Drano 694768 User Manual

Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
Product name
:
DRANO® MAX GEL PRO-STRENGTH CLOG REMOVER
Recommended use
:
Drain Cleaner
Manufacturer, importer, supplier
:
S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236
Telephone
:
+18005585252
Emergency telephone number
:
24 Hour Medical Emergency Phone: (866)231-5406
24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300
Hazard classification
Hazard category
Hazards identification
Skin corrosion
Category 1B
Causes severe skin burns and eye damage.
Serious eye damage
Category 1
Causes serious eye damage.
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Globally Harmonized System (GHS) Classification
Labelling Hazard symbols
Corrosion
Signal word Danger
Hazard statements
Causes severe skin burns and eye damage.
Precautionary statements
If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Immediately call a POISON CENTER or doctor/ physician. Specific treatment (see supplemental first aid instructions on this label). IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
1/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
Other hazards
:
None identified
Chemical Name
CAS-No.
Weight percent
Sodium hypochlorite
7681-52-9
5.00 - 10.00
Sodium chloride
7647-14-5
5.00 - 10.00
Sodium hydroxide
1310-73-2
1.00 - 5.00
Eye contact
:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Get medical attention immediately.
Skin contact
:
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or doctor/ physician.
Inhalation
:
No special requirements.
Ingestion
:
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/ container to an approved incineration plant. Wear protective gloves. Do not breathe dust or mist. Wash hands thoroughly after handling.
3. COMPOSITION/INFORMATION ON INGREDIENTS
The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
2/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during firefighting
:
Container may melt and leak in heat of fire.
Special protective equipment for firefighters
:
Wear suitable protective clothing and gloves.
Further information
:
Wear full protective clothing and positive pressure self­contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.
Personal precautions
:
Wear personal protective equipment. Wash thoroughly after handling.
Environmental precautions
:
Outside of normal use, avoid release to the environment.
Methods and materials for containment and cleaning up
:
Dike large spills. Clean residue from spill site.
Precautions for safe handling
:
Avoid contact with skin, eyes and clothing. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Avoid breathing vapours, mist or gas. Wash thoroughly after handling.
Advice on protection against fire and explosion
:
Normal measures for preventive fire protection.
5. FIREFIGHTING MEASURES
6. ACCIDENTAL RELEASE MEASURES
7. HANDLING AND STORAGE
Handling
Storage
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Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
Requirements for storage areas and containers
:
Store locked up.
Components
CAS-No.
mg/m3
ppm
Non-
standard
units
Basis
Sodium hydroxide
1310-73-2
2 mg/m3
-
-
OSHA TWA
Sodium hydroxide
1310-73-2
2 mg/m3
-
- ACGIH
Ceiling
Respiratory protection
:
Substantial amounts of mist/vapors can be controlled with local exhaust ventilation or respiratory protection.
Hand protection
:
Rubber gloves
Eye protection
:
Wear splash-resistant Chemical goggles.
Skin and body protection
:
Protective footwear.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.
Form
:
gel
Color
:
natural colour
Odor
:
Bleach
Odour Threshold
:
No data available
pH
:
11.5 - 13.5
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Personal protective equipment
9. PHYSICAL AND CHEMICAL PROPERTIES
4/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
Melting point/freezing point
:
No data available
Initial boiling point and boiling range
:
212 °F
Flash point
:
does not flash
Evaporation rate
:
No data available
Flammability (solid, gas)
:
No data available
Upper/lower flammability or explosive limits
:
Not applicable
Vapour pressure
:
No data available
Vapour density
:
No data available
Relative density
:
1.11 g/cm3 at 25 °C
Solubility(ies)
:
completely soluble
Partition coefficient: n­octanol/water
:
No data available
Auto-ignition temperature
:
Not applicable
Decomposition temperature
:
No data available
Viscosity, dynamic
:
700 cps at 25 °C Method: ASTM D 2196
5/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
Viscosity, kinematic
:
No data available
Oxidizing properties
:
No data available
Volatile Organic Compounds Total VOC (wt. %)*
:
0.1 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
Other information
:
None identified
:
No data available
Possibility of hazardous reactions
:
If accidental mixing occurs and toxic gas is formed, exit area immediately. Do not return until well ventilated.
Conditions to avoid
:
Direct sources of heat.
Incompatible materials
:
Do not mix with bleach or any other household cleaners. Strong bases
Hazardous decomposition products
:
Thermal decomposition can lead to release of irritating gases and vapours.
Emergency Overview
:
Danger
Acute oral toxicity
:
LD50 estimated > 5,000 mg/kg Causes severe digestive tract burns.
Acute inhalation toxicity
:
No data available
Acute dermal toxicity
:
LD50 estimated
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
6/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
> 2,000 mg/kg
GHS Properties
Classification
Routes of entry
Acute toxicity
No classification proposed
-
Skin corrosion
Category 1B -
Serious eye damage
Category 1 -
Skin sensitisation
No classification proposed
-
Respiratory sensitisation
No classification proposed
-
Germ cell mutagenicity
No classification proposed
-
Carcinogenicity
No classification proposed
-
Reproductive toxicity
No classification proposed
-
Specific target organ toxicity - single exposure
No classification proposed
-
Specific target organ toxicity - repeated exposure
No classification proposed
-
Aspiration hazard
No classification proposed
-
Aggravated Medical Condition
:
Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc. may be more susceptible to irritating effects
Components
End point
Species
Value
Exposure
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested. Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions.
Toxicity to fish
7/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
Sodium hypochlorite
semi­static test LC50
Oncorhynchus mykiss (rainbow trout)
0.03 - <
0.19 mg/l
96 h
NOEC
0.01 - <
0.1 mg/l
28 d
Sodium chloride
flow­through test LC50
Lepomis macrochirus
5,840 mg/l
96 h
NOEC
Pimephales promelas (fathead minnow)
252 mg/l
33 d
Sodium hydroxide
LC50
Fish
35 - 189 mg/l
96 h
Sodium hypochlorite
static test EC50
Daphnia magna (Water flea)
0.033 -
0.044 mg/l
48 h
Sodium chloride
static test EC50
Daphnia magna (Water flea)
340.7 -
469.2 mg/l
48 h
NOEC
Daphnia pulex
314 mg/l
21 d
Sodium hydroxide
EC50
Daphnia magna (Water flea)
40.4 mg/l
48 h
time
Components
End point
Species
Value
Exposure time
Toxicity to aquatic invertebrates
8/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
Sodium hypochlorite
EC50
Skeletonema costatum
0.095 mg/l
72 h
Sodium chloride
IC50
Algae
3,014 mg/l
72 h
Sodium hydroxide
No data available
Component
Biodegradation
Exposure time
Summary
Sodium hypochlorite
No data available
Sodium chloride
No data available
Sodium hydroxide
No data available
Component
Bioconcentration factor (BCF)
Partition Coefficient n­Octanol/water (log)
Sodium hypochlorite
No data available
-3.42
Sodium chloride
1.09 QSAR
0.54
Sodium hydroxide
0.89 estimated
-1.38
Component
End point
Value
Sodium hypochlorite
No data available
Sodium chloride
No data available
Sodium hydroxide
No data available
Component
Results
Sodium hypochlorite
Not fulfilling PBT and vPvB criteria
Sodium chloride
Not fulfilling PBT and vPvB criteria Sodium hydroxide
Not fulfilling PBT and vPvB criteria
Components
End point
Species
Value
Exposure time
Toxicity to aquatic plants
Persistence and degradability
Bioaccumulative potential
Mobility
PBT and vPvB assessment
9/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
Other adverse effects
:
None known.
Consumer may discard empty container in trash, or recycle where facilities exist.
Land transport
Sea transport
Air transport
UN number
1760
1760
1760
UN proper shipping name
UN 1760 Corrosive Liquid, N.O.S. 8, III
UN 1760 Corrosive Liquid, N.O.S. 8, III
UN 1760 Corrosive Liquid, N.O.S. 8, III
Transport hazard class(es)
8 8 8
Packing group
III
III
III
Environmental hazards
-
- -
Special precautions for user
Limited quantities derogation may be applicable to this product, please check transport documents.
Limited quantities derogation may be applicable to this product, please check transport documents.
Limited quantities derogation may be applicable to this product, please check transport documents.
Notification status
:
All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Notification status
:
All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
13. DISPOSAL CONSIDERATIONS
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
15. REGULATORY INFORMATION
10/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
California Prop. 65
:
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Health
3
Flammability
0
Reactivity
0
Health
3
Fire
0
Reactivity
0
Special
-
Prepared by
SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
16. OTHER INFORMATION
HMIS Ratings
NFPA Ratings
This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
11/12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000013008
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