Dupli-Color DE1635 User Manual

DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
Not available. Aerosol.
(216) 566-2917
SAFETY DATA SHEET
Section 1. Identification
:
:::
:
Dupli-Color Products Company Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
DE1635
DE1635
:
:
(800) 247-3270
:
(216) 566-2902
:
(800) 424-9300
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1 ASPIRATION HAZARD - Category 1
:
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute oral toxicity:
14.3% Percentage of the mixture consisting of ingredient(s) of unknown acute dermal toxicity:
22.6% Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation toxicity: 56.3%
:
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:201/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 2. Hazards identification
Signal word
:
Danger
Hazard pictograms
:
Precautionary statements
Prevention
:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Pressurized container: Do not pierce or burn, even after use.
Response
:
Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage
:
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.
Disposal
Dispose of contents and container in accordance with all local, regional, national and international regulations.
General
:
Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
:
DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations.
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. Suspected of damaging the unborn child. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. Causes damage to organs through prolonged or repeated exposure. (lungs)
:
Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.
Supplemental label elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
:
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:202/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 3. Composition/information on ingredients
Methyl Acetate
≥25 - ≤50
79-20-9
Isobutyl Acetate
≥10 - ≤25
110-19-0
Propane
≥10 - ≤25
74-98-6
Butane
≥10 - ≤25
106-97-8
Toluene
≤10
108-88-3
2-methoxy-1-methylethyl acetate
≤10
108-65-6
Talc≤314807-96-6
Carbon Black
≤1
1333-86-4
Xylene, mixed isomers
≤0.3
1330-20-7
Methyl Ethyl Ketoxime
≤0.3
96-29-7
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
:
Not available.
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Causes serious eye irritation.
:
Eye contact
Potential acute health effects
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:203/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.
:
Ingestion Skin contact
:
Causes skin irritation. May cause an allergic skin reaction.
Over-exposure signs/symptoms
Skin contact Ingestion
Inhalation
Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations
Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations
Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations
:
:
:
Eye contact
:
Adverse symptoms may include the following: pain or irritation watering redness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:204/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides
Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
: :
:
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
:
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill
:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:205/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 7. Handling and storage
Advice on general occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures
Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure ­obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.
:
Precautions for safe handling
Methyl Acetate
79-20-9
ACGIH TLV (United States, 3/2019).
TWA: 200 ppm 8 hours. TWA: 606 mg/m³ 8 hours. STEL: 250 ppm 15 minutes. STEL: 757 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 200 ppm 10 hours. TWA: 610 mg/m³ 10 hours. STEL: 250 ppm 15 minutes. STEL: 760 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 200 ppm 8 hours. TWA: 610 mg/m³ 8 hours.
Isobutyl Acetate
110-19-0
NIOSH REL (United States, 10/2016).
TWA: 150 ppm 10 hours. TWA: 700 mg/m³ 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 150 ppm 8 hours. TWA: 700 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2019).
STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours.
Propane
74-98-6
NIOSH REL (United States, 10/2016).
TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:206/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
OSHA PEL (United States, 5/2018).
TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2019). Oxygen Depletion [Asphyxiant]. Explosive potential.
Butane
106-97-8
NIOSH REL (United States, 10/2016).
TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 3/2019). Explosive potential.
STEL: 1000 ppm 15 minutes.
Toluene
108-88-3
OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours. TWA: 375 mg/m³ 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours. 2-methoxy-1-methylethyl acetate
108-65-6
AIHA WEEL (United States, 7/2018).
TWA: 50 ppm 8 hours.
Talc
14807-96-6
NIOSH REL (United States, 10/2016).
TWA: 2 mg/m³ 10 hours. Form: Respirable fraction
ACGIH TLV (United States, 3/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable fraction
Carbon Black
1333-86-4
NIOSH REL (United States, 10/2016).
TWA: 3.5 mg/m³ 10 hours. TWA: 0.1 mg of PAHs/cm³ 10 hours.
ACGIH TLV (United States, 3/2019).
TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction
OSHA PEL (United States, 5/2018).
TWA: 3.5 mg/m³ 8 hours.
Xylene, mixed isomers
1330-20-7
ACGIH TLV (United States, 3/2019).
TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.
Methyl Ethyl Ketoxime
96-29-7
AIHA WEEL (United States, 7/2018). Skin sensitizer.
TWA: 10 ppm 8 hours.
Occupational exposure limits (Canada)
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:207/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Methyl acetate
79-20-9
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 606 mg/m³ 8 hours. 15 min OEL: 757 mg/m³ 15 minutes. 15 min OEL: 250 ppm 15 minutes. 8 hrs OEL: 200 ppm 8 hours.
CA British Columbia Provincial (Canada, 5/2019).
TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes.
CA Ontario Provincial (Canada, 1/2018).
TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 200 ppm 8 hours. TWAEV: 606 mg/m³ 8 hours. STEV: 250 ppm 15 minutes. STEV: 757 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 250 ppm 15 minutes. TWA: 200 ppm 8 hours.
Isobutyl acetate
110-19-0
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 150 ppm 8 hours. 8 hrs OEL: 713 mg/m³ 8 hours.
CA British Columbia Provincial (Canada, 5/2019).
TWA: 150 ppm 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 150 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 150 ppm 8 hours. TWAEV: 713 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 188 ppm 15 minutes. TWA: 150 ppm 8 hours.
Normal propane
74-98-6
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 1000 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 1000 ppm 8 hours. TWAEV: 1800 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 1000 ppm 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours.
CA British Columbia Provincial (Canada, 5/2019). Oxygen Depletion [Asphyxiant]. Explosive potential.
Butane
106-97-8
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 1000 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 800 ppm 8 hours. TWAEV: 1900 mg/m³ 8 hours.
Ingredient name
Exposure limits
CAS #
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:208/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
CA Ontario Provincial (Canada, 1/2018).
TWA: 800 ppm 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours.
CA British Columbia Provincial (Canada, 5/2019). Explosive potential.
STEL: 1000 ppm 15 minutes.
Toluene
108-88-3
CA Alberta Provincial (Canada, 6/2018). Absorbed through skin.
8 hrs OEL: 50 ppm 8 hours. 8 hrs OEL: 188 mg/m³ 8 hours.
CA British Columbia Provincial (Canada, 5/2019).
TWA: 20 ppm 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 20 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014). Absorbed through skin.
TWAEV: 50 ppm 8 hours. TWAEV: 188 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013). Absorbed through skin.
STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours.
talc (none asbestiform)
14807-96-6
CA British Columbia Provincial (Canada, 5/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable TWA: 0.1 f/cc 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 3 mg/m³ 8 hours. Form: Respirable dust.
CA Ontario Provincial (Canada, 1/2018).
TWA: 2 mg/m³ 8 hours. Form: Respirable fraction. TWA: 2 f/cc 8 hours.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m³ 8 hours. Form: Respirable particulate
CA Saskatchewan Provincial (Canada, 7/2013).
TWA: 2 mg/m³ 8 hours. Form: respirable fraction
Carbon black
1333-86-4
CA British Columbia Provincial (Canada, 5/2019).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
CA Ontario Provincial (Canada, 1/2018).
TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 3.5 mg/m³ 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 3.5 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 7 mg/m³ 15 minutes.
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:209/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
TWA: 3.5 mg/m³ 8 hours.
Xylene
1330-20-7
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours.
CA British Columbia Provincial (Canada, 5/2019).
TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes.
CA Ontario Provincial (Canada, 1/2018).
STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours.
Methyl Ethyl Ketoxime
96-29-7
AIHA WEEL (United States, 7/2018). Skin sensitizer.
TWA: 10 ppm 8 hours.
Kaolin
1332-58-7
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m³ 8 hours. Form: Respirable
CA British Columbia Provincial (Canada, 5/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 5 mg/m³ 8 hours. Form: Respirable dust.
CA Ontario Provincial (Canada, 1/2018).
TWA: 2 mg/m³ 8 hours. Form: Respirable fraction.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 4 mg/m³ 15 minutes. Form: respirable fraction TWA: 2 mg/m³ 8 hours. Form: respirable fraction
Methyl Acetate
79-20-9
NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes.
Isobutyl Acetate
110-19-0
NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 150 ppm 8 hours.
Propane
74-98-6
NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 1000 ppm 8 hours.
Butane
106-97-8
NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 1000 ppm 8 hours.
Toluene
108-88-3
NOM-010-STPS-2014 (Mexico, 4/2016).
Exposure limits
Occupational exposure limits (Mexico)
CAS #
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2010/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti­static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
:
Individual protection measures
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Environmental exposure controls
:
TWA: 20 ppm 8 hours.
Section 9. Physical and chemical properties
Physical state
Liquid.
Not available.
Not available.
Not available.
Color
Not available.
Not available.
:::
:::
Appearance
:
Not available.
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2011/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 9. Physical and chemical properties
0.78
1.55 [Air = 1]
101.3 kPa (760 mm Hg) [at 20°C]
Not available.
5.3 (butyl acetate = 1)
Not available.
Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Not available.
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
:
:
:
:::
:::
:
Not available.
:
Lower: 1% Upper: 16%
:
Not available.
Type of aerosol
:
Spray
Heat of combustion
:
32.635 kJ/g
Aerosol product
:
Not applicable.
Section 10. Stability and reactivity
Avoid all possible sources of ignition (spark or flame).
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.
No specific data.
:
:
:
Incompatible materials
:
:
Under normal conditions of storage and use, hazardous reactions will not occur.
:
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Methyl Acetate
LD50 Dermal
Rabbit
>5 g/kg
-
LD50 Oral
Rat
>5 g/kg
-
Isobutyl Acetate
LD50 Dermal
Rabbit
>17400 mg/kg
-
LD50 Oral
Rat
13400 mg/kg
-
Butane
LC50 Inhalation Vapor
Rat
658000 mg/m³
4 hours
Toluene
LC50 Inhalation Vapor
Rat
49 g/m³
4 hours
LD50 Oral
Rat
636 mg/kg
-
2-methoxy-1-methylethyl acetate
LD50 Dermal
Rabbit
>5 g/kg
-
LD50 Oral
Rat
8532 mg/kg
-
Carbon Black
LD50 Oral
Rat
>15400 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Information on toxicological effects
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2012/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 11. Toxicological information
Xylene, mixed isomers
LC50 Inhalation Gas.
Rat
5000 ppm
4 hours
LD50 Oral
Rat
4300 mg/kg
-
Methyl Ethyl Ketoxime
LD50 Oral
Rat
930 mg/kg
-
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Reproductive toxicity
Not available.
Irritation/Corrosion
Methyl Acetate
Eyes - Moderate irritant
Rabbit
-
24 hours 100 mg
-
Skin - Mild irritant
Rabbit
-
24 hours 500 mg
-
Skin - Moderate irritant
Rabbit
-
24 hours 20 mg
-
Isobutyl Acetate
Eyes - Moderate irritant
Rabbit
-
24 hours 500 mg
-
Skin - Mild irritant
Rabbit
-
500 mg
-
Skin - Moderate irritant
Rabbit
-
24 hours 500 mg
-
Toluene
Eyes - Mild irritant
Rabbit
-
0.5 minutes 100 mg
-
Eyes - Mild irritant
Rabbit
-
870 ug
-
Eyes - Severe irritant
Rabbit
-
24 hours 2 mg
-
Skin - Mild irritant
Pig
-
24 hours 250 Ul
-
Skin - Mild irritant
Rabbit
-
435 mg
-
Skin - Moderate irritant
Rabbit
-
24 hours 20 mg-Skin - Moderate irritant
Rabbit
-
500 mg
-
Talc
Skin - Mild irritant
Human
-
72 hours 300 ug I
-
Xylene, mixed isomers
Eyes - Mild irritant
Rabbit
-
87 mg
-
Eyes - Severe irritant
Rabbit
-
24 hours 5 mg
-
Skin - Mild irritant
Rat-8 hours 60 Ul
-
Skin - Moderate irritant
Rabbit
-
24 hours 500 mg
-
Skin - Moderate irritant
Rabbit
-
100 %
-
Methyl Ethyl Ketoxime
Eyes - Severe irritant
Rabbit
-
100 Ul
-
Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Not available.
Species
Classification
Toluene
-3-
Talc-3
-
Carbon Black
-2B-
Xylene, mixed isomers
-3-
Product/ingredient name
NTP
IARC
OSHA
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2013/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 11. Toxicological information
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Methyl Acetate
Category 3
Not applicable.
Narcotic effects
Isobutyl Acetate
Category 3
Not applicable.
Narcotic effects
Propane
Category 3
Not applicable.
Narcotic effects
Category 3
Not applicable.
Respiratory tract irritation
Butane
Category 3
Not applicable.
Narcotic effects
Category 3
Not applicable.
Respiratory tract irritation
Toluene
Category 3
Not applicable.
Narcotic effects
Category 3
Not applicable.
Respiratory tract irritation
2-methoxy-1-methylethyl acetate
Category 3
Not applicable.
Narcotic effects
Xylene, mixed isomers
Category 3
Not applicable.
Respiratory tract irritation
Name
Category
Name
Category
Propane
Category 2
Not determined
Not determined
Butane
Category 2
Not determined
Not determined
Toluene
Category 2
Not determined
Not determined
Talc
Category 1
Inhalation
lungs
Xylene, mixed isomers
Category 2
Not determined
Not determined
Aspiration hazard
Name
Result
Propane
ASPIRATION HAZARD - Category 1
Butane
ASPIRATION HAZARD - Category 1
Toluene
ASPIRATION HAZARD - Category 1
Xylene, mixed isomers
ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.
:
Ingestion
Skin contact
:
Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
:
Adverse symptoms may include the following: pain or irritation watering redness
:
Not available.
Potential acute health effects
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2014/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General
:
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
Suspected of damaging the unborn child.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations
Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations
Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations
:
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral
6585.73 mg/kg
Route
ATE value
Acute toxicity estimates
Potential immediate effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2015/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 12. Ecological information
BCF
Potential
Bioaccumulative potential
:
No known significant effects or critical hazards.
Product/ingredient name
Toluene
-90low
Xylene, mixed isomers
-
8.1 to 25.9
low
Methyl Ethyl Ketoxime
-
2.5 to 5.8
low
Product/ingredient name
Photolysis
Biodegradability
Toluene
--Readily
Xylene, mixed isomers
--Readily
Toxicity
Methyl Acetate
Acute LC50 320000 µg/l Fresh water
Fish - Pimephales promelas
96 hours
Toluene
Acute EC50 12500 µg/l Fresh water
Algae - Pseudokirchneriella subcapitata
72 hours
Acute EC50 11600 µg/l Fresh water
Crustaceans - Gammarus pseudolimnaeus - Adult
48 hours
Acute EC50 6000 µg/l Fresh water
Daphnia - Daphnia magna ­Juvenile (Fledgling, Hatchling, Weanling)
48 hours
Acute LC50 5500 µg/l Fresh water
Fish - Oncorhynchus kisutch - Fry
96 hours
Chronic NOEC 1000 µg/l Fresh water
Daphnia - Daphnia magna
21 days
Xylene, mixed isomers
Acute LC50 8500 µg/l Marine water
Crustaceans - Palaemonetes pugio
48 hours
Acute LC50 13400 µg/l Fresh water
Fish - Pimephales promelas
96 hours
Methyl Ethyl Ketoxime
Acute LC50 843000 µg/l Fresh water
Fish - Pimephales promelas
96 hours
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
:
Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.
:
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2016/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 14. Transport information
AEROSOLS
2.1
-
AEROSOLS
2.1
-
UN1950
UN1950
-
Emergency schedules
F-D, S-
U
DOT
Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Transport in bulk according to Annex II of MARPOL and the IBC Code
No.
No. Not available.
:
Proper shipping name
:
Ship type
:
Not available.
Pollution category
:
Not available.
Not available.
:
TDG
Classification
UN1950
AEROSOLS
2.1
-
No.
Product classified as per the following sections of the Transportation of Dangerous Goods Regulations:
2.13-2.17 (Class
2).
Mexico
Classification
UN1950
AEROSOLS
2.1
-
No.
­Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
UN1950
AEROSOLS, flammable
2.1
-
No.
-
126
ERG No.
126
126
ERG No.
ERG No.
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
International regulations
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2017/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 15. Regulatory information
Australia inventory (AICS)
: Not determined.
China inventory (IECSC)
: Not determined.
Japan inventory (ENCS)
: Not determined.
Japan inventory (ISHL)
: Not determined.
Korea inventory (KECI)
: Not determined.
New Zealand Inventory of Chemicals (NZIoC)
: Not determined.
Philippines inventory (PICCS)
: Not determined.
Taiwan Chemical Substances Inventory (TCSI)
: Not determined.
Thailand inventory
: Not determined.
Turkey inventory
: Not determined.
Vietnam inventory
: Not determined.
:
Section 16. Other information
5/12/2020
History
Date of printing
Date of issue/Date of revision
Version
Date of previous issue
:
:::
5/12/2020
11/26/2019
20
Hazardous Material Information System (U.S.A.)
3
4
3
*
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
FLAMMABLE AEROSOLS - Category 1
On basis of test data
GASES UNDER PRESSURE - Compressed gas
Calculation method
SKIN CORROSION/IRRITATION - Category 2
Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
Calculation method
SKIN SENSITIZATION - Category 1
Calculation method
CARCINOGENICITY - Category 2
Calculation method
TOXIC TO REPRODUCTION (Unborn child) - Category 2
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Calculation method
ASPIRATION HAZARD - Category 1
Calculation method
Procedure used to derive the classification
Classification
Justification
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2018/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Indicates information that has changed from previously issued version.
Key to abbreviations
:
Notice to reader
ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations
Date of issue/Date of revision
:
5/12/2020
Date of previous issue
:
11/26/2019
Version
:2019/19
DE1635
DUPLI-COLOR™ Engine Enamel with Ceramic Ford Semi-Gloss Black
SHW-85-NA-GHS-US
Loading...