For information regarding the use of this product by a consumer, please refer directly to the product label. This
industrial MSDS is provided for workplace employees, per US OSHA regulations. It contains recommendations
for handling of this product in an occupa tional, or workplace, setting.
Any first aid or warnings that are applicable to consumer use are stated directly on the product label, in
accordance with all applicable government regulations.
Section 2. Hazards identification
OSHA/HCS status :
Classification of the substance or
mixture
GHS label elements
Hazard pictograms :
This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
:
Signal word :
Hazard statements :
Warning
Causes serious eye irritation.
Precautionary statements
General :
Prevention :
Response :
Keep out of reach of children.
Not applicable.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Storage :
Disposal :
Supplemental label elements :
Hazards not otherwise classified :
Not applicable.
Not applicable.
None known.
None known.
Section 3. Composition/information on ingredients
Substance/mixture :
CAS number/other identifiers
Ingredient name % CAS number
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Mixture
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Cocamidopropyl Betaine 1 - 10 61789-40-0
Sodium Lauroyl Isethionate 1- 5 7381-01-3
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Sodium Lauroyl Glycinate 0 - 5
18777-32-7
Lauric Acid 0 - 3 143-07-7
Glycerin 0 - 5
56-81-5
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in
the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First-aid measures
Description of necessary first aid measures
Eye contact :
Inhalation :
Skin contact :
Ingestion :
Get medical attention immediately. Call a poison center or
physician. Immediately flush eyes with plenty of water, occasionally
lifting the upper and lower eyelids. Check for and remove any
contact lenses. Continue to rinse for at least 10 minutes. Chemical
burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or
physician. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If it is suspected that fumes are still
present, the rescuer should wear an appropriate mask or selfcontained breathing apparatus. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration
or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. If unconscious,
place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband.
Get medical attention immediately. Call a poison center or
physician. Flush contaminated skin with plenty of water. Remove
contaminated clothing and shoes. Wash contaminated clothing
thoroughly with water before removi ng it, or wea r gl o ves. Cont i n ue
to rinse for at least 10 minutes. Chemical burns must be treated
promptly by a physician. Wash clothing before reuse. Clean shoes
thoroughly before reuse.
Get medical attention immediately. Call a poison center or
physician. Wash out mouth with water. Remove dentures if any.
Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if
the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If
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vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Chemical burns must be treated promptly by a
physician. Never give anything by mouth to an unc onscious person.
If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Causes serious eye irritation.
No known significant effects or critical hazards.
May cause skin irritation.
No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact :
Adverse symptoms may include the following:
redness
irritation
Inhalation :
Skin contact :
Ingestion :
No specific data.
No specific data.
No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician :
Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
Specific treatments :
No specific treatment.
Protection of first-aiders :
No action shall be taken involving any personal risk or withou t
suitable training. If it is suspected that fumes are still present, the
rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscita t i on. Was h co nt aminated clothing
thoroughly with water before removi ng it, or wea r gl o ves.
See toxicological information (Section 11)
Page:4/16
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media :
Unsuitable extinguishing media :
NFPA 30B Classification :
Specific hazards arising from the
chemical
Version:
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Use an extinguishing agent suitable for the surrounding fire.
None known.
Not available.
In a fire or if heated, a pressure increase will occur and the container
:
may burst.
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Hazardous thermal
decomposition products
Decomposition products may include the following materials:
:
carbon dioxide
carbon monoxide
Special protective actions for firefighters
Promptly isolate the scene by removing all persons from the vicinity
:
of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training.
Special protective equipment for
fire-fighters
Fire-fighters should wear appropriate protective equipment and self-
:
contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency proce dures
For non-emergency personnel :
For emergency responders :
Environmental precautions :
Methods and materials for containment and cleaning up
Small spill :
Large spill :
No action shall be taken involving any personal risk or withou t
suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through
spilt material. Do not breathe vapour or mist. Provide adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
If specialised clothing is required to deal with the spillage, take note
of any information in Section 8 on suitable and unsuitable materials.
See also the information in "For non-emergency personnel".
Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air).
Stop leak if without risk. Move containers from spill area. Dilute
with water and mop up if water-soluble. Alternatively, or if waterinsoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Stop leak if without risk. Move containers from spill area. Approach
the release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilt product. Note: see Section 1
for emergency contact information and Section 13 for waste
disposal.
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Section 7. Handling and storage
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Precautions for safe handling
Protective measures :
Put on appropriate personal protective equipment (see Section 8).
Do not get in eyes or on skin or clothing. Do not breathe vapour or
mist. Do not ingest. If during normal use the material presents a
respiratory hazard, use only with adequate ventilation or wear
appropriate respirator. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed
when not in use. Empty containers retain product resi d ue an d ca n be
hazardous. Do not reuse container.
Advice on general occupational
hygiene
Eating, drinking and smoking should be proh i bi te d in areas where
:
this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering
eating areas. See also Section 8 for additional information on
hygiene measures.
Conditions for safe storage,
including any incompatibilities
Store in accordance with local regulations. Store in original
:
container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10)
and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate c ontai n ment to
avoid environmental contamination.
Page:6/16
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient nameExposure limits
Glycerin
Version:
1.1
Date of issue/Date of revision:
OSHA PEL 1989 1989-03-01 TWA
10 mg/m3
Form:Total dust
TWA
5 mg/m3
Form:Respirable fraction
OSHA PEL 1993-06-30 TWA
15 mg/m3
Form:Total dust
TWA
5 mg/m3
Form:Respirable fraction
NIOSH REL 1994-06-01
Form:Mist
ACGIH TLV 1994-09-01 TWA
10 mg/m3
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Form:Mist
ACGIH TLV 2013-06-14
Form:Mist
Appropriate engineering controls :
If user operations generate dust, fume s, gas, vapo ur or m i st , use
process enclosures, local exhaust ventilation or other engineering
controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits.
Environmental exposure controls :
Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume scrubbers,
filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures :
Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techni q ues sh ould be used to
remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection :
Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be wo rn , unless the
assessment indicates a higher degree of protection: chemical splash
goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
Skin protection
Hand protection :
Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. Considering
the parameters specified by the glove manufacturer, check during
use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material
may be different for different glove manufacturers. In the case of
mixtures, consisting of several substances, the protection time of the
gloves cannot be accurately estimated.
Body protection :
Personal protective equipment for the body should be selected based
on the task being performed and the risks involved and sh ould be
approved by a specialist before handling this product.
Other skin protection :
Appropriate footwear and any additional skin protection measures
should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this
product.
Respiratory protection :
Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or
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anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Section 9. Physical and chemical properties
Appearance
Physical state :
Colour :
Odour :
Odour threshold :
pH :
Melting point :
Boiling point :
Flash point :
Evaporation rate :
Flammability (solid, gas) :
Lower and upper explosive
(flammable) limits
Vapour density :
Relative density :
Solubility :
Solubility in water :
Partition coefficient: noctanol/water
Auto-ignition temperature :
Decomposition temperature :
Viscosity :
liquid
Various tinted colors
perfumed
Not available.
7 [Conc. (% w/w): 1,000 g/l ]
Not applicable
Not available.
Not available.
Not available.
Not available.
Lower: Not available.
:
Upper: Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
:
Not available.
Not available.
Not available.
Not available.
Page:8/16
Section 10. Stability and reactivity
Reactivity :
Chemical stability :
Possibility of hazardous reactions :
Conditions to avoid :
Incompatible materials :
Hazardous decomposition
products
No specific test data related to reactivity available for this product or
its ingredients.
The product is stable.
Under normal conditions of storage and use, hazardous reactions
will not occur.
No specific data.
No specific data.
Under normal conditions of storage and use, hazardous
:
decomposition products should not be produced. Under normal
conditions of storage and use, hazardous decomposition products
should not be produced.
Section 11. Toxicological information
Information on toxicological effects
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Acute toxicity
Conclusion/Summary :
Very low toxicity to humans or animals.
Irritation/Corrosion
Conclusion/Summary Skin :
The mixture is not an irritant for the skin. Under the application of
the Global Harmonised System (GHS) available data have been used
to assess the hazardous properties of this mixture.
Eyes :
Causes serious eye irritation. Under the application of the Global
Harmonised System (GHS) available data have been used to assess
the hazardous properties of this mixture.
Respiratory :
Based on available data, the classification criteria are not met.
Sensitisation
Conclusion/Summary
Skin :
Respiratory :
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Mutagenicity
Conclusion/Summary :
Not applicable.
Carcinogenicity
Conclusion/Summary :
Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
Reproductive toxicity
Conclusion/Summary :
Not applicable.
Teratogenicity
Conclusion/Summary :
Not applicable.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Causes serious eye irritation.
No known significant effects or critical hazards.
May cause skin irritation.
No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact :
Adverse symptoms may include the following:
redness
irritation
Inhalation :
Skin contact :
Ingestion :
No specific data.
No specific data.
No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route ATE value
Oral>5,000 mg/kg
Page:10/16
Section 12. Ecological information
Toxicity
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Conclusion/Summary :
No known significant effects or critical hazards.
Persistence and degradability
Conclusion/Summary :
No known significant effects or critical hazards.
Conclusion/Summary :
No known significant effects or critical hazards.
Mobility in soil
Soil/water partition coefficient
Not available.
:
(KOC)
Other adverse effects :
No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods :
RCRA classification :
United States - RCRA Acute hazardous waste "P" List: Not listed
United States - RCRA Toxic hazardous waste "U" List: Not listed
The generation of waste should be avoided or minimised wherever
possible. Disposal of this product, s olut i o ns and any by - pr o duct s
should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regio nal local
authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not
be disposed of untreated to the sewer unless fully compliant with the
requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be
considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or
rinsed out. Empty containers or liners may retain some product
residues. Avoid dispersal of spilt material and runoff and contact
with soil, waterways, drains and sewers.
No known significant effects or critical hazards.
Page:11/16
Section 14. Transport information
FOR SHIPMENT IN
CONSUMER
GROUND
PACKAGING
PROPER SHIPPING
NAME:
HAZARD CLASS:
UN/ID #:
Not regulated Not regulated Not regulated
Not regulated Not regulated Not regulated
None None None
PACKING GROUP: None None None
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REQUIRED LABELING: None None None
LABEL TYPE: None None None
Page:12/16
ADDITIONAL
INFORMATION:
Not regulated Not regulated Not regulated
Special precautions for user :
Transport within user’s premises: always transport in closed
containers that are upright and secure. Ensure that persons
transporting the product have been trained in the event of an
accident or spillage.’
Transport in bulk according to Annex II of MARPOL 73/ 78 and the IBC Code
Not available.
Section 15. Regulatory information
U.S. Federal regulations :
United States - TSCA 8(d) - Health a nd safety studies: Not listed
United States - TSCA 8(c) - Significant adverse reaction (SAR):
Not listed
United States - TSCA 8(a) - Preliminary assessment report
(PAIR): Not listed
United States - TSCA 8(a) - Chemical Data Reporting (CDR):
Not determined
United States - TSCA 8(a) - Dioxin/Furan precursor: Not listed
United States - TSCA 6 - Proposed risk management: Not listed
United States - TSCA 6 - Final risk management: Not listed
United States - TSCA 5(e) - Substances consent order: Not listed
United States - TSCA 5(a)2 - Proposed significant new use rules:
Not listed
United States - TSCA 5(a)2 - Final significant new use rules:
Not listed
United States - TSCA 4(f) - Priority risk review: Not listed
United States - TSCA 4(a) - Proposed test rules: Not listed
United States - TSCA 4(a) - ITC Priority list: Not listed
United States - TSCA 4(a) - Final Test Rules: Not listed
United States - TSCA 12(b) - Chemical export notification: The following components are listed: Lauric Acid
United States - TSCA 8(a) - Chemical risk rules: Not listed
United States - EPA Clean water act (CWA) section 307 Priority pollutants: Not listed
United States - EPA Clean water act (CWA) section 311 Hazardous substances: Not listed
United States - EPA Clean air act (CAA) section 112 Accidental release prevention - Flammable substances: Not
listed
United States - EPA Clean air act (CAA) section 112 Accidental release prevention - Toxic substances: Not listed
United States - Department of commerce - Precursor chemical:
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Not listed
Clean Air Act Section 112(b)
:
Not listed
Hazardous Air Pollutants (HAPs)
Clean Air Act Section 602 Class I
:
Not listed
Substances
Clean Air Act Section 602 Class
:
Not listed
II Substances
DEA List I Chemicals (Precursor
:
Not listed
Chemicals)
DEA List II Chemicals (Essential
:
Not listed
Chemicals)
SARA 302/304
Not applicable.
:
SARA 304 RQ:
Not applicable.
SARA 311/312
Classification:
Immediate (acute) health hazard
SARA 313
None of the components are listed.
State regulations
Massachusetts :
The following components are listed:
Glycerin
New York :
New Jersey :
None of the components are listed.
The following components are listed:
Glycerin
Pennsylvania :
The following components are listed:
Glycerin
US California 22CCR Appendix X Substances
Not listed
Page:13/16
California Prop. 65:
Not available.
United States inventory (TSCA
:
Exempted
8b)
Canada inventory :
Not determined.
International regulations
International lists :
Philippines inventory (PICCS): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
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Korea inventory: Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
Taiwan inventory (CSNN): Not determined.
Australia inventory (AICS): Not determined.
Chemical Weapons Convention
List Schedule I Chemicals
Chemical Weapons Convention
List Schedule II Chemicals
Chemical Weapons Convention
List Schedule III Chemicals
EPCRA = Emergency Planning and Community Right‑To‑Know Act
EST = Eastern Standard Time
F = Fire
HAPS = Hazardous Air Pollutants
HCS = Hazard Communication Standard
HMIS = Hazardous Materials Information System
HVOC = High Volatile Organic Compound
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals
IARC = International Agency for the Research of Cancer
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
ICAO = International Civil Aviation Organization
IMDG = International Maritime Dangerous Goods
IMO = International Maritime Organization
ITC = Interagency Testing Committee (TSCA)
KOC = Organic Carbon/Water Partition Constant
LogPow = logarithm of the octanol/water partition coefficient
LVOC = Low Volatile Organic Compound
MARPOL 73/78 = International Convention for the Prevention of Pollution
From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine
pollution)
MPPCF = Million Particles Per Cubic Foot
N/A = Not Applicable
NFPA = National Fire Protection Association
NOEC = No Observable Effect Concentration
NTP = National Toxicology Program
OSHA = Occupation Safety & Health Administration
PEL = Permissible Exposure Limit
RCRA = Resource Conservation & Recovery Act
RQ = Reportable Quantity
RTK = Right-To-Know
SARA = Superfund Amendments & Reauthorization Act
STEL = Short-Term Exposure Limit
TBD = To Be Determined
TCC = Tagliabue Closed Cup
TCLP = Toxicity Characteristic Leaching Procedure
TDG = Transport of Dangerous Goods
TLV = Threshold Limit Value
TSCA = Toxic Substances Control Act
TWA = Time Weighted Average
UN = United Nations
References :
Evaluation method used for mixture classification: Calculation
method.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.
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