Page 1/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
SECTION 1: Identific ation of the substance/mixture and of the company/
undertaking
·
1.1 Product identifier
·
Trade name: Duck Brand Adhesive Remover
·
Article number:
·
CAS Number:
64742-47-8
·
EC number:
265-149-8
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
ShurTech Brands LLC
32150 Just Imagine Dr
Avon, Ohio 44011
(440) 937-7000
askus@shurtech.com
·
1.4 Emergency telephone number:
313770; 527263; 994614
Adhesive remover
Rocky Mountain Poison and Drug Center: 800-222-1222
SECTION 2: Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
Clas s ific a tion s lis ted are appli c able to the OSHA GH S Ha za r d Co mm unic a tion Stan d ard
(29CFR1910.1200).
The following Hazard Statements are applicable only according to OSHA regulations within the United
States. These Statements are not applicable for the CLP regulation (1272/2008/EC) in the EU: H227.
Flamm. Liq. 4
H227: Combustible Liquid.
health hazard
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
·
Additional information:
There are no other hazards not otherwise classified that have been identified.
0 % of the mixture consists of component(s) of unknown toxicity.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is additionally classified and labelled according to the Globally Harmonized System within the
United States (GHS).
The substance is classified and labelled according to the CLP regulation.
(Cont'd. on page 2)
41.0
Page 2/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
(Cont'd. from page 1)
·
Hazard pictograms
GHS08
·
Signal word
·
Hazard-determining components of labelling:
Distillates (petroleum), hydrotreated light
·
Hazard statements
The following Hazard Statements are applicable only according to OSHA regulations within the United
States. These Statements are not applicable for the CLP regulation (1272/2008/EC) in the EU: H227.
H227 Combustible liquid.
H304 May be fatal if swallowed and enters airways.
·
Precautionary statements
The following Precautionary Statements are applicable only to the OSHA GHS regulations and not the
specific CLP regulation: P210, P370+P378, P403+P235.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
P280 Wear protective gloves / eye protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P370+P378 In case of fire: Use foam, powder, or carbon dioxide for extinction.
P331 Do NOT induce vomiting.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/international
·
NFPA ratings (scale 0 - 4)
120
Danger
smoking.
regulations.
Health = 1
Fire = 2
Reactivity = 0
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
·
HMIS Long Term Health Hazard Substances
1
Health = 1
2
Fire = 2
0
Reactivity = 0
Substance is not listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
41.0
Not applicable.
(Cont'd. on page 3)
Page 3/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
(Cont'd. from page 2)
SECTION 3: Composition/information on ingredients
·
3.1 Substances
·
CAS No. Description
64742-47-8 Distillates (petroleum), hydrotreated light
·
Identification number(s)
·
EC number:
·
Index number:
SECTION 4: First aid measures
·
4.1 Description of first aid measures
·
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
Take affected persons out into the fresh air.
·
After inhalation:
Supply fresh air; consult doctor in case of complaints.
Provide oxygen treatment if affected person has difficulty breathing.
In case of unconsciousness place patient stably in side position for transportation.
·
After skin contact:
Immediately remove any clothing soiled by the product.
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
A person vomiting while laying on their back should be turned onto their side.
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Headache
Breathing difficulty
Coughing
Slight irritant effect on eyes.
Slight irritant effect on skin and mucous membranes.
Gastric or intestinal disorders when ingested.
Nausea in case of ingestion.
·
Hazards
·
4.3 Indication of any immediate medical attention and special treatment needed
Medical supervision for at least 48 hours.
If swallowed or in case of vomiting, danger of entering the lungs.
If necessary oxygen respiration treatment.
Later observation for pneumonia and pulmonary oedema.
265-149-8
649-422-00-2
Danger of impaired breathing.
(Cont'd. on page 4)
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Page 4/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
(Cont'd. from page 3)
SECTION 5: Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
Foam
Fire-extinguishing powder
Carbon dioxide
Water haze or fog
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
Cool endangered receptacles with water fog or haze.
Water with full jet
SECTION 6: Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources.
Particular danger of slipping on leaked/spilled product.
·
6.2 Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
Prevent from spreading (e.g. by damming-in or oil barriers).
Inform respective authorities in case of seepage into water course or sewage system.
·
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Remove from the water surface (e.g. skim or suck off).
Send for recovery or disposal in suitable receptacles.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
·
7.1 Precautions for safe handling
Prevent formation of aerosols.
Avoid splashes or spray in enclosed areas.
Use only in well ventilated areas.
·
Information about fire - and explosion protection:
Combustible liquid.
(Cont'd. on page 5)
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Page 5/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
(Cont'd. from page 4)
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Avoid storage near extreme heat, ignition sources or open flame.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidising agents.
·
Further information about storage conditions:
·
7.3 Specific end use(s)
No further relevant information available.
SECTION 8: Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
64742-47-8 Distillates (petroleum), hydrotreated light
EL (Canada) Long-term value: 200 mg/m³
Skin
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes.
Avoid close or long term contact with the skin.
·
Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
For spills, respiratory protection may be advisable.
·
Protection of hands:
No further relevant information available.
No further relevant information available.
No further relevant information available.
Store in cool, dry conditions in well sealed receptacles.
No further data; see section 7.
Protective gloves
Wear protective gloves to handle contents of damaged or leaking units.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
(Cont'd. on page 6)
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Page 6/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
(Cont'd. from page 5)
·
Eye protection:
Safety glasses
·
Body protection:
·
Limitation and supervision of exposure into the environment
No further relevant information available.
SECTION 9: Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Auto/Self-ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Oxidising properties
·
Vapour pressure:
·
Density at 20 °C (68 °F):
·
Relative density
·
Vapour density
·
Evaporation rate at 20 °C (68 °F)
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
Oil resistant protective clothing
Liquid
Orange
Citrus.
Not determined.
Not determined.
-60 °C (-76 °F)
> 176 °C (> 349 °F)
76 - 93 °C (169 - 199 °F)
Not applicable.
Not determined.
Not determined.
Not determined.
Product does not present an explosion hazard.
Not determined.
Not determined.
Non-oxidising.
Not determined.
0,78 - 0,82 g/cm³ (6,509 - 6,843 lbs/gal)
Not determined.
Not determined.
< 1 (Butyl Acetate = 1)
Not miscible or difficult to mix.
Not determined.
(Cont'd. on page 7)
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Page 7/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
(Cont'd. from page 6)
·
Viscosity:
Dynamic:
Kinematic:
·
9.2 Other information
SECTION 10: Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Reacts with strong acids and oxidising agents.
Toxic fumes may be released if heated above the decomposition point.
Used empty containers may contain product gases which form explosive mixtures with air.
·
10.4 Conditions to avoid
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Hydrocarbons
Excessive heat and contact with oxidizers.
No further relevant information available.
Not determined.
Not determined.
No further relevant information available.
SECTION 11: Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity
·
LD/LC50 values relevant for classification:
·
Primary irritant effect:
·
Skin corrosion/irritation
·
Serious eye damage/irritation
·
Respiratory or skin sensitisation
·
Additional toxicological information:
Slight irritant effect on skin and mucous membranes.
Slight irritant effect on eyes.
No sensitising effects known.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
·
Repeated dose toxicity:
Possible risk of irreversible effects.
Repeated exposure may cause skin dryness or cracking.
·
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction):
·
Germ cell mutagenicity
·
Carcinogenicity
·
Reproductive toxicity
·
STOT-single exposure
·
STOT-repeated exposure
·
Aspiration hazard
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
May be fatal if swallowed and enters airways.
None.
(Cont'd. on page 8)
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Page 8/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
(Cont'd. from page 7)
SECTION 12: Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Ecotoxical effects:
·
Remark:
·
Additional ecological information:
·
General notes:
Due to mechanical actions of the product (e.g. agglutinations) damages may occur.
Water hazard class 1 (German Regulation) (Assessment by list): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
Not applicable.
No further relevant information available.
The product is partially biodegradable. Significant residuals remain.
No further relevant information available.
No further relevant information available.
No further relevant information available.
SECTION 13: Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Product is recyclable as a waste oil. Deliver unused and/or contaminated product to waste oil collectors.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous.
·
Uncleaned packaging:
·
Recommendation:
Disposal must be made according to local official regulations.
SECTION 14: Transport information
·
14.1 UN-Number
·
DOT
·
ADR, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT
·
ADR, IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT
NA1993
Not Regulated
COMBUSTIBLE LIQUID, N.O.S (petroleum distillates)
Not Regulated
·
Class
41.0
3 Flammable liquids.
(Cont'd. on page 9)
Page 9/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
(Cont'd. from page 8)
·
Label
·
ADR, ADN, IMDG, IATA
·
Class
·
14.4 Packing group
·
DOT
·
ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
Transport/Additional information:
·
DOT
·
UN "Model Regulation":
3
Not Regulated
III
Not Regulated
No
Not applicable.
Not applicable.
Transport labeling is not required for non-bulk single
package shipments by motor vehicle, rail car or aircraft.
Bulk packaging consists of a maxim um capacity of
greater than 450L (119 gallons) for a liquid and a
maximum net mass greater than 400kg (882 pounds)
for a solid.
-
SECTION 15: Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
Substance is not listed.
·
Section 313 (Specific toxic chemical listings):
Substance is not listed.
·
TSCA (Toxic Substances Control Act):
Substance is listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
Substance is not listed.
·
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
·
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
·
Chemicals known to cause developmental toxicity:
Substance is not listed.
(Cont'd. on page 10)
41.0
Page 10/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
(Cont'd. from page 9)
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
Substance is not listed.
·
IARC (International Agency for Research on Cancer)
Substance is not listed.
·
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
Substance is listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
Substance is not listed.
·
Canadian Ingredient Disclosure list (limit 1%)
Substance is not listed.
·
Directive 2012/18/EU
·
Named dangerous substances - ANNEX I
·
Other regulations, limitations and prohibitive regulations
Substance is not listed.
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the SDS contains all the information required by the Controlled Products Regulations.
·
Substances of very high concern (SVHC) according to REACH, Article 57
Substance is not listed.
·
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Abbreviations and acronyms:
ADR: Accord européen sur le tr ansport des marchandises dangereuses par Route (European Agree ment concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
(Cont'd. on page 11)
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Page 11/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date 08.07.2015 Revision: 08.07.2015
Trade name: Duck Brand Adhesive Remover
LD50: Lethal dose, 50 percent
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
(Cont'd. from page 10)
41.0
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