Dorcy 41-1081 User Manual

Material Safety Data Sheet

Material Safety Data Sheet

Client

Add. of Client

Description

Model /Type

Manufacturer
Add. of
Manufacturer

Nominal Voltage 3.7V, 300mAh, 1.1Wh

Date of Receipt

SHENZHEN BAK BATTERY CO., LTD.

BAK INDUSTRIAL ZONE KUICHONG ST, LONGGANG DI STRICT,
SHENZHEN, GUANGDONG, CHINA

Lithium Polymer Battery

423040A

SHENZHEN BAK BATTERY CO., LTD.
BAK INDUSTRIAL ZONE KUICHONG ST, LONGGANG DI STRICT,

SHENZHEN, GUANGDONG, CHINA

2015-03-13

Laboratory

Address

Approved
Signatory

Inspected by Bella.Wang

Censored by Frank. feng

Shenzhen ZRLK Testing Technology Co., Ltd.

3F, HengFengYuan Business Building, QunHui Road, Bao'an District,
ShenZhen, P.R.C (518101)

Williau. liu

Report No.: ZRLK1503130001 Page 1 of 9

Material Safety Data Sheet

Section 1- Chemical Product and Company Identification

1. Chemical Product Identification

Product name: Lithium Polymer Battery

Model: 423040A

2. Company Identification

Manufacturer /Supplier Name: SHENZHEN BAK BATTERY CO., LTD.
Address: BAK INDUSTRIAL ZONE KUICHONG ST, LONGGANG DISTRICT, SHENZHEN,
GUANGDONG, CHINA
Telephone number of the supplier: 0086-0755-27607256
Emergency Telephone No.(24h): 0086-0755-27607256
e-mail address: [e-mail]
This MSDS was prepared by Shenzhen ZRLK Testing Technology Co., Ltd.
Referenced documents: ISO 11014:2009 Safety data sheet for chemical products;

Section 2 – Hazards Identification

Preparation
hazards and
classification

Apperance,
Color, and
Odor
Primary
Route(s) of
Exposure

Potential
Health Effects:

Medical
Conditions
Aggravated by
Exposure

When the battery is In extreme pressure deformation, hig h -t emperature environment,
overload, short-circuit condition, or disassemble the battery, an explosion of fire and
chemical burn hazards may occur.
Solid object with no odor, no color.

These chemicals are contained in a sealed stainless steel enclosure. Risk of exposure
occurs only if the cell is mechanically, thermally or electrically abused to the point of
compromising the enclosure. If this occurs, exposure to the electrolyte solution contained
within can occur by Inhalation, Ingestion, Eye contact and Skin contact
ACUTE (short term): see Section 8 for exposure controls In the event that this battery
has been ruptured, the electrolyte solution contained within the battery would be corrosive
and can cause burns.
Inhalation: A battery volatilizes no gas unless it was damaged. Damaged battery will
volatilize little gas that may stimulate the respiratory tract or cause an anaphylaxis in
serious condition.

Ingestion: Swallowing battery will be Damaged to the respiratory tract and Cause
chemical burns to the stomach; in serious conditions it will cause Permanent damage.
Skin: In normal condition, Contact between the battery and skin will not cause any harms.
Contact with a damaged battery may cause skin allergies or chemical burns.
Eye: in normal condition, Contact between the battery and eyes will not cause any harms.
However, the gas Volatilize from a damaged battery may be harmful to eyes.

CHRONIC (long term): see Section 11 for additional toxicological data
Not applicable

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Material Safety Data Sheet

Reported as
carcinogen

Not applicable

Section 3 – Composition/Information on Ingredients

Lithium Polymer Battery is a mixture.

Hazardous Ingredients
(Chemical Name)

Lithium Cobalt Oxide (CoLiO2) 40.85 12190-79-3
Graphite 19.82 7782-42-5
Rubber, neoprene 1 69028-37-1
Carbon black 1 1333-86-4
Rubber, butadiene styrene 1 61789-96-6
Polypropylene 1.78 9003-07-0
Polyethylene 1.38 9002-88-4

Concentration or concentration
ranges (%)

CAS Number

Phosphate(1-), hexafluoro-,
lithium

Ethylene carbonate 6.41 96-49-1
Diethyl carbonate 4.91 105-58-8
Propylene carbonate 1.53 108-32-7
Nylon-6 1.35 25038-54-4
Copper 9.88 7440-50-8
Aluminum Foils 5.7 7429-90-5
Nickel 2 7440-02-0

Note: CAS number is Chemical Abstract Service Registry Number.
N/A=Not apply.

(*)Main ingredients: Lithium hexafluorophosphate, organic carbonates

1.41 21324-40-3

Section 4 – First-aid Measures

Inhalation

Skin contact

If contents of an opened battery are inhaled, remove source of contamination or move
victim to fresh air. Obtain medical advice.
If skin contact with contents of an open battery occurs, as quickly as possible remove
contaminated clothing, shoes and leather goods. Immediately flush with lukewarm, gently
flowing water for at least 30 minutes. If irritation or pain persists, seek medical attention.

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Material Safety Data Sheet

Completely decontaminate clothing, shoes and leather goods before reuse or discard.

Eye contact

Ingestion

If eye contact with contents of an open battery occurs, immediately flush the contaminated
eye(s) with lukewarm, gently flowing water for at least 30 minutes while holding the
eyelids open. Neutral saline solution may be used as soon as it is available. If necessary,
continue flushing during transport to emergency care facility. Take care not to rinse
contaminated water into the unaffected eye or onto face. Quickly transport victim to an
emergency care facility.
If ingestion of contents of an open batte ry o ccurs, never give anything by mouth if vict i m
is rapidly losing consciousness, or is unconscious or convulsing. Have victim rinse mouth
thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 60 to 240 mL
(2-8 oz.) of water. If vomiting occurs naturally, have victim lean forward to reduce risk of
aspiration. Have victim rinse mouth with water again. Quickly transport victim to an
emergency care facility.

Section 5 – Fire-fighting Measures

Flammable
Properties

Suitable
extinguishing
Media
Unsuitable
extinguishing
Media
Explosion Data

Specific
Hazards arising
from the
chemical
Protective
Equipment and
precautions for
firefighters
NFPA Health: 0 Flammability: 0 Instability: 0

In the event that this battery has been ruptured, the electrolyte solution contain within the
battery would be flammable. Like any sealed container, battery cells may rupture when
exposed to excessive heat; this could result in the release of flammable or corrosive
materials.

Use extinguishing media suitable for the materials that are burning.

Not available

Sensitivity to Mechanical Impact: This may result in rupture in extreme cases Sensitivity
to Static Discharge: Not Applicable

Fires involving Lithium Polymer Battery was controlled with water. When water is used,
however, hydrogen gas may evolve. In a confined space, hydrogen gas can form an
explosive mixture. In this situation, smothering agents are recommended to extinguish the
fire
As for any fire, evacuate the area and fight the fire from a safe distance. Wear a
pressure-demand, self-contained breathing apparatus and full protective gear. Fight fire
from a protected location or a safe distance. Use NIOSH/MSHA approved full-face
self-contained breathing apparatus (SCBA) with full protective gear.

Section 6 – Accidental Release Measures

Personal Precautions, protective equipment, and Restrict access to area until completion of clean-up.

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Material Safety Data Sheet

emergency procedures Do not touch the spilled material. Wear adequate

personal protective equipment as indicated in Section

8.

Environmental Precautions Prevent material from contaminating soil and from

entering sewers or waterways.

Methods and materials for Containment Stop the leak if safe to do so. Contain the spilled

liquid with dry sand or earth. Clean up spills
immediately.

Methods and materials for cleaning up Absorb spilled material with an inert absorbent (dry

sand or earth). Scoop contaminated absorbent into an
acceptable waste container. Collect all contaminated
absorbent and dispose of according to directions in
Section 13. Scrub the area with detergent and water;
collect all contaminated wash water for proper
disposal.

Section 7 – Handling and Storage

Handling Do not dismantle, open or shred secondary Lithium

Polymer Battery;

Don’t handling Polymer Li-ion Batterywith
metalwork. Do not open, dissemble, crush or burn
battery. Ensure good ventilation/ exhaustion at the
workplace.

Prevent formation of dust.
Information about protection against explosions and

fires: Keep ignition sources away- Do not smoke.

Storage If the Lithium Polymer Battery is subject to storage

for such a long term as more than 3 months, it is
recommended to recharge the Lithium Polymer
Battery periodically.

3 months: -10℃~+40℃, 45 to 85%RH
And recommended at -20℃~+25℃ for long period

storage.
The capacity recovery rate in the delivery state

(50% capacity of fully charged) after storage is
assumed to be 80% or more.

The voltage for a long time storage shall be

3.7V~4.0V range.
Do not storage Lithium Polymer Battery

haphazardly in a box or drawer where they may
short-circuit each other or be short-circui t ed by ot her
metal objects.

Keep out of reach of children.
Do not expose Lithium Polymer Battery to heat or

fire. Avoid storage in direct sunlight.

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Material Safety Data Sheet

Do not store together with oxidizing and acidic
materials.

Section 8 – Exposure Controls and Personal Protection

Engineering Controls Use local exhaust ventilation or other engineering

controls to control sources of dust, mist, fumes and
vapor.
Keep away from heat and open flame. Store in a
cool, dry place.

Personal Protective Equipment

Other Protective Equipment Have a safety shower and eye wash fountain readily

Hygiene Measures Do not eat, drink, or smoke in work area. Maintain

Respiratory Protection: Not necessary und er
normal conditions.
Skin and body Protection: Not necessary under
normal conditions, Wear neoprene or nitrile rubber
gloves if handling an open or leaking battery.
Hand protection: Wear neoprene or natural rub ber
material gloves if handling an open or leaking
battery.
Eye Protection: Not necessary under normal
conditions, Wear safety glasses if handling an open
or leaking battery.

available in the immediate work area.

good housekeeping.

Section 9 - Physical and Chemical Properties

Form: Solid

Physical
State

Change in condition:
pH, with indication of the concentration Not applicable
Melting point/freezing point Not available.

Boiling Point, initial boiling point and Boiling
range:

Flash Point Not available.
Upper/lower flammability or explosive limits Not available.

Vapor Pressure:

Report No.: ZRLK1503130001 Page 6 of 9

Color: Silvery white
Odour: Monotony

Not available.

Not applicable

Material Safety Data Sheet

Vapor Density: (Air = 1)

Density/relative density Not available.
Solubility in Water: Insoluble
n-octanol/water partition coefficient Not available.
Auto-ignition temperature
Decomposition temperature Not available.
Odout threshold Not available.

Evaporation rate

Flammability (soil, gas) Not available.
Viscosity Not applicable

Not applicable

130°C

Not available.

Section 10 - Stability and Reactivity

Stability The product is stable under normal conditions.
Conditions to Avoid (e.g. static discharge, shock or

vibration)

Incompatible Materials Not Available

Do not subject Lithium Polymer Battery to
mechanical shock.
Vibration encountered during trans po rt a t i on does not
cause leakage, fire or explosion.
Do not disassemble, crush, short or install with
incorrect polarity. Avoid mechanical or electrical
abuse.

Hazardous Decomposition Products This material may release toxic fumes if burned or

exposed to fire

Possibility of Hazardous Reaction Not Available

Section 11 - Toxicological Information

In normal condition, contact with the battery is non-toxic.

Section 12 - Ecological Information

General note: Water hazard class 1(Self-assessment): slightly

hazardous for water.
Do not allow undiluted product or large quantities of
it to reach ground water, water course or sewage

system.
Anticipated behavior of a chemical product in
environment/possible environmental

Not Available

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Material Safety Data Sheet

impace/ecotoxicity
Mobility in soil Not Available
Persistence and Degradability Not Available
Bioaccumulation potential Not Available
Other Adverse Effects Not Available

Section 13 – Disposal Considerations

Product disposal recommendation: Observe local, state and federal laws and regulations.
Packaging disposal recommendation: Be aware discarded batteries may cause fire, tape the battery terminals
to insulate them. Don’t disassembly the battery. Completely discharge containers (no tear drops, no powder
rest, scraped carefully). Containers may be recycled or re-used. Observe local, state and federal laws and
regulations.
The potential effects on the environment and human health of the substances used in batteries and
accumulators; the desirability of not disposing of waste batteries and accumulators as unsorted municipal
waste and of participating in their separate collection so as to facilitate treatment and recycling;

Section 14 – Transport Information

This report applies to by sea, by air and by land;
The Lithium Polymer Battery according to Section II of PACKING INSTRUCTION 965-967 of the

th

2015 IATA Dangerous Goods re gul at i ons 56
regulations for the safe transport of Lithium Polymer Battery.

Polymer Li-ion Battery was protected so as to prevent short circuits. This includes protection against

contact with conductive materials within the same packaging that could lead to short circuit;

Cell and batteries offered for transport must be packed in inner packaging’s that completely enclose the cell
or battery; to provide protection from damage or compression to the batteries, the inner packaging’s must be
placed in a strong rigid outer packaging;
The packaging shall be adequate to avoid mechanical damage during transport, handling and stacking. The
materials and pack design shall be chosen so as to prevent the development of unintentional electrical
conduction, corrosion of the terminals and ingress of moisture.
The package must be handled with care and that a flammability hazard exists if the package is damaged;
With regard to transport, the following regulations are cited and considered:

- The International Civil Aviation Organization (ICAO) Technical Instructions.

- The International Air transport Association (IATA) Dangerous Goods Regulations.
UN number of lithium battery: UN3480;
UN Proper shipping name/Description (technical name): Lithium ion batteries;
Marine pollutant(Y/N): N;

- The International Maritime Dangerous Goods (IMDG) Code (2012 Edition).
For lithium-ion batteries by sea, provided that packaging is strong and prevent the products from short-circuit.

Edition may be transported. and applicable U.S. DOT

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Material Safety Data Sheet

UN number of lithium battery: UN3481;
UN Proper shipping name/Description (technical name): Lithium ion batteries
Marine pollutant(Y/N): Y;
Special Provision: International maritime dangerous goods code (IMDG) 188, 230, 310, 348, 957;

- The US Hazardous Materials Regulation (HMR) pursuant to a final rule issued by RSPA

- The Office of Hazardous Materials Safety within the US Department of Transport at i o n s’ (D OT) Research
and Special Programs Administration (RSPA)

Section 15 - Regulatory Information

OSHA hazard communication standard (29 CFR 1910.1200)

Hazardous ∨ Non-hazardous

Section 16 - Other Information

The information above is believed to be accurate and represents the best information currently available to
us. However, concorde makes no warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use. users should make their own
investigations to determine the suitability of the information for their particular purposes. although reasonab le
precautions have been taken in the preparation of the data contained herein, it is offered solely for your
information, consideration and investigation. This material safety data sheet provides guidelines for the safe
handling and use of this product; it does not and cannot advise on all possible situations, therefore, your
specific use of this product should be evaluated to determine if additional precautions are required.

The data/information contained herein has been reviewed and approved for general release on the basis that
this document contains no export controlled information.

******************The End****** ************

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