Chemical Name
CAS#
Weight Percent
Section 1 - Product and Company Identification
Section 2 - Hazards Identification
Section 3 - Composition / Information on Ingredients
Safety Data Sheet Page 1 of 7
Repel Insect Repellent Sportsmen Formula 25% DEET
Product Identifiers:
Product name: Repel Insect Repellent Sportsmen Formula 25% DEET
EPA reg. number: 305-51
Recommended product use: Insect Repellent - Aerosol
Details of the Supplier of the Safety Data Sheet:
Manufacturer/Supplier: Chemsico
Div. of United Industries Corp.
P.O. Box 142642
St. Louis, MO 63114
For product information: 1-800-880-1181
For medical emergencies: 1-800-633-2873
Conforms to Hazard Communication Standard 29 CFR 1910.1200.
GHS Classification of Substance or Mixture:
Physical Hazards GHS Classification Flammable aerosol - Category 2
Gases under pressure – Compressed Gas
Health Hazards GHS Classification Skin Sensitizer – Category 1B
GHS Label Elements:
Hazard pictogram(s):
Revision date: 10/04/2016
Signal word: WARNING
Hazard statements: • Flammable aerosol
• Compressed gas – contents under pressure; may burst if
heated
• Harmful if swallowed
• May cause an allergic skin reaction
Precautionary Statements: • Contents under pressure.
• Do not use or store near heat or open flame.
• Do not puncture or incinerate container.
• Exposure to temperatures above 130°F may cause
bursting.
• Wash hands with soap and water after handling. Do not
eat, drink or smoke when using this product. If swallowed:
Call a poison control center or doctor for treatment advice
if you feel unwell. Rinse mouth.
• If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.
DEET (N,N-Diethyl-m-toluamide)
134-62-3
25.00%
Ethanol
64-17-5
23.00%
Isobutane
75-28-5
8.00%
Section 4 - First Aid Measures
Section 5 - Fire Fighting Measures
Section 6 - Accidental Release Measures
Safety Data Sheet Page 2 of 7
Repel Insect Repellent Sportsmen Formula 25% DEET
Note: Ingredients not identified are proprietary or non-hazardous. Values are not product
specifications.
Eye contact: No special requirements
Skin contact: After returning indoors, wash treated skin with soap and
Inhalation: No special requirements
water. Discontinue use if irritation or rash occurs.
Ingestion: Call a poison control center or doctor immediately for
treatment advice. Have person sip if able to swallow. Do
not induce vomiting unless told to do so by a poison
control center or doctor. Do not give anything by mouth to
Note to Physician: No special requirements
an unconscious person.
General advice: If you feel unwell, seek medical advice (show the label
where possible). Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect
themselves. Keep out of reach of children.
Revision date: 10/04/2016
Flammable properties: Pressurized aerosol container
NFPA classification: NFPA level 1 aerosol
Suitable extinguishing media: Water fog, foam, CO2, dry chemical
Unsuitable extinguishing media: Not available
Specific hazards arising from the
chemical: Contents under pressure – container may burst in heat of
fire.
Protective equipment for firefighters: Firefighters should wear full protective clothing including
self-contained breathing apparatus.
Hazardous combustion products: None known
Explosion data: Not available
Sensitivity to static discharge: Not available
Personal precautions: Keep unnecessary personnel away. Do not touch or walk
through spilled material.
Personnel precautions: Remove all sources of ignition. Wear personnel protective
equipment as recommended in Section 8. Wash
thoroughly after handling.
For emergency responders: If specialized clothing is required to deal with the spillage,
take note of any information in Section 8 on suitable and
unsuitable materials.
Components with Occupational Exposure Limits
Exposure Limits
OSHA PEL
ACGIH TLV
SupplierOEL
Chemical name
ppm
mg/m
3
ppm
mg/m3
ppm
mg/m3
DEET
TWA
None
None
None
Ethanol
TWA
1000
1900
1000
------
1000
1900
Isobutane
TWA
Not established
1000
------
Not established
Section 7 - Handling and Storage
Section 8 - Exposure Controls / Personal Protection
Safety Data Sheet Page 3 of 7
Repel Insect Repellent Sportsmen Formula 25% DEET
Environmental precautions: Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Methods for containment and
cleaning up: Stop leak if without risk. Move containers from spill area.
Before attempting clean up, refer to hazard data given
above. Small spills may be absorbed with earth, sand or
absorbent material swept up and placed in suitable,
covered, and labeled containers. Prevent large spills from
entering sewers or waterways. Contact emergency
services and supplier for advice. Never return spills in
original containers for re-use.
Precautions for safe handling: Put on appropriate personal protective equipment as
recommended in Section 8. Pressurized container: protect
from sunlight and do not expose to temperatures
exceeding 50°C (122°F). Do not pierce or burn, even after
use. Do not ingest. Avoid contact with skin, eyes and
clothing. Avoid breathing vapor or mist. Use only with
adequate ventilation. Store and use away from heat,
sparks, open flame or any other ignition source. Use
explosion-proof electrical equipment. Use only nonsparking tools. Empty containers retain product residue
and can be hazardous.
Storage: Store in a cool, dry area away from open flame. Do not
store above 50°C (122°F).
Revision date: 10/04/2016
Exposure guidelines:
Engineering controls: General ventilation normally adequate.
Personal protective equipment:
Eye/Face protection: During application, prevent entry into eyes. Wear safety
glasses with side shields if using in large applications.
Skin and body protection: None required
Respiratory protection: None required
General hygiene considerations: Handle in accordance with good industrial hygiene and
safety practices. When using, do not eat or drink. Wash
hands before breaks and immediately after handling the
product.
Section 9 - Physical & Chemical Properties
Section 10 - Chemical Stability & Reactivity Information
Section 11 - Toxicological Information
Safety Data Sheet Page 4 of 7
Repel Insect Repellent Sportsmen Formula 25% DEET
Appearance: Clear
Color: Light yellow
Physical state: Pressurized liquid
Odor: Ethanol and DEET
Odor threshold: No data available
pH: 8.8 (liquid portion)
Melting point: No data available
Freezing point: No data available
Boiling point: No data available
Flash point: 85°F (liquid portion)
Flame Extension 6-12”
Flammability limits in air,
lower, % by volume: No data available
Flammability limits in air,
upper, % by volume: No data available
Vapor pressure: No data available
Vapor density: No data available
Relative density @ 20°C: 0.955 (liquid portion)
Octanol/water coefficient: No data available
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Solubility: Miscible in water
Evaporation rate: No data available
% Volatile organic compounds: 31.2
Revision date: 10/04/2016
Reactivity
Conditions to avoid: Do not mix with other chemicals.
Incompatible materials: Avoid strong oxidizers.
Chemical stability
Product stability: Stable under recommended storage conditions.
Other
Hazardous decomposition products: None known
Possibility of hazardous reactions: Hazardous polymerization does not occur.
Primary eye irritation: Non-irritating (EPA tox. category IV)
Primary skin irritation: Non-irritating (EPA tox. category IV)
Section 12 - Ecological Information
Section 13 - Disposal Considerations
Section 14 - Transportation Information
Section 15 - Regulatory Information
Safety Data Sheet Page 5 of 7
Repel Insect Repellent Sportsmen Formula 25% DEET
Acute dermal: LD50 > 5000 mg/kg (EPA tox. category IV)
Acute inhalation: LC50 > 2 mg/L (EPA tox. category IV)
Acute oral: LD50 > 2000 mg/kg (EPA tox. category III)
Sensitization: May cause an allergic reaction after repeated contact.
Chronic effects/ Carcinogenicity: No data available
Mutagenicity: No data available
Reproductive effects: No data available
Teratogenicity: No data available
Ecotoxicity: No data available
Environmental effects: No data available
Aquatic toxicity: None
Persistence / degradability: No data available
Bioaccumulation / accumulation: No data available
Partition coefficient: No data available
Mobility in environmental media: No data available
Chemical fate information: No data available
Revision date: 10/04/2016
Waste codes: Not available
Disposal instructions: Dispose in accordance with all applicable regulations.
Waste from residues / unused
products: Not available
Contaminated packaging: Not available
U.S. Department of Transportation
(DOT): UN-1950, Aerosols, Flammable, 2.1, Limited Quantity
IATA: UN-1950, Aerosols, 2.1
IMDG: UN-1950, Aerosols, Flammable, 2, Limited Quantity
29 CFR 1910.1200 hazardous chemical
Occupational Safety and Health
Administration (OSHA): No
CERCLA (Superfund) reportable
quantity: Not available
Hazard categories
Superfund Amendments and Reauthorization Act of 1986 (SARA):
Section 16 - Other Information
Safety Data Sheet Page 6 of 7
Repel Insect Repellent Sportsmen Formula 25% DEET
Immediate Hazard No
Delayed Hazard No
Fire Hazard No
Pressure Hazard No
Reactivity Hazard No
Section 302 extremely hazardous
Substance: No
Section 311 hazardous chemical: No
Clean Air Act (CAA): Not available
Clean Water Act (CWA): Not available
State regulations:
FIFRA labeling: This chemical is a pesticide product registered by the Environmental Protection
Agency and is subject to certain labeling requirements under federal pesticide law.
These requirements differ from the classification criteria and hazard information
required for safety data sheets, and for workplace non-pesticide chemicals.
Following is the hazard information as required on the pesticide label:
Signal word: CAUTION
Precautionary
statements: Harmful if swallowed. Use of this product may cause skin reactions in rare cases.
Wash treated clothing before wearing it again. Wash hands before eating, drinking,
chewing gum, using tobacco or using the toilet.
FLAMMABLE. Contents under pressure. Do not use or store near heat or open
flame. Do not puncture or incinerate container. Exposure to temperatures above
130°F may cause bursting.
Notification status: All ingredients of this product are listed or are excluded from listing on the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
California Prop. 65: This product does not contain any chemicals known to the state of California to
cause cancer, birth defects or any other reproductive harm.
Disclaimer: Information contained herein was obtained from sources considered technically
accurate and reliable. While every effort has been made to ensure full disclosure of
product hazards, in some cases data is not available and is so stated. Since
conditions of actual product use are beyond control of the supplier, it is assumed
that users of this material have been fully trained according to the requirements of
all applicable legislation and regulatory instruments. No warranty, expressed or
implied, is made and supplier will not be liable for any losses, injuries or
consequential damages which may result from the use of or reliance on any
information contained in this document.
Revision date: 10/04/2016
Item number(s): HG-84137; HG-94137
Formula number(s): 21-1323
HMIS ratings: Health Hazard 1 Flammability 2 Physical Hazard 1
Issue date: 2/22/2016
Prepared by: WPC Brands, Inc.
P.O. Box 4406
Bridgeton, MO 63044-0406
(800) 242-1166
Safety Data Sheet Page 7 of 7
Repel Insect Repellent Sportsmen Formula 25% DEET
Revision date: 10/04/2016
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