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SAFETY DATA SHEET
Crew Clinging Toilet Bowl Cleaner
Version Number: 3 Preparation date: 2014-07-24
1. IDENTIFICATION
Product name:
Product Code:
SDS #:
Recommended use:
Uses advised against:
Manufacturer, importer, supplier:
US Headquarters
Diversey, Inc.
P.O. Box 19747
Charlotte, NC 28219-0747
Phone: 1-888-352-2249
SDS Internet Address: www.diversey.com
Emergency telephone number:
Crew Clinging Toilet Bowl Cleaner
04578
MS0800445
• Industrial/Industrial
• Restroom Care
• This product is intended to be used neat.
Uses other than those identified are not recommended
1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)
2. HAZARDS IDENTIFICATION
Classification for the undiluted product
Skin corrosion/irritation Category 1B
Serious eye damage/eye irritation Category 1
Signal Word: Danger.
Precautionary Statements
Causes burns/ serious damage to mouth, throat and stomach. Avoid contact with eyes, skin and clothing. Keep container tightly closed. Wash
affected areas thoroughly after handling. Wear chemical-splash goggles, chemical-resistant gloves and protective footwear. IF SWALLOWED:
Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or water. IF ON SKIN (or hair): Take
off immediately all contaminated clothing. Rinse skin with water for at least 15 minutes. IF INHALED: Remove person to fresh air and keep
comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing for at least 15 minutes. Immediately call a Poison Center (1-800-851-7145) or physician. Wash contaminated clothing before reuse. Dispose
of in accordance with all federal, state and local applicable regulations.
Health hazards not otherwise classified (HHNOC) - Not applicable
Physical hazards not otherwise classified (PHNOC) - Not applicable
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Classification for the diluted product @ RTU
This product is intended to be used neat.
Precautionary Statements
None required.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Classified Ingredients
Ingredient(s) CAS # Weight %
Hydrochloric acid 7647-01-0 5 - 10%
Ethoxylated oleyl amine 13127-82-7 1% - < 3%
Alcohol ethoxylates 68131-39-5 1% - < 3%
n-Alkyl (60% C14, 30% C16, 5% C12, 5% C18)
dimethyl benzyl ammonium chloride
n-Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl
ammonium chloride
68391-01-5 > 0.1% - < 1%
68956-79-6 > 0.1% - < 1%
*Exact percentages are being withheld as trade secret information
4. FIRST AID MEASURES
Undiluted Product:
Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least
15 minutes.
Skin: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water for at least 15 minutes.
Inhalation: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Ingestion: IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or
water.
Notes to physician: Probable mucosal damage may contraindicate the use of gastric lavage.
Most Important Symptoms/Effects: No information available.
Immediate medical attention and special treatment needed Not applicable.
Aggravated Medical Conditions: Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may be
more susceptible to irritating effects.
Diluted Product:
This product is intended to be used neat.
Eyes: See undiluted product information above.
Skin: See undiluted product information above.
Inhalation: See undiluted product information above.
Ingestion: See undiluted product information above.
5. FIRE-FIGHTING MEASURES
Specific methods:
Suitable extinguishing media:
Specific hazards:
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.
Extinguishing media which must not be used for safety reasons: No information available.
No special methods required
The product is not flammable. Extinguish fire using agent suitable for surrounding fire.
Corrosive material (See sections 8 and 10).
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Environmental precautions
and clean-up methods:
Put on appropriate personal protective equipment (see Section 8.).
Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in
a chemical waste container. Use a water rinse for final clean-up.
7. HANDLING AND STORAGE
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Handling: Avoid contact with skin, eyes and clothing. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation.
Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. DO NOT MIX WITH CHLORINE BLEACH,
ACIDS, OR ANY OTHER PRODUCT OR CHEMICAL. Product residue may remain on/in empty containers. All precautions for handling the product
must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage: Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN.
Aerosol Level (if applicable) : Not applicable
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
.
Undiluted Product:
Engineering measures to reduce exposure:
Good general ventilation should be sufficient to control airborne levels Respiratory protection is not required if good ventilation is maintained.
Personal Protective Equipment
Eye protection:
Hand protection:
Skin and body protection:
Respiratory protection:
Hygiene measures:
Chemical-splash goggles.
Chemical-resistant gloves.
Protective footwear. If major exposure is possible, wear suitable protective clothing and footwear.
In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program
that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever
workplace conditions warrant a respirator's use.
Handle in accordance with good industrial hygiene and safety practice.
Diluted Product:
This product is intended to be used neat.
Personal Protective Equipment
Eye protection:
Hand protection:
Skin and body protection:
Respiratory protection:
Hygiene measures:
No personal protective equipment required under normal use conditions.
No personal protective equipment required under normal use conditions.
No personal protective equipment required under normal use conditions.
No personal protective equipment required under normal use conditions.
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Physical State: Liquid Color: Clear, Green
Evaporation Rate: No information available Odor: Floral
Odor threshold: No information available. Boiling point/range: Not determined
Melting point/range: Not determined Decomposition temperature: Not determined
Autoignition temperature: No information available Solubility: Completely Soluble
Solubility in other solvents: No information available Relative Density (relative to water): 1.05
Density: 8.76 lbs/gal 1.05 Kg/L Vapor density: No information available
Bulk density: No information available Vapor pressure: No information available.
Flash point: > 200 °F > 93.3 °C Partition coefficient (n-octanol/water): No information available
Dilution Flash Point: 200 °F 93.3 °C Viscosity: No information available
Elemental Phosphorus: 0.00 % by wt. VOC: 0 % *
pH: 1.0 VOC % by wt. at use dilution 0 % *
Dilution pH: 1.0 @ RTU Flammability (Solid or Gas): Not applicable
Metal Corrosion: Not determined
Explosion limits: - upper: Not determined - lower: Not determined
* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508
10. STABILITY AND REACTIVITY
Reactivity:
Stability:
Hazardous decomposition products:
Materials to avoid:
Conditions to avoid:
Not Applicable
The product is stable
None reasonably foreseeable.
Strong bases. Oxidizing agents.
Do not mix with any other product or chemical.
11. TOXICOLOGICAL INFORMATION
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Information on likely routes of exposure:
Eye contact, Skin contact, Inhalation, Ingestion
Delayed, immediate, or chronic effects and symptoms from short and long-term exposure
Skin contact: Corrosive. Causes severe burns. Symptoms may include burns, blisters, redness and pain (which may be delayed).
Eye contact: Corrosive. Causes serious eye damage. Symptoms may include pain, burning sensation, redness, watering, blurred
vision or loss of vision.
Ingestion: Causes burns/ serious damage to mouth, throat and stomach. Symptoms may include stomach pain and nausea.
Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Symptoms may include coughing and
difficulty breathing.
Sensitization: No known effects.
Target Organs (SE): None known
Target Organs (RE): None known
Ingredient(s) CAS # NTP IARC OSHA
Hydrochloric acid 7647-01-0 1
Numerical measures of toxicity
12. ECOLOGICAL INFORMATION
Ecotoxicity: No information available.
Persistence and Degradability: No information available.
Bioaccumulation: No information available.
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products: This product, as sold, if discarded or disposed, is a hazardous waste according to Federal regulations
(40 CFR 261.4 (b)(4)). Dispose in compliance with all Federal, state, provincial, and local laws and regulations.
Contaminated Packaging: Do not re-use empty containers.
RCRA Hazard Class (undiluted product): D002 Corrosive Waste
14. TRANSPORT INFORMATION
DOT/TDG/IMDG: Proper shipping descriptions can vary by pack size. Please refer to the Diversey HazMat Library, only available through
Internet Explorer, http://naextranet.diversey.com/dot/, for up to date shipping information.
DOT (Ground) Bill of Lading Description:
IMDG (Ocean) Bill of Lading Description:
LTD. QTY.
UN3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., (hydrochloric acid, quaternary
ammonium compounds), 8, II, LTD. QTY.
15. REGULATORY INFORMATION
International Inventories at CAS# Level
All components of this product are listed on the following inventories: U.S.A. (TSCA).
U.S. Regulations
EPA Reg. No. : 70627-5
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data
sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The
pesticide label also includes other important information, including directions for use.
DANGER: CORROSIVE. Causes irreversible eye damage or skin burns. Do not get in eyes, on skin or on clothing. Harmful if swallowed, absorbed
through skin or inhaled. Avoid breathing vapors. Wear chemical splash-proof goggles, protective clothing and chemical resistant gloves. Wash
thoroughly with soap and water after handling.Remove and wash clothing before reuse. CHEMICAL HAZARDS: NEVER USE WITH CHLORINE
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PRODUCTS... these can react to give chlorine gas. If this occurs, flush toilet to remove chemicals and leave area. Do not return for half hour.
Ventilate if possible. Never use or mix with other cleaners or chemicals. Clean up spills right away.
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65.
RIGHT TO KNOW (RTK)
CERCLA/ SARA
Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants
Hydrochloric acid X
SARA 311/312 Hazard Categories
Immediate:
Delayed:
Fire:
Reactivity:
Sudden Release of Pressure:
X
-
-
-
-
Canadian Regulations
WHMIS hazard class: Not for sale in Canada.
Ingredient(s) CAS # NPRI
Hydrochloric acid 7647-01-0 X
NFPA (National Fire Protection Association)
Rating Scale: (Low Hazard) 0 - 4 (Extreme Hazard)
Health 3
Flammability 0
Instability 0
Version Number: 3
Preparation date: 2014-07-24
Reason for revision:
Prepared by:
Additional advice:
Not applicable
NAPRAC
• Contains an added fragrance, see "Odor" heading in section 9 for specific description
16. OTHER INFORMATION
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is
responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and
Local laws and regulations.
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