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Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula Spray Pump 40% DEET
Section 1 - Product and Company Identification
Product Identifiers:
Product Name: Repel Insect Repellent Sportsmen Max Formula Pump
Spray 40% DEET
EPA Registration Number: 121-88-305
Product Use: Insect Repellent Pump Spray
Details of the Supplier of the Safety Data Sheet:
Manufacturer/Supplier: Chemsico
Division of United Industries Corp.
P.O. Box 142642
St. Louis, MO 63114-0642
For product information: 1-800-880-1181
For medical emergencies: 1-800-880-1181
Section 2 - Hazards Identification
Conforms to Hazard Communication Standard 29 CFR 1910.1200.
GHS Classification of Substance or Mixture:
Flammable liquid – category 3
GHS Label Elements:
Ethanol solution
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Revision date: 6/22/2016
Signal word: WARNING
Hazard pictogram(s):
Hazard statements: • Flammable liquid – Do not use or store near heat or open
flame
• Causes serious eye irritation
• Harmful if swallowed
• May cause an allergic skin reaction
Precautionary Statements:
• Keep away from sparks and open flames. No smoking.
Keep container tightly closed. Use explosion-proof
equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Wear
eye protection/face protection.
• Wash hands thoroughly with soap and water after
handling. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/attention.
• Do not eat, drink or smoke when using this product. If
swallowed: Call a poison control center or doctor for
treatment advice if you feel unwell. Rinse mouth.
• If skin irritation occurs: Get medical attention/advice.
Take off contaminated clothing and wash before reuse.
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Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula Spray Pump 40% DEET
Section 3 - Composition / Information on Ingredients
Chemical Name CAS# Weight Percent
DEET (N,N-diethyl-m-toluamide) 134-62-3 40.0%
Section 4 - First Aid Measures
Section 5 - Fire Fighting Measures
Ethanol 64-17-5 32.0%
Note: Ingredients not identified are proprietary or non-hazardous. Values are not product
specifications.
Eye contact: Hold eye open and rinse slowly and gently with water for
15-20 minutes. Remove contact lenses, if present, after the
first 5 minutes, then continue rinsing. Call a poison control
center or doctor for treatment advice.
Skin contact: After returning indoors, wash treated skin with soap and
Inhalation: No special requirements
water. Discontinue product use if irritation or rash occurs.
Ingestion: Call a poison control center or doctor immediately for
treatment advice. Have person sip a glass of water if able
to swallow. Do not induce vomiting unless told to do so by
a poison control center or doctor. Do not give anything to
Notes to physician: None
an unconscious person
General advice: If you feel unwell, seek medical advice (show the label
where possible). Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect
themselves. Keep out of reach of children.
Flammable properties: Flammable liquid – category 3. Flashpoint 85 F.
Suitable extinguishing media: Water fog, alcohol resistant foam, CO2, dry chemical
Unsuitable extinguishing media: Not available
Specific hazards arising from the
chemical: Flammable liquid. Vapors are heavier than air and may
travel to a source of ignition and flash back. Liquid run-off
to sewers may create fire/explosion hazard. Container
may melt and leak in heat of fire. Do not allow run-off
from firefighting to enter drains or water courses.
Protective equipment for firefighters: Firefighters should wear full protective clothing including
self-contained breathing apparatus.
Hazardous combustion products: None known
Sensitivity to mechanical impact: None known
Explosion data: Not available
Sensitivity to static discharge: Not available
Personal precautions: Keep unnecessary personnel away. Do not touch or walk
through spilled material. Do not touch damaged containers
or spilled material unless wearing appropriate protective
clothing. Keep people away from and upwind of spill/leak.
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Revision date: 6/22/2016
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Safety Data Sheet
Exposure Limits
Chemical name
Repel Insect Repellent Sportsmen Max Formula Spray Pump 40% DEET
Revision date: 6/22/2016
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Section 6 - Accidental Release Measures
Personal precautions: Remove all sources of ignition. Beware of vapors
accumulating to form explosive concentrations. Vapors
can accumulate in low areas. Wear personal protective
equipment. Wash thoroughly after handling.
For emergency responders: If specialized clothing is required to deal with the spillage,
take note of any information in Section 8 on suitable and
unsuitable materials.
Environmental precautions: Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Methods for containment and
cleaning up: Stop leak if without risk. Move containers from spill area.
Before attempting clean up, refer to hazard data given
above. Small spills may be absorbed with earth, sand or
absorbent material swept up and placed in suitable,
covered, and labeled containers. Prevent large spills from
entering sewers or waterways. Contact emergency
services and supplier for advice. Never return spills in
original containers for re-use.
Section 7 - Handling and Storage
Precautions for safe handling: Put on appropriate personal protective equipment.
Flammable liquid – keep away from sources of ignition.
Take measures to prevent the buildup of electrostatic
charge.
Storage: Store product in a cool, dry place, out of reach of children.
Keep container closed when not in use. Keep away from
food, drink and animal feedingstuffs. Keep tightly closed.
Non-refillable container. Do not reuse or refill this
container. Place in trash or offer for recycling if available.
Section 8 - Exposure Controls / Personal Protection
Exposure guidelines:
Components with Occupational Exposure Limits
OSHA PEL ACGIH TLV SupplierOEL
ppm mg/m
DEET (N,N-diethyl-m-toluamide) TWA None None None
Ethanol TWA 1000 1900 1000 ------ 1000 1900
Engineering controls:
General ventilation normally adequate.
Personal protective equipment:
Eye/Face protection: During application, prevent entry into eyes. Wear safety
glasses with side shields if using in large applications.
Skin and body protection: After returning indoors, wash treated skin with soap and
water.
Respiratory protection: Where exposure guideline levels may be exceeded, use an
approved NIOSH respirator.
3
ppm mg/m3 ppm mg/m3
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Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula Spray Pump 40% DEET
General hygiene considerations: Handle in accordance with good industrial hygiene and
safety practice. When using, do not eat or drink. Wash
hands before breaks and immediately after handling the
product.
Section 9 - Physical & Chemical Properties
Appearance: Clear
Color: Light yellow to water-white
Physical state: Liquid
Odor: Alcohol
Odor threshold: No data available
pH: 7.5
Melting point: No data available
Freezing point: No data available
Boiling point: No data available
Flash point: 85°F
Evaporation rate: No data available
Flammability limits in air,
lower, % by volume: No data available
Flammability limits in air,
upper, % by volume: No data available
Vapor pressure: No data available
Vapor density: No data available
Relative density @ 20°C: 0.940
Octanol/water coefficient: No data available
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Section 10 - Chemical Stability & Reactivity Information
Reactivity
Chemical stability
Other
Solubility: Miscible in water
% Volatile organic compounds: 32
Conditions to avoid: Do not mix with other chemicals.
Incompatible materials: Oxidizers
Product stability: Stable under recommended storage conditions.
Hazardous decomposition products: None known
Possibility of hazardous reactions: Hazardous polymerization does not occur.
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Revision date: 6/22/2016
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Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula Spray Pump 40% DEET
Revision date: 6/22/2016
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Section 11 - Toxicological Information
Primary eye irritation: Causes substantial but temporary eye injury (EPA tox.
category II)
Primary skin irritation: Non-irritating (EPA tox. category IV)
Acute dermal: LD50 > 5000 mg/kg (EPA category IV)
Acute inhalation: LC50 > 2 mg/L (EPA tox. category IV)
Acute oral: LD50 > 3000 mg/kg (EPA tox. category III)
Sensitization: May cause allergic reaction after repeated contact.
Chronic effects: No data available
Carcinogenicity: No data available
Mutagenicity: No data available
Reproductive effects: No data available
Teratogenicity: No data available
Ecotoxicity: No data available
Section 12 - Ecological Information
Environmental effects: No data available
Aquatic toxicity: None
Persistence / degradability: No data available
Bioaccumulation / accumulation: No data available
Partition coefficient: No data available
Mobility in environmental media: No data available
Chemical fate information: No data available
Section 13 - Disposal Considerations
Waste codes: Not available
Disposal instructions: Dispose in accordance with all applicable regulations.
Waste from residues/unused
products: Not available
Contaminated packaging: Not available
Section 14 - Transportation Information
U.S. Department of Transportation
(DOT): Ethanol Solution, 3, UN-1170, PG-III
IATA: Ethanol Solution, 3, UN-1170, PG-III
IMDG: Ethanol Solution, 3, UN-1170, PG-III
Section 15 - Regulatory Information
29 CFR 1910.1200 hazardous chemical
Occupational Safety and Health
Administration (OSHA) : No
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Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula Spray Pump 40% DEET
CERCLA (Superfund) reportable
quantity: Not available
Hazard categories
Superfund Amendments and Reauthorization Act of 1986 (SARA):
Immediate Hazard No
Delayed Hazard No
Fire Hazard No
Pressure Hazard No
Reactivity Hazard No
Section 302 extremely hazardous
Substance: No
Section 311 hazardous chemical: No
Clean Air Act (CAA): Not Available
Clean Water Act (CWA): Not Available
State regulations: None
FIFRA labeling:
This chemical is a pesticide product registered by the Environmental Protection
Agency and is subject to certain labeling requirements under federal pesticide law.
These requirements differ from the classification criteria and hazard information
required for safety data sheets, and for workplace non-pesticide chemicals.
Following is the hazard information as required on the pesticide label:
Signal word: WARNING
Precautionary
statements: Causes substantial but temporary eye injury. Harmful if swallowed. Do not get in
eyes. Use of this product may cause skin reactions in rare cases. Wash treated
clothing before wearing it again. Wash hands before eating, drinking, chewing gum,
using tobacco or using the toilet. Wash hands thoroughly with soap and water after
handling and before eating, drinking, chewing gum or using tobacco.
COMBUSTIBLE. Do not use or store near heat or open flame.
Notification status:
California Prop. 65:
Disclaimer:
Information contained herein was obtained from sources considered technically
All ingredients of this product are listed or are excluded from listing on the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
This product does not contain any chemicals known to the state of California to
cause cancer, birth defects or any other reproductive harm.
accurate and reliable. While every effort has been made to ensure full disclosure of
product hazards, in some cases data is not available and is so stated. Since
conditions of actual product use are beyond control of the supplier, it is assumed
that users of this material have been fully trained according to the requirements of
all applicable legislation and regulatory instruments. No warranty, expressed or
implied, is made and supplier will not be liable for any losses, injuries or
consequential damages which may result from the use of or reliance on any
information contained in this document.
SECTION 16 - OTHER INFORMATION
HMIS ratings: Health Hazard 2 Fire Hazard 3 Reactivity 0
Item number(s): HG-34101; HG-94101; HG-84101; HG-94095;
Formula number(s): 21-0811
Revision date: 6/22/2016
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Safety Data Sheet
Repel Insect Repellent Sportsmen Max Formula Spray Pump 40% DEET
Issue date: 6/22/2016
Prepared by: WPC Brands, Inc.
P.O. Box 4406
Bridgeton, MO 63044-0406
(800) 242-1166
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Revision date: 6/22/2016
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