Propylene glycol 57-55-6 200-338-0 70-80 Not classied
SECTION 4. FIRST AID MEASURES
4.1. Description of rst aid measures
Ingestion: Immediately drink 3 or 4 glasses of water. Get medical attention if you feel unwell.
Skin Contact: Wash with soap and water.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation occurs:
Get medical advice.
4.2. Signs and Symptoms of Exposure:
Inhalation: No signicant adverse effects are expected under anticipated conditions of normal use. If effects do occur, refer to FIRST AID section.
Ingestion: No signicant adverse effects are expected under anticipated conditions of normal use. Excessive ingestion may cause central nervous
system effects.
Skin Contact: No signicant adverse effects are expected under anticipated conditions of normal use. Repeated, prolonged exposure may cause slight
aking, tenderness, and softening of skin.
Eye Contact: May cause minor eye irritation.
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SECTION 5. FIREFIGHTING MEASURES
Suitable and Unsuitable Extinguishing Media:
Carbon dioxide, dry chemical, alcohol type foam, water spray, water fog.
Special Equipment and Precautions for Fire-Fighters:
In the event of a re, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face-piece operated in the pressure
demand or other positive pressure mode. Cool re-exposed containers with a water spray. Heat may build up pressure and rupture closed containers.
Liquid may form slippy lm. Use water spray or fog for cooling, solid stream may spread re as burning liquid will oat on water. Avoid frothing/steam
explosion.
Unusual Fire And Explosion Hazards:
Heat from re can generate ammable vapor. When mixed with air and exposed to ignition source, vapors can burn in open or explode if conned.
Vapors may be heavier than air and travel long distances along the ground before igniting and ashing back. Fine sprays and mists may be combustible
at temperatures below normal ash point.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures: Dike the spill to prevent the spread of liquid using the materials
described under Cleanup and Disposal of Spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal
protective equipment and clothing during clean-up.
Methods and Material for Containment and Clean-Up: Prevent ow to sewers and public waters as it may contaminate water. Restrict usage
to prevent slip/fall hazard. Soak up small spills inert solids. Dike and recover large land spills. Notify appropriate authorities if product enters any
waterways.
SECTION 7. HANDLING AND STORAGE
Precautions for Safe Handling: Keep in a tightly closed container. Avoid breathing vapors and mists. Avoid direct or prolonged contact with skin and
eyes. Protect from physical damage. Keep this and all chemicals out of the reach of children. Wash thoroughly after handling.
Conditions for Safe Storage, Including any Incompatibilities: Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatible materials. Do not store near food, foodstuffs, drugs or potable water supplies. Observe all warnings and precautions listed for the product.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Airborne Exposure Limits: None
Appropriate Engineering Controls:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is
generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please
refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators: Not required for normal use in accordance with label directions.
Skin Protection: Use rubber, neoprene or nitrile gloves to minimize skin contact.
Eye Protection: Eye and face protection requirements will vary dependent upon work environment conditions and material handling practices.
Appropriate ANSI Z87 approved equipment should be selected for the particular use intended for this material.
Work Hygienic Practices: Use proper industrial hygiene practices to minimize hazardous exposure. Wash hands after handling this material, and
before eating, smoking or using the bathroom.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear, slightly viscous, blue liquid Specic gravity (H2O = 1): 1.066
Odor: Odorless Solubility in water: miscible
Odor Threshold: None Octanol/Water Partition Coefcient: -1.36
pH @ 25°C: 8.5-10.5 Autoignition Temperature: Not available
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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES (cont.)
Melting Point (Pour Point): <0°C (-32°F) Decomposition Temperature: Not available
Boiling Point: 185 °C (365 °F)
Flash Point: 99 °C (211 °F)
Freeze Point: -60°F
Evaporation Rate (Water = 1): >1
Flammable Limits:
LEL: 3.5%
UEL: 17.5%
Vapor pressure (mm Hg): @ 20 °C: <0.1 mm hg
Vapor Density (Air = 1): 2.6
SECTION 10. STABILITY AND REACTIVITY
Chemical Stability: Stable under ordinary conditions of use and storage.
Possibility of Hazardous Reactions: Will not occur.
Hazardous Decomposition Products: Carbon monoxide and other toxic vapors.
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects:
Inhalation: No signicant adverse effects are expected under anticipated conditions of normal use. If effects do occur, refer to FIRST AID section.
Ingestion: No signicant adverse effects are expected under anticipated conditions of normal use. Excessive ingestion may cause central nervous
system effects.
Skin Contact: No signicant adverse effects are expected under anticipated conditions of normal use. Repeated, prolonged exposure may cause slight
aking, tenderness, and softening of skin.
Eye Contact: May cause minor eye irritation.
Carcinogenic effects: Not classied
Teratogenicity/Reproductive toxicity: Not classied
Mutagenic effects: In vitro mutagenicity studies were negative. Animal mutagenicity studies were negative.
Ecotoxicity: Based largely or completely in information for similar material, i.e. propylene glycol. Material is practically non-toxic to aquatic organisms
on an acute basis (LC50 greater than 100 mg/L in most sensitive species.
Acute LC50 for fathead minnow (Pimephales promelas) is 4600-54900 mg/L.
Acute LC50 for guppy (Poecilla reticulata) is greater than 10000 mg/L.
Acute LC50 for water ea Daphine magna is 4850-34400 mg/L.
Acute LC50 for rainbow trout (Oncorhynchus mykiss) is 44mL/L (about 44000 mg/L).
Aquatic: Not available.
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SECTION 12. ECOLOGICAL INFORMATION (cont.)
Persistence and Degradability: Biodegradation under aerobic static laboratory conditions is high (BOD20 or BOD28/ThOD greater than 4 0%).
Biodegradation is expected to be achievable in a secondary wastewater treatment plant.
5-Day biochemical oxygen demand (BOD5) is 1.16 p/p.
20-Day biochemical oxygen demand (BOD20) is 1.45 p/p.
Theoretical oxygen demand (ThOD) is calculated to be 1.68 p/p.
Biodegradation may occur under both aerobic and anaerobic conditions (in either the presence or absence of oxygen).
Inhibitory concentration (IC50) in OECD “Activated Sludge, Respiration Inhibition Test” (Guideline #209) is < 1000 mg/L. Degradation is expected in the
atmospheric environment within days to weeks.
Bioaccumulative Potential: Bioconcentration potential is low (BCF less than 100 or Log Kow less than 3).
Mobility in Soil: No data available
Other Adverse Effects: None
Other: For more information, see “HANDBOOK OF ENVIRONMENTAL FATE AND EXPOSURE DATA.”
SECTION 13. DISPOSAL CONSIDERATIONS
Landll solids at permitted sites using registered transporters. Burn concentrated liquids, avoiding ameouts, and assuring emissions comply with
applicable regulations. Diluted aqueous waste may biodegrade, but avoid overloading plant biomass and assure efuent complies with applicable
regulations.
SECTION 14. TRANSPORTATION INFORMATION
US DOT: None
Proper Shipping Name: Not classied
Hazard Class: none
UN Number: none
UN Proper Shipping Name: noneTransport Hazard Class(s): none
Packing group: none
Environmental Hazards: Not an environmentally Hazardous Substance of a Marine Pollutant ADR/RID Transport Information: Not dangerous for transport under ADR/RID, IMO and IATA/ICAO regulations.
ADR/RID Class: None Allocated
ADR/RID Packing Group: None Allocated IMDG Hazard Class: None Allocated IMDG Packing Group: None Allocated ADNR Class: None Allocated
ADNR Item: None Allocated
IATA Hazard Class: None Allocated
IATA Packing Group: None Allocated
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable
SECTION 15. REGULATORY INFORMATION
Country Inventory
Australia AICS X
Canada DSL X
Canada DSL no data for mixture
China IECS X
European Union EINECS X
European Union ELINCS no data for mixture
European Union NLP no data for mixture
Japan ENCS X
Korea ECL X
Philippines PICCS X
WHIMS classication for product: N/A
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SECTION 15. REGULATORY INFORMATION (cont.)
Regulatory Status
SARA 302/304: Chemicals with provided CAS numbers in this material are not subject to the reporting requirements of CERCLA.
SARA 311/312: Based upon available information, this material is not classied as a health and/or physical hazard according to Section 311 & 312.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the De Minimis reporting levels established
by SARA Title III, Section 313 and 40 CFR 372.
Component Reporting Threshold
State Reporting:
California Proposition 65: This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins under at levels
which would be subject to the proposition.
Massachusetts Substances List (MSL) - Extraordinarily hazardous substances must be identied when present in material at levels greater than the
state specied criterion. The criterion is >= 0.0001%. Hazardous Substances (MSL-HS) on the MSL must be identied when present in materials at
levels greater than the state specied criterion. The criterion is >= 1%. Components with CAS numbers present in this material, at levels specied in
Section 3-composition do not require reporting under the statute.
State of Pennsylvania: Hazardous Substances must be identied when present in materials at levels greater than the state specied criterion. The
criterion is >= 1%. Components with CAS numbers in this material at a level which could require reporting under the statute are: Propylene Glycol/
CAS#57-55-6. Dipotassium Phosphate/ CAS# 7758-11-4. Special Hazardous Substances listed by the state of Pennsylvania must be identied when
present in materials at levels greater than the state specied criterion. The criterion is >=0.01%. Components with CAS numbers present in this material,
at levels specied in Section 3-composition do not require reporting under the statute.
SECTION 16. OTHER INFORMATION:
Revision Summary: All Sections: New GHS Format
SDS DATE REVISED: 10/13/2015
HMIS III
Ratings:
®
HMIS III
Health0
Flamability1
Physical Hazard0
Personal ProtectionB
This information is, to the best of our knowledge and belief, accurate and reliable as of the date completed. However no representation, warranty or
guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the completeness and suitability of
such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information, nor do we
offer any warranty against patent infringement.
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