Diversey CB123410 User Manual

SAFETY DATA SHEET
Dove Body Wash – All Variants
Rejuvenate, Sweet Cream + Peony,
Pomegrante & Lemon Verbena Scent
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Dry Oil Moisture, Micellar Water,
Section 1. Identification
Product name :
Product type : UPC Code :
Internal product code :
Relevant identified uses of the substance or mixture and uses advised against
Industrial uses Consumer uses Professional uses
Supplier's details :
Emergency telephone number (with hours of operation)
Consumer Information:
Dove Body Wash – All Variants Rejuvenate, Sweet Cream + Peony, Dry Oil Moisture, Micellar Water, Pomegrante & Lemon Verbena Scent Body Cleansing Product 011111631540, 011111527201, 011111552722, 011111005617, 011111611044 M_83329177, M_83296240, M_83302939, M_67286932, M_ 83275934
Identified uses
UNILEVER 700 Sylvan Avenue Englewood Cliffs NJ 07632 USA
Phone #: 800-761-3683 Monday thru Friday
:
Emergency #: 800-745-9269 (24 hours) Poison Control #: 800-949-7866 (24 hours) CHEMTREC #: 800-424-9300(24 hours, Transportation Emergencies)
(8:30 AM – 5:00 PM EST)
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Date of previous issue:
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For information regarding the use of this product by a consumer, please refer directly to the product label. This industrial MSDS is provided for workplace employees, per US OSHA regulations. It contains recommendations for handling of this product in an occupa tional, or workplace, setting.
Any first aid or warnings that are applicable to consumer use are stated directly on the product label, in accordance with all applicable government regulations.
Section 2. Hazards identification
OSHA/HCS status :
Classification of the substance or mixture
GHS label elements
Hazard pictograms :
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
:
Signal word : Hazard statements :
Warning Causes serious eye irritation.
Precautionary statements
General : Prevention : Response :
Keep out of reach of children. Not applicable. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Storage : Disposal :
Supplemental label elements : Hazards not otherwise classified :
Not applicable. Not applicable. None known. None known.
Section 3. Composition/information on ingredients
Substance/mixture :
CAS number/other identifiers
Ingredient name % CAS number
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Mixture
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Cocamidopropyl Betaine 1 - 10 61789-40-0
Sodium Lauroyl Isethionate 1- 5 7381-01-3
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Sodium Lauroyl Glycinate 0 - 5
18777-32-7
Lauric Acid 0 - 3 143-07-7
Glycerin 0 - 5
56-81-5
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.
Section 4. First-aid measures
Description of necessary first aid measures
Eye contact :
Inhalation :
Skin contact :
Ingestion :
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self­contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Call a poison center or physician. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removi ng it, or wea r gl o ves. Cont i n ue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If
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vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unc onscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact : Inhalation : Skin contact : Ingestion :
Causes serious eye irritation. No known significant effects or critical hazards. May cause skin irritation. No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact :
Adverse symptoms may include the following: redness irritation
Inhalation : Skin contact : Ingestion :
No specific data. No specific data. No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician :
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments :
No specific treatment.
Protection of first-aiders :
No action shall be taken involving any personal risk or withou t suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscita t i on. Was h co nt aminated clothing thoroughly with water before removi ng it, or wea r gl o ves.
See toxicological information (Section 11)
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Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media : Unsuitable extinguishing media :
NFPA 30B Classification :
Specific hazards arising from the chemical
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Use an extinguishing agent suitable for the surrounding fire. None known. Not available.
In a fire or if heated, a pressure increase will occur and the container
:
may burst.
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Hazardous thermal decomposition products
Decomposition products may include the following materials:
:
carbon dioxide carbon monoxide
Special protective actions for fire­fighters
Promptly isolate the scene by removing all persons from the vicinity
:
of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Special protective equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-
:
contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency proce dures
For non-emergency personnel :
For emergency responders :
Environmental precautions :
Methods and materials for containment and cleaning up
Small spill :
Large spill :
No action shall be taken involving any personal risk or withou t suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water­insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
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Section 7. Handling and storage
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Precautions for safe handling
Protective measures :
Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product resi d ue an d ca n be hazardous. Do not reuse container.
Advice on general occupational hygiene
Eating, drinking and smoking should be proh i bi te d in areas where
:
this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in original
:
container protected from direct sunlight in a dry, cool and well­ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate c ontai n ment to avoid environmental contamination.
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Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Glycerin
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OSHA PEL 1989 1989-03-01 TWA
10 mg/m3 Form:Total dust
TWA
5 mg/m3 Form:Respirable fraction
OSHA PEL 1993-06-30 TWA
15 mg/m3 Form:Total dust
TWA
5 mg/m3 Form:Respirable fraction
NIOSH REL 1994-06-01
Form:Mist
ACGIH TLV 1994-09-01 TWA
10 mg/m3
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Form:Mist
ACGIH TLV 2013-06-14
Form:Mist
Appropriate engineering controls :
If user operations generate dust, fume s, gas, vapo ur or m i st , use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Environmental exposure controls :
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures :
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techni q ues sh ould be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face protection :
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be wo rn , unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Skin protection
Hand protection :
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Body protection :
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and sh ould be approved by a specialist before handling this product.
Other skin protection :
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Respiratory protection :
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or
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anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9. Physical and chemical properties
Appearance
Physical state : Colour :
Odour : Odour threshold : pH :
Melting point :
Boiling point : Flash point : Evaporation rate : Flammability (solid, gas) : Lower and upper explosive (flammable) limits Vapour density : Relative density : Solubility : Solubility in water : Partition coefficient: n­octanol/water Auto-ignition temperature : Decomposition temperature : Viscosity :
liquid Various tinted colors
perfumed Not available. 7 [Conc. (% w/w): 1,000 g/l ]
Not applicable
Not available. Not available. Not available. Not available.
Lower: Not available.
:
Upper: Not available.
Not available. Not available. Not available. Not available. Not available.
:
Not available. Not available. Not available. Not available.
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Section 10. Stability and reactivity
Reactivity :
Chemical stability : Possibility of hazardous reactions :
Conditions to avoid : Incompatible materials : Hazardous decomposition products
No specific test data related to reactivity available for this product or its ingredients. The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. No specific data. No specific data. Under normal conditions of storage and use, hazardous
:
decomposition products should not be produced. Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Section 11. Toxicological information
Information on toxicological effects
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Acute toxicity
Conclusion/Summary :
Very low toxicity to humans or animals.
Irritation/Corrosion
Conclusion/Summary Skin :
The mixture is not an irritant for the skin. Under the application of the Global Harmonised System (GHS) available data have been used to assess the hazardous properties of this mixture.
Eyes :
Causes serious eye irritation. Under the application of the Global Harmonised System (GHS) available data have been used to assess the hazardous properties of this mixture.
Respiratory :
Based on available data, the classification criteria are not met.
Sensitisation
Conclusion/Summary
Skin : Respiratory :
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met.
Mutagenicity
Conclusion/Summary :
Not applicable.
Carcinogenicity
Conclusion/Summary :
Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
Reproductive toxicity
Conclusion/Summary :
Not applicable.
Teratogenicity
Conclusion/Summary :
Not applicable.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
Information on the likely routes
Not available.
:
of exposure
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Potential acute health effects
Eye contact : Inhalation : Skin contact : Ingestion :
Causes serious eye irritation. No known significant effects or critical hazards. May cause skin irritation. No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact :
Adverse symptoms may include the following: redness irritation
Inhalation : Skin contact : Ingestion :
No specific data. No specific data. No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : Potential delayed effects :
Not available. Not available.
Long term exposure
Potential immediate effects : Potential delayed effects :
Not available. Not available.
Potential chronic health effects
Conclusion/Summary :
Very low toxicity to humans or animals.
General : Carcinogenicity : Mutagenicity : Teratogenicity : Developmental effects : Fertility effects :
No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route ATE value
Oral >5,000 mg/kg
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Section 12. Ecological information
Toxicity
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Conclusion/Summary :
No known significant effects or critical hazards.
Persistence and degradability
Conclusion/Summary :
No known significant effects or critical hazards.
Conclusion/Summary :
No known significant effects or critical hazards.
Mobility in soil
Soil/water partition coefficient
Not available.
:
(KOC)
Other adverse effects :
No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods :
RCRA classification :
United States - RCRA Acute hazardous waste "P" List: Not listed
United States - RCRA Toxic hazardous waste "U" List: Not listed
The generation of waste should be avoided or minimised wherever possible. Disposal of this product, s olut i o ns and any by - pr o duct s should at all times comply with the requirements of environmental protection and waste disposal legislation and any regio nal local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
No known significant effects or critical hazards.
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Section 14. Transport information
FOR SHIPMENT IN
CONSUMER
GROUND
PACKAGING
PROPER SHIPPING NAME:
HAZARD CLASS: UN/ID #:
Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated
None None None
PACKING GROUP: None None None
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WATER AIR
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REQUIRED LABELING: None None None
LABEL TYPE: None None None
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ADDITIONAL INFORMATION:
Not regulated Not regulated Not regulated
Special precautions for user :
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product have been trained in the event of an accident or spillage.’
Transport in bulk according to Annex II of MARPOL 73/ 78 and the IBC Code
Not available.
Section 15. Regulatory information
U.S. Federal regulations :
United States - TSCA 8(d) - Health a nd safety studies: Not listed United States - TSCA 8(c) - Significant adverse reaction (SAR):
Not listed
United States - TSCA 8(a) - Preliminary assessment report (PAIR): Not listed United States - TSCA 8(a) - Chemical Data Reporting (CDR):
Not determined
United States - TSCA 8(a) - Dioxin/Furan precursor: Not listed United States - TSCA 6 - Proposed risk management: Not listed United States - TSCA 6 - Final risk management: Not listed United States - TSCA 5(e) - Substances consent order: Not listed United States - TSCA 5(a)2 - Proposed significant new use rules:
Not listed
United States - TSCA 5(a)2 - Final significant new use rules:
Not listed
United States - TSCA 4(f) - Priority risk review: Not listed United States - TSCA 4(a) - Proposed test rules: Not listed United States - TSCA 4(a) - ITC Priority list: Not listed United States - TSCA 4(a) - Final Test Rules: Not listed United States - TSCA 12(b) - Chemical export notification: The following components are listed: Lauric Acid United States - TSCA 8(a) - Chemical risk rules: Not listed United States - EPA Clean water act (CWA) section 307 ­Priority pollutants: Not listed United States - EPA Clean water act (CWA) section 311 ­Hazardous substances: Not listed United States - EPA Clean air act (CAA) section 112 ­Accidental release prevention - Flammable substances: Not
listed
United States - EPA Clean air act (CAA) section 112 ­Accidental release prevention - Toxic substances: Not listed United States - Department of commerce - Precursor chemical:
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Not listed
Clean Air Act Section 112(b)
:
Not listed Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I
:
Not listed Substances Clean Air Act Section 602 Class
:
Not listed II Substances DEA List I Chemicals (Precursor
:
Not listed Chemicals) DEA List II Chemicals (Essential
:
Not listed Chemicals)
SARA 302/304
Not applicable.
:
SARA 304 RQ :
Not applicable.
SARA 311/312
Classification :
Immediate (acute) health hazard
SARA 313
None of the components are listed.
State regulations Massachusetts :
The following components are listed:
Glycerin
New York : New Jersey :
None of the components are listed.
The following components are listed:
Glycerin
Pennsylvania :
The following components are listed:
Glycerin
US California 22CCR Appendix X Substances
Not listed
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California Prop. 65 :
Not available.
United States inventory (TSCA
:
Exempted
8b)
Canada inventory :
Not determined.
International regulations
International lists :
Philippines inventory (PICCS): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
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Korea inventory: Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
Taiwan inventory (CSNN): Not determined.
Australia inventory (AICS): Not determined.
Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule III Chemicals
:
:
:
Not listed
Not listed
Not listed
Section 16. Other information
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
History
Date of printing : Date of issue/Date of revision : Date of previous issue : Version : Prepared by :
Key to abbreviations :
Version:
1.1
Date of issue/Date of revision:
06.26.2017
06.26.2017
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1.0
Global Product Compliance
Unilever Regulatory Affairs
40 Merritt Blvd
Trumbull, CT 06611
USA
ATE = Acute Toxicity Estimate
ACGIH = American Conference of Governmental & Industrial Hygienists
AH = Acute Hazard
BCF = Bioconcentration Factor
CAA = Clean Air Act
CARB = California Air Resources Board
CCR = California Code of Regulations
CERCLA = Comprehensive Environmental Response, Compensation &
Liability Act
CFR = Code of Federal Regulations
CH = Chronic Hazard
CWA = Clean Water Act
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DEA = Drug Enforcement Administration
DOT = Department of Transportation
EC = European Commission
EPCRA = Emergency Planning and Community Right‑To‑Know Act
EST = Eastern Standard Time
F = Fire
HAPS = Hazardous Air Pollutants
HCS = Hazard Communication Standard
HMIS = Hazardous Materials Information System
HVOC = High Volatile Organic Compound
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals
IARC = International Agency for the Research of Cancer
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
ICAO = International Civil Aviation Organization
IMDG = International Maritime Dangerous Goods
IMO = International Maritime Organization
ITC = Interagency Testing Committee (TSCA)
KOC = Organic Carbon/Water Partition Constant
LogPow = logarithm of the octanol/water partition coefficient
LVOC = Low Volatile Organic Compound
MARPOL 73/78 = International Convention for the Prevention of Pollution
From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine
pollution)
MPPCF = Million Particles Per Cubic Foot
N/A = Not Applicable
NFPA = National Fire Protection Association
NOEC = No Observable Effect Concentration
NTP = National Toxicology Program
OSHA = Occupation Safety & Health Administration
PEL = Permissible Exposure Limit
RCRA = Resource Conservation & Recovery Act
RQ = Reportable Quantity
RTK = Right-To-Know
SARA = Superfund Amendments & Reauthorization Act
STEL = Short-Term Exposure Limit
TBD = To Be Determined
TCC = Tagliabue Closed Cup
TCLP = Toxicity Characteristic Leaching Procedure
TDG = Transport of Dangerous Goods
TLV = Threshold Limit Value
TSCA = Toxic Substances Control Act
TWA = Time Weighted Average
UN = United Nations
References :
Evaluation method used for mixture classification: Calculation
method.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above­named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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