for recovery or disposal in suitable receptacles.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
·
Precautions for safe handling
Keep away from heat and direct sunlight.
Use only in well ventilated areas.
Avoid splashes or spray in enclosed areas.
· Information about protection against explosions and fires:
Do not spray on a naked flame or any incandescent material.
·
Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Avoid storage near extreme heat, ignition sources or open flame.
Observe official regulations on storing packagings with pressurized containers.
Provide ventilation for receptacles.
· Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidizing agents.
· Further information about storage conditions:
Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting.
Protect from frost.
· Specific end use(s)
No further relevant information available.
(Contd. on page 5)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
(Contd. of page 4)
8 Exposure controls/personal protection
·
Additional information about design of technical systems: No further data; see item 7.
·
Control parameters
·
Components with limit values that require monitoring at the workplace:
111-76-2 2-butoxyethanol
PEL (USA)
REL (USA)
TLV (USA)
EL (Canada)
EV (Canada)
LMPE (Mexico)
Long-term value: 240 mg/m³, 50 ppm
Skin
Long-term value: 24 mg/m³, 5 ppm
Skin
Long-term value: 97 mg/m³, 20 ppm
BEI
Long-term value: 20 ppm
Long-term value: 20 ppm
Skin
Long-term value: 20 ppm
A3, IBE
112-34-5 2-(2-butoxyethoxy)ethanol
TLV (USA)
Long-term value: 67.5* mg/m³, 10* ppm
*Inhalable fraction and vapor
67-63-0 propan-2-ol
PEL (USA)
REL (USA)
TLV (USA)
EL (Canada)
EV (Canada)
LMPE (Mexico)
Long-term value: 980 mg/m³, 400 ppm
Short-term value: 1225 mg/m³, 500 ppm
Long-term value: 980 mg/m³, 400 ppm
Short-term value: 984 mg/m³, 400 ppm
Long-term value: 492 mg/m³, 200 ppm
BEI
Short-term value: 400 ppm
Long-term value: 200 ppm
Short-term value: 400 ppm
Long-term value: 200 ppm
Short-term value: 400 ppm
Long-term value: 200 ppm
A4, IBE
74-98-6 propane
PEL (USA)
REL (USA)
TLV (USA)
EL (Canada)
EV (Canada)
LMPE (Mexico)
Long-term value: 1800 mg/m³, 1000 ppm
Long-term value: 1800 mg/m³, 1000 ppm
refer to Appendix F
Long-term value: 1000 ppm
Long-term value: 1.000 ppm
Long-term value: 1000 ppm
(Contd. on page 6)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
(Contd. of page 5)
·
Ingredients with biological limit values:
111-76-2 2-butoxyethanol
BEI (USA)
200 mg/g creatinine
Medium: urine
Time: end of shift
Parameter: Butoxyacetic acid with hydrolysis
67-63-0 propan-2-ol
BEI (USA)
40 mg/L
Medium: urine
Time: end of shift at end of workweek
Parameter: Acetone (background, nonspecific)
·
Additional information: The lists that were valid during the creation were used as basis.
·
Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid close or long term contact with the skin.
Avoid contact with the eyes.
· Breathing equipment:
Not required under normal conditions of use.
For spills, respiratory protection may be advisable.
Use suitable respiratory protective device in case of insufficient ventilation.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depen d on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
· Eye protection:
Safety
glasses
·
Body protection: Protective work clothing
(Contd. on page 7)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
·
Limitation and supervision of exposure into the environment
No further relevant information available.
(Contd. of page 6)
9 Physical and chemical properties
·
Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Color: Various
colors
White / Pink /
Yellow
·
Odor: Citrus.
·
Odor threshold: Not determined.
·
pH-value: 8.0 - 10.0
·
Change in condition
Melting point/Melting range: Not applicable, as aerosol.
Boiling point/Boiling range: Not applicable, as aerosol.
·
Flash point: Not applicable, as aerosol.
·
Flammability (solid, gaseous): Not applicable.
·
Auto-ignition temperature: Not determined.
·
Decomposition temperature: Not determined.
·
Auto igniting: Product is not self-igniting.
·
Danger of explosion: Not determined.
·
Explosion limits:
Lower: Not determined.
Upper: Not determined.
·
Vapor pressure at 21 °C (70 °F): 121 psig
·
Density at 20 °C (68 °F): 0.99 g/cm³ (8.262 lbs/gal)
·
Relative density Not determined.
·
Vapour density > 1 (Air=1)
·
Evaporation rate Not applicable.
·
Solubility in / Miscibility with
Water: Soluble.
·
Partition coefficient (n-octanol/water): Not determined.
·
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
·
Solvent content:
VOC content: 14.91 %
(Contd. on page 8)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
·
Other information No further relevant information available.
(Contd. of page 7)
10 Stability and reactivity
·
Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
· Possibility of hazardous reactions
Toxic fumes may be released if heated above the decomposition point.
Reacts with strong acids and oxidizing agents.
·
Conditions to avoid Keep away from heat and direct sunlight.
·
Incompatible materials: No further relevant information available.
·
Hazardous decomposition products: Carbon monoxide and carbon dioxide
11 Toxicological information
·
Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
·
on the skin: Slight irritant effect on skin and mucous membranes.
·
on the eye: Irritating effect.
·
Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Irritant
·
Carcinogenic categories
·
IARC (International Agency for Research on Cancer) See Section 15.
·
NTP (National Toxicology Program)
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
·
Toxicity
·
Aquatic toxicity: No further relevant information available.
·
Persistence and degradability No further relevant information available.
·
Bioaccumulative potential No further relevant information available.
·
Mobility in soil No further relevant information available.
· Results of PBT and vPvB assessment
·
PBT: Not applicable.
·
vPvB: Not applicable.
(Contd. on page 9)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
·
Other adverse effects No further relevant information available.
(Contd. of page 8)
13 Disposal
considerations
·
Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Contact waste processors for recycling information.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous.
·
Waste disposal key: EPA RCRA Code (USA) : D001 .
·
Uncleaned packagings:
·
Recommendation: Disposal must be made according to official regulations.
14 Transport
information
·
UN-Number
·
DOT, ADR, IMDG, IATA UN1950
· UN proper shipping name
Limited Quantity for packages less than 30 kg (66 lb) and inner packagings less than 1 L (0.3
gal).
·
DOT Aerosols
·
ADR 1950 AEROSOLS
·
IMDG AEROSOLS
·
IATA AEROSOLS, non-flammable
· Transport hazard class(es)
·
DOT
·
Class 2 Gases
·
Label 2.2
·
ADR
·
Class 2 5A Gases
(Contd. on page 10)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
·
Label 2.2
·
IMDG
·
Class 2 Gases
·
Label 2.2
·
IATA
·
Class 2.2
·
Label 2.2
· Packing group
·
DOT, ADR, IMDG, IATA Not Regulated
· Environmental hazards:
·
Marine pollutant: No
·
Special precautions for user Warning: Gases
·
Danger code (Kemler): -
·
EMS Number: F-D,S-U
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not
applicable.
·
Transport/Additional information:
·
DOT
·
Quantity limitations On passenger aircraft/rail: 75kg
On cargo aircraft only:
150kg
(Contd. of page 9)
·
ADR
·
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
·
IMDG
·
Limited quantities (LQ) 1L
·
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
·
UN "Model Regulation": UN1950, Aerosols, 2.2
15 Regulatory information
·
Safety, health and environmental regulations/legislation specific for the substance or mixture
· SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
(Contd. on page 11)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
(Contd. of page 10)
·
Section 313 (Specific toxic chemical listings):
111-76-2
2-butoxyethanol
67-63-0
propan-2-ol
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California)
·
Chemicals known to cause cancer:
None of the ingredients are listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
·
Carcinogenic categories
·
EPA (Environmental Protection Agency)
111-76-2
2-butoxyethanol
NL
·
IARC (International Agency for Research on Cancer)
111-76-2
2-butoxyethanol
3
67-63-0
propan-2-ol
3
·
TLV (Threshold Limit Value established by ACGIH)
111-76-2
2-butoxyethanol
A3
67-63-0
propan-2-ol
A4
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
State Right to Know Listings
Some ingredients listed.
·
Canadian substance listings:
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
·
Canadian Ingredient Disclosure list (limit 1%)
111-76-2
2-butoxyethanol
112-34-5
2-(2-butoxyethoxy)ethanol
67-63-0
propan-2-ol
·
Other regulations, limitations and prohibitive regulations
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the SDS contains all the information required by the Controlled Products Regulations.
(Contd. on page 12)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 11/24/2014
Trade name: Eliminator Carpet Spot Cleaner
·
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
(Contd. of page 11)
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Date of preparation / last revision 11/24/2014 / -
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
VOC: Volatile Organic Compounds (USA, EU)
Flam. Gas 1: Flammable gases, Hazard Category 1
Press. Gas: Gases under pressure: Compressed gas
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Flam. Liq. 4: Flammable liquids, Hazard Category 4
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
· Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
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