Page 1
SAFETY DATA SHEET
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
Product Name:
Phone:
Items:
Formula Code:
Black Flag Ant & Roach Killer
1-800-887-3524
HG-11066; HG-11067; HG-11068
HG-11031; HG-11033; HG-11034
21-1288
SDS Date: 2/25/15
Product Name: Black Flag Ant & Roach Killer
EPA Reg. No. 9688-246
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
CAS #: Aerosol
Product Use: Crawling Bug Insect Killer Aerosol
Manufacturer: Chemsico
Div. of United Industries Corp.
P.O. Box 142642
St. Louis, MO 63114
SECTION 2 - HAZARDS IDENTIFICATION
This product is classified according to the Globally Harmonized System (GHS).
ROUTES OF EXPOSURE
Potential short term health effects: Eyes
Eyes: Moderate eye irritation.
Skin: No expected reaction.
Inhalation: No expected reaction.
Ingestion: No expected reaction.
Target organs: Eyes
Chronic effects: Prolonged or repeated exposure can cause drying,
defatting and dermatitis.
Signs and symptoms: Symptoms may include redness, edema, drying, defatting
and cracking of the skin.
SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Composition comments: This product is considered not hazardous under 29 CFR
1910.1200 (Hazard Communication).
NOTE: No reportable quantities of hazardous ingredients are present per OSHA 29 CFR
1910.1200. No toxic chemical(s) subject to reporting requirements of Section 313 of Title III
and 40 CFR 372 are present.
ACTIVE COMPONENT CAS# PERCENTAGE
Lambda-Cyhalothrin 91465-08-6 0.025%
Imiprothrin 72963-72-5 0.100%
Petroleum Distillates 64742-47-8 4.500%
Diethylene glycol monobutyl ether 112-34-5 1.500%
Isobutane 75-28-5 1.620%
Propane 74-98-6 2.880%
OTHER COMPONENT CAS# PERCENTAGE
Other N/A 89.375%
Note: Ingredients not identified are not hazardous.
Page 1
Page 2
SAFETY DATA SHEET
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
Product Name:
Phone:
Items:
Formula Code:
Black Flag Ant & Roach Killer
1-800-887-3524
HG-11066; HG-11067; HG-11068
HG-11031; HG-11033; HG-11034
21-1288
SECTION 4 - FIRST AID MEASURES
FIRST AID PROCEDURES
Eye contact: Hold eye open and rinse slowly and gently with water for
15-20 minutes. Remove contact lenses if present after the
first 5 minutes then continue rinsing eye. Call a Poison
Skin contact: None required.
Inhalation: None required.
Ingestion: None required.
Note to Physician: Symptoms may be delayed.
Control Center or doctor for treatment advice.
General advice: If you feel unwell, seek medical advice (show the label
where possible). Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect
themselves. Keep out of reach of children.
SECTION 5 - FIRE FIGHTING MEASURES
Flammable properties: Pressurized Aerosol Container
SUITABLE EXTINGUISHING MEDIA
Extinguishing media: Water Fog, Foam, CO2, Dry Chemical
Unsuitable extinguishing media: Not Available
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL
Protection of firefighters: Not Available
Protective equipment for firefighters: Firefighters should wear full protective clothing
including self-contained breathing apparatus.
Hazardous combustion products: None known
SENSITIVITY TO MECHANICAL IMPACT
Explosion data: Not Available
Sensitivity to static discharge: Not Available
Personal precautions: Keep unnecessary personnel away. Do not touch or walk
through spilled material.
HMIS Ratings Health Hazard 1 Fire Hazard 2 Reactivity 0
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Methods for containment: Prevent entry into waterways, sewers, basements or
confined areas.
Methods for cleaning up: Before attempting clean up, refer to hazard data given
above. Small spills may be absorbed with earth, sand or
absorbent material swept up and placed in suitable,
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Page 3
SAFETY DATA SHEET
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
Product Name:
Phone:
Items:
Formula Code:
covered, and labeled containers. Prevent large spills from
entering sewers or waterways. Contact emergency
services and supplier for advice. Never return spills in
original containers for re-use.
SECTION 7 - HANDLING AND STORAGE
Handling: Use good industrial hygiene practices in handling this
material.
Storage: Keep out of reach of children. Store in a closed container
away from incompatible materials.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: General ventilation normally adequate.
EYE / FACE PROTECTION
Personal protective equipment: None required
Hand protection: None required
Skin and body protection: None required
Respiratory protection: None required
General hygiene considerations: Handle in accordance with good industrial hygiene and
safety practice. When using, do not eat or drink. Wash
hands before breaks and immediately after handling the
product.
SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES
Appearance: Clear
Color: Light yellow to water-white
Form: Aerosol
Odor: Aromatic solvent (slight), or fragranced
Odor threshold: Not Available
Physical state: Pressurized liquid
pH: 7.50
Freezing point: 32°F
Boiling point: 212°F
Flash point: >2000F (liquid portion)
Flame Extension 0” (level 1 aerosol)
Flammability limits in air,
lower, % by volume: Not Available
Flammability limits in air,
upper, % by volume: Not Available
Black Flag Ant & Roach Killer
1-800-887-3524
HG-11066; HG-11067; HG-11068
HG-11031; HG-11033; HG-11034
21-1288
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Page 4
SAFETY DATA SHEET
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
Product Name:
Phone:
Items:
Formula Code:
Vapor pressure: Not Available
Vapor density: Not Available
Specific gravity: 1.0008
Octanol/water coefficient: Not Available
Auto-ignition temperature: Not Available
SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION
Chemical stability: Stable under recommended storage conditions.
Conditions to avoid: Do not mix with other chemicals.
Incompatible materials: Avoid strong oxidizers.
Hazardous decomposition products: None known.
Possibility of hazardous reactions: Hazardous polymerization does not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
EFFECTS OF ACUTE EXPOSURE
Eye: Causes moderate eye irritation.
Skin: None expected.
Inhalation: LC50 > 2mg/L (EPA Tox category IV)
Ingestion: LD50 > 5000 mg/kg
Sensitization: Not a skin sensitizer.
Chronic effects/ Carcinogenicity: Not Available
Mutagenicity: Not Available
Reproductive effects: Not Available
Teratogenicity: Not Available
Ecotoxicity: Not Available
SECTION 12 - ECOLOGICAL INFORMATION
Environmental effects: Not Available
Aquatic toxicity: Not Available
Persistence / degradability: Not Available
Bioaccumulation / accumulation: Not Available
Partition coefficient: Not Available
Mobility in environmental media: Not Available
Chemical fate information: Not Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste codes: Not Available
Page 4
Black Flag Ant & Roach Killer
1-800-887-3524
HG-11066; HG-11067; HG-11068
HG-11031; HG-11033; HG-11034
21-1288
Page 5
SAFETY DATA SHEET
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
Product Name:
Phone:
Items:
Formula Code:
Black Flag Ant & Roach Killer
1-800-887-3524
HG-11066; HG-11067; HG-11068
HG-11031; HG-11033; HG-11034
21-1288
Disposal instructions: Dispose in accordance with all applicable regulations.
Waste from residues / unused
products: Not Available
Contaminated packaging: Not Available
SECTION 14 - TRANSPORTATION INFORMATION
U.S. Department of Transportation
(DOT): Aerosols, Flammable, 2.1, UN-1950, Limited Quantity
U.S. Federal regulations: This product is not known to be a "Hazardous Chemical" as
defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200. All components are on the U.S. EPA TSCA
IATA: 1950, Aerosols, Flammable, 2.1
Inventory List.
IMDG: 1950, Aerosols, (Lambda cyhalothrin), Marine Pollutant,
2.1, Limited Quantity
SECTION 15 - REGULATORY INFORMATION
29 CFR 1910.1200 hazardous chemical
Occupational Safety and Health
Administration (OSHA): No
CERCLA (Superfund) reportable
quantity: Not Available
HAZARD CATEGORIES
Superfund Amendments and Reauthorization Act of 1986 (SARA):
Immediate Hazard No
Delayed Hazard No
Fire Hazard No
Pressure Hazard No
Reactivity Hazard No
Section 302 extremely hazardous
Substance: No
Section 311 hazardous chemical: No
Clean Air Act (CAA): Not Available
Clean Water Act (CWA): Not Available
State regulations:
INVENTORY STATUS
Inventory Country(s) or region name
on inventory (yes/no)*: N/A, Regulated by EPA
Disclaimer: Information contained herein was obtained from sources
considered technically accurate and reliable. While every
effort has been made to ensure full disclosure of product
Page 5
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SAFETY DATA SHEET
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
SECTION 16 - OTHER INFORMATION
Issue date: 2/25/15
Prepared by: United Industries Corp.
Product Name:
Phone:
Items:
Formula Code:
Black Flag Ant & Roach Killer
1-800-887-3524
HG-11066; HG-11067; HG-11068
HG-11031; HG-11033; HG-11034
21-1288
hazards, in some cases data is not available and is so
stated. Since conditions of actual product use are beyond
control of the supplier, it is assumed that users of this
material have been fully trained according to the
requirements of all applicable legislation and regulatory
instruments. No warranty, expressed or implied, is made
and supplier will not be liable for any losses, injuries or
consequential damages which may result from the use of
or reliance on any information contained in this document.
(800) 242-1166
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