Page 1
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 07/08/2016
1 Identification
·
Product identifier
·
Trade name: Graffiti & Spray Paint Remover
·
Article number: 078
·
Application of the substance / the mixture Graffiti remover
·
Details of the supplier of the Safety Data Sheet
· Manufacturer/Supplier:
ITW Pro Brands
805 East Old 56 Highway
Olathe, Kansas 66061
Phone: 1-800-224-4860
·
Emergency telephone number: Infotrac Emergency Hotline: 1-800-535-5053
2 Hazard(s) identification
·
Classification of the substance or mixture
GHS 04 gas cylinder
H280 Contains gas under pressure; may explode if heated.
GHS02 Flame
Flam. Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurized container: May burst if heated.
GHS08 Health hazard
Repr. 2
H361
Suspected of damaging fertility or the unborn child. Route of exposure:
Inhalative.
STOT RE 2
H373
May cause damage to the central nervous system through prolonged or
repeated exposure. Route of exposure: Inhalative.
Asp. Tox. 1
H304 May be fatal if swallowed and enters airways.
GHS07
Skin Irrit. 2
H315
Causes skin irritation.
STOT SE 3
H336
May cause drowsiness or dizziness.
·
Label elements
· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
·
Hazard pictograms
GHS02 GHS07 GHS08
(Contd. of page 1)
·
Signal word Danger
·
Hazard-determining components of labeling:
toluene
· Hazard statements
H280 Contains gas under pressure; may explode if heated.
H222-H229 Extremely flammable aerosol. Pressurized container: May burst if heated.
H315 Causes skin irritation.
H361 Suspected of damaging fertility or the unborn child. Route of exposure: Inhalative.
H336 May cause drowsiness or dizziness.
H373 May cause damage to the centr al nervous system through prolonged or repeated exposure.
Route of exposure: Inhalative.
H304 May be fatal if swallowed and enters airways.
· Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P251 Pressurized container: Do not pierce or burn, even after use.
P260 Do not breathe mist/vapours/spray.
P211 Do not spray on an open flame or other ignition source.
P281 Use personal protective equipment as required.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P302+P352 If on skin: Wash with plenty of water.
P405 Store locked up.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
·
Additional information: Pressurized container: May burst if heated.
· Hazard description:
· WHMIS-symbols:
A - Compressed gas
B5 - Flammable aerosol
D2A - Very toxic material causing other toxic effects
·
Classification system:
·
NFPA ratings (scale 0 - 4)
Health =
1
4
Fire = 4
1 0
Reactivity = 0
(Contd. on page 3)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
·
HMIS-ratings (scale 0 - 4)
(Contd. of page 2)
HEALTH
FIRE
*1
Health = *1
4
Fire = 4
REACTIVITY 0
Reactivity = 0
* - Indicates a long term health hazard from repeated or prolonged exposures.
· Other hazards
· Results of PBT and vPvB assessment
·
PBT: Not applicable.
·
vPvB: Not applicable.
3
Composition/information
on ingredients
·
Chemical characterization: Mixtures
·
Description: Mixture of the substances listed below with nonhazardous additions.
·
Dangerous components:
108-88-3
toluene
20-40%
Flam. Liq. 2, H225
Repr. 2, H361; STOT RE 2, H373; Asp. Tox. 1, H304
Skin Irrit. 2, H315; STOT SE 3, H336
75-28-5
Isobutane
10-20%
Flam. Gas 1, H220
111-76-2
2-butoxyethanol
1-5%
Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2,
H315; Eye Irrit. 2, H319
Flam. Liq. 4, H227
74-98-6
propane
1-5%
Flam. Gas 1, H220
Press. Gas, H280
71011-25-1
Alkyl Quaternary ammonium bentonite
1-5%
Eye Irrit. 2A, H319
4 First-aid measures
·
Description of first aid measures
·
General information: Take affected persons out into the fresh air.
· After inhalation:
Supply fresh air; consult doctor in case of complaints.
Provide oxygen treatment if affected person has difficulty breathing.
In case of irregular breathing or respiratory arrest provide artificial respiration.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
In cases of frostbite, rinse with plenty of water. Do not remove clothing.
(Contd. on page 4)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
·
After eye contact:
Remove contact lenses if worn.
(Contd. of page 3)
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Unlikely route of exposure.
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; immediately call for medical help.
· Most important symptoms and effects, both acute and delayed
Headache
Dizziness
Nausea
Gastric or intestinal disorders when ingested.
Breathing difficulty
Allergic reactions
Coughing
Irritant to skin and mucous membranes.
Slight irritant effect on eyes.
Disorientation
· Danger
Danger of impaired breathing.
Vapours may cause drowsiness and dizziness.
May damage fertility or the unborn child. Route of exposure: Inhalative. Route of exposure: Inhalative.
Danger of disturbed cardiac rhythm.
Danger of pulmonary edema.
Condition may deteriorate with alcohol consumption.
Repeated exposure may cause skin dryness or cracking.
Danger of serious damage to health by prolonged exposure.
· Indication of any immediate medical attention and special treatment needed
If swallowed, gastric irrigation with added, activated carbon.
If necessary oxygen respiration treatment.
Medical supervision for at least 48 hours.
If swallowed or in case of vomiting, danger of entering the lungs.
Treat skin and mucous membrane with antihistamine and corticoid preparations.
5 Fire-fighting measures
·
Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
·
For safety reasons unsuitable extinguishing agents: Water stream.
· Special hazards arising from the substance or mixture
Danger of receptacles bursting because of high vapor pressure if heated.
Formation of toxic gases is possible during heating or in case of fire.
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Additional information
Eliminate all ignition sources if safe to do so.
(Contd. on page 5)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
Cool endangered product with water spray.
(Contd. of page 4)
6 Accidental release measures
·
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
If containers are leaking, use respiratory protective device against the effects of fumes/dust/aerosol.
Ensure adequate ventilation.
Keep away from ignition sources.
·
Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Allow to evaporate.
Absorb liquid components with liquid-binding material.
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Send for recovery or disposal in suitable receptacles.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
·
Precautions for safe handling
Keep away from heat and direct sunlight.
Use only in well ventilated areas.
Pressurized container: Do not pierce or burn, even after use.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Fumes can combine with air to form an explosive mixture.
Flammable gas-air mixtures may be formed in empty receptacles.
Do not spray on a naked flame or any incandescent material.
·
Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressurized containers.
Provide ventilation for receptacles.
Avoid storage near extreme heat, ignition sources or open flame.
· Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidizing agents.
· Further information about storage conditions:
Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting.
(Contd. on page 6)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
·
Specific end use(s) No further relevant information available.
(Contd. of page 5)
8 Exposure controls/personal protection
·
Additional information about design of technical systems: No further data; see item 7.
·
Control parameters
·
Components with limit values that require monitoring at the workplace:
108-88-3 toluene
PEL (USA)
REL (USA)
TLV (USA)
EL (Canada)
EV (Canada)
LMPE (Mexico)
Long-term value: 200 ppm
Ceiling limit value: 300; 500* ppm
*10-min peak per 8-hr shift
Short-term value: 560 mg/m³, 150 ppm
Long-term value: 375 mg/m³, 100 ppm
Long-term value: 75 mg/m³, 20 ppm
BEI
Long-term value: 20 ppm
R
Long-term value: 20 ppm
Long-term value: 20 ppm
A4, IBE
111-76-2 2-butoxyethanol
PEL (USA)
REL (USA)
TLV (USA)
EL (Canada)
EV (Canada)
LMPE (Mexico)
Long-term value: 240 mg/m³, 50 ppm
Skin
Long-term value: 24 mg/m³, 5 ppm
Skin
Long-term value: 97 mg/m³, 20 ppm
BEI
Long-term value: 20 ppm
Long-term value: 20 ppm
Skin
Long-term value: 20 ppm
A3, IBE
74-98-6 propane
PEL (USA)
REL (USA)
TLV (USA)
EL (Canada)
EV (Canada)
LMPE (Mexico)
Long-term value: 1800 mg/m³, 1000 ppm
Long-term value: 1800 mg/m³, 1000 ppm
refer to Appendix F
Long-term value: 1000 ppm
Long-term value: 1.000 ppm
Long-term value: 1000 ppm
(Contd. on page 7)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
(Contd. of page 6)
·
Ingredients with biological limit values:
108-88-3 toluene
BEI (USA)
0.02 mg/L
Medium: blood
Time: prior to last shift of workweek
Parameter: Toluene
0.03 mg/L
Medium: urine
Time: end of shift
Parameter: Toluene
0.3 mg/g creatinine
Medium: urine
Time: end of shift
Parameter: o-Cresol with hydrolysis (background)
111-76-2 2-butoxyethanol
BEI (USA)
200 mg/g creatinine
Medium: urine
Time: end of shift
Parameter: Butoxyacetic acid with hydrolysis
·
Additional information: The lists that were valid during the creation were used as basis.
·
Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Pregnant women should strictly avoid inhalation or skin contact.
Avoid contact with the eyes and skin.
· Breathing equipment:
Suitable respiratory protective device recommended.
For spills, respiratory protection may be advisable.
Use suitable respiratory protective device in case of insufficient ventilation.
NIOSH or EN approved organic vapor respirator equipped with a dust/mist prefilter should be used.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
·
Material of gloves
(Contd. on page 8)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
(Contd. of page 7)
The selection of the suitable gloves does not only depen d on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
· Eye protection:
Safety glasses
·
Body protection: Protective work clothing
· Limitation and supervision of exposure into the environment
No further relevant information available.
9 Physical and chemical properties
·
Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Color: Light Tan
·
Odor: Aromatic
·
Odor threshold: Not determined.
·
pH-value: 6.3 - 7.3
·
Change in condition
Melting point/Melting range:
Undetermined.
Boiling point/Boiling range: Not applicable, as aerosol.
·
Flash point: < 2 °C (< 36 °F) (liquid)
·
Flammability (solid, gaseous): Not applicable.
·
Auto-ignition temperature: Not determined.
·
Decomposition temperature: Not determined.
·
Auto igniting: Product is not self-igniting.
·
Danger of explosion: Product is not explosive. However, formation of explosive air/
vapor mixtures are possible.
·
Explosion limits:
Lower: Not determined.
Upper: Not determined.
·
Vapor pressure at 21 °C (70 °F): 125 psig
·
Density at 21 °C (70 °F): 0.94 g/cm³ (7.844 lbs/gal)
·
Relative density Not determined.
·
Vapour density > 1 (Air=1)
(Contd. on page 9)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
·
Evaporation rate Not applicable.
·
Solubility in / Miscibility with
Water: Fully miscible.
·
Partition coefficient (n-octanol/water): Not determined.
·
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
·
Solvent content:
VOC content: 49.6 %
·
Other information No further relevant information available.
(Contd. of page 8)
10 Stability and reactivity
·
Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Danger of receptacles bursting because of high vapor pressure if heated.
· Possibility of hazardous reactions
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomized.
Extremely flammable aerosol.
Used empty containers may contain product gases which form explosive mixtures with air.
Toxic fumes may be released if heated above the decomposition point.
Reacts violently with oxidizing agents.
Danger of receptacles bursting because of high vapor pressure if heated.
· Conditions to avoid
Keep away from heat and direct sunlight.
Keep ignition sources away - Do not smoke.
Store away from oxidizing agents.
·
Incompatible materials: No further relevant information available.
· Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Hydrocarbons
Nitrogen oxides
11 Toxicological information
·
Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values that are relevant for classification:
108-88-3 toluene
Oral
Dermal
Inhalative
LD50
LD50
LC50/4h
5000 mg/kg (rat)
12124 mg/kg (rabbit)
5320 mg/l (mouse)
(Contd. on page 10)
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Safety Data Sheet
acc. to HCS and GHS
Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
·
Primary irritant effect:
·
on the skin: Irritant to skin and mucous membranes.
·
on the eye: Slight irritant effect on eyes.
·
Sensitization: No sensitizing effects known.
·
Additional toxicological information:
(Contd. of page 9)
The product shows the following dangers according to internally approved calculation methods for
preparations:
Irritant
Inhalation of concentrated vapors as well as oral intake will lead to an aesthesia-li ke conditions and
headache, dizziness, etc.
Toxic and/or corrosive effects may be delayed up to 24 hours.
Suspected of damaging fertility or the unborn child. Route of exposure: Inhalative. Rou te of exposure:
Inhalative.
·
Carcinogenic categories
·
NTP (National Toxicology Program)
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
· Repeated Dose Toxicity:
May cause damage to organs through prolonged or repeated exposure.
12 Ecological information
·
Toxicity
·
Aquatic toxicity: No further relevant information available.
·
Persistence and degradability The product is partially biodegradable. Significant residuals remain.
·
Bioaccumulative potential No further relevant information available.
·
Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Avoid transfer into the environment.
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· Results of PBT and vPvB assessment
·
PBT: Not applicable.
·
vPvB: Not applicable.
·
Other adverse effects No further relevant information available.
13 Disposal
considerations
·
Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Contact waste processors for recycling information.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous.
(Contd. on page 11)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
·
Waste disposal key: EPA RCRA Code (USA) : D001
·
Uncleaned packagings:
·
Recommendation: Disposal must be made according to official regulations.
(Contd. of page 10)
14 Transport
information
·
UN-Number
·
DOT, ADR, IMDG, IATA UN1950
· UN proper shipping name
Limited Quantity for packages less than 30 kg (66 lb) and inner packagings less than 1 L (0.3
gal).
·
DOT Aerosols, flammable
·
ADR 1950 AEROSOLS, flammable
·
IMDG AEROSOLS
·
IATA AEROSOLS, flammable
· Transport hazard class(es)
·
DOT
·
Class
2.1
·
Label
2.1
·
ADR
·
Class 2 5F Gases
·
Label 2.1
·
IMDG
·
Class 2 Gases
·
Label 2.1
·
IATA
·
Class 2.1
·
Label 2.1
(Contd. on page 12)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
·
Packing group
·
DOT, ADR, IMDG, IATA Not Regulated
· Environmental hazards:
·
Marine pollutant: No
·
Special precautions for user Warning: Gases
·
Danger code (Kemler): -
·
EMS Number: F-D,S-U
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not
applicable.
·
Transport/Additional information:
·
DOT
·
Quantity limitations On passenger aircraft/rail: 75kg
On cargo aircraft only:
150kg
(Contd. of page 11)
·
ADR
·
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
·
IMDG
·
Limited quantities (LQ) 1000mL
·
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
·
UN "Model Regulation": UN1950, Aerosols, 2.1
15 Regulatory information
·
Safety, health and environmental regulations/legislation specific for the substance or mixture
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
108-88-3
toluene
111-76-2
2-butoxyethanol
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California)
· Chemicals known to cause cancer:
Present in trace
quantities.
14808-60-7
Quartz (SiO2)
·
Chemicals known to cause reproductive toxicity for females:
108-88-3
toluene
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
(Contd. on page 13)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
·
Chemicals known to cause developmental toxicity:
108-88-3 toluene
·
Carcinogenic categories
(Contd. of page 12)
·
EPA (Environmental Protection Agency)
108-88-3
toluene
II
111-76-2
2-butoxyethanol
NL
·
IARC (International Agency for Research on Cancer)
108-88-3
toluene
3
111-76-2
2-butoxyethanol
3
·
TLV (Threshold Limit Value established by ACGIH)
108-88-3
toluene
A4
111-76-2
2-butoxyethanol
A3
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
State Right to Know Listings
Some ingredients listed.
·
Canadian substance listings:
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
·
Canadian Ingredient Disclosure list (limit 1%)
108-88-3
toluene
111-76-2
2-butoxyethanol
·
Other regulations, limitations and prohibitive regulations
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the SDS contains all the information required by the Controlled Products Regulations.
· Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Date of preparation / last revision 11/24/2014 / -
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
(Contd. on page 14)
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Safety Data Sheet
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Printing date 11/24/2014
Reviewed on 07/08/2016
Trade name: Graffiti & Spray Paint Remover
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Flam. Gas 1: Flammable gases, Hazard Category 1
Flam. Aerosol 1: Flammable aerosols, Hazard Category 1
Press. Gas: Gases under pressure: Compressed gas
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Flam. Liq. 4: Flammable liquids, Hazard Category 4
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
Repr. 2: Reproductive toxicity, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
· Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
(Contd. of page 13)
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