Diversey 94977476 User Manual

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SAFETY DATA SHEET
Suma Supreme Pot and Pan Detergent
Version Number: 2 Preparation date: 2014-09-10
1. IDENTIFICATION
Product name: Product Code: SDS #: Recommended use:
Uses advised against:
Manufacturer, importer, supplier:
US Headquarters Diversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-1964 Phone: 1-888-352-2249 MSDS Internet Address: www.diversey.com
Emergency telephone number:
Suma Supreme Pot and Pan Detergent 94977476 MS0800363
• Professional kitchen hygiene product
• This product is intended to be diluted prior to use
Uses other than those identified are not recommended
1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)
Classification for the undiluted product
Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Specific target organ toxicity (single exposure)
Category 3
Canadian Headquarters Diversey, Inc. - Canada 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-800-668-3131
2. HAZARDS IDENTIFICATION
Signal Word: Danger
Precautionary Statements MAY CAUSE RESPIRATORY IRRITATION. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE DAMAGE.
Causes burns/ serious damage to mouth, throat and stomach. Avoid contact with eyes, skin and clothing. Avoid breathing spray. Wash affected areas thoroughly after handling. Use only in a well-ventilated area. Wear chemical-splash goggles and chemical-resistant gloves. IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or water. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Immediately call a Poison Center (1-800-851-7145) or physician. Take off contaminated clothing and wash it before reuse. Store in a well-ventilated place. Keep container tightly closed. Dispose of in accordance with all federal, state and local applicable regulations.
Health hazards not otherwise classified (HHNOC) - Not applicable Physical hazards not otherwise classified (PHNOC) - Not applicable
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Classification for the diluted product @ 1:640
This product, when diluted as stated on the label, is not classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and current Canadian Controlled Products Regulations (CPR).
Precautionary Statements
3. COMPOSITION/INFORMATION ON INGREDIENTS
Classified Ingredients
Ingredient(s) CAS # Weight %
Dodecylbenzene sulfonic acid 68584-22-5 20 - 30%
Propylene glycol 57-55-6 10 - 20%
Sodium methyl ester and fatty acids 149458-07-1 5 - 10%
Alcohol ethoxylates 68439-46-3 5 - 10% Alkyl poly glycoside 110615-47-9 5 - 10%
Ammonium laureth sulfate 67762-19-0 5 - 10%
Sodium xylene sulfonate 1300-72-7 1% - < 3%
Ethyl alcohol 64-17-5 1% - < 3%
Magnesium oxide 1309-48-4 1% - < 3%
Sulfuric acid 7664-93-9 > 0.1% - < 1%
Sulphur dioxide 7446-09-5 > 0.1% - < 1%
*Exact percentages are being withheld as trade secret information
4. FIRST AID MEASURES
Undiluted Product:
Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least
15 minutes.
Skin: IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Inhalation: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Ingestion: IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or
water.
Most Important Symptoms/Effects: No information available. Immediate medical attention and special treatment needed Not applicable. Aggravated Medical Conditions: Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may be
more susceptible to irritating effects.
Diluted Product:
Eyes: Rinse with plenty of water If irritation occurs and persists, get medical attention Skin: Rinse with plenty of water If irritation occurs and persists, get medical attention Inhalation: No specific first aid measures are required Ingestion: Rinse mouth with water.
5. FIRE-FIGHTING MEASURES
Specific methods: Suitable extinguishing media: Specific hazards:
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear. Extinguishing media which must not be used for safety reasons: No information available.
No special methods required The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Not applicable.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
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Put on appropriate personal protective equipment (see Section 8.).
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Environmental precautions and clean-up methods:
Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up.
7. HANDLING AND STORAGE
Handling: Avoid contact with skin, eyes and clothing. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation.
Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage:
Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN.
Aerosol Level (if applicable) : Not applicable
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Ingredient(s) CAS # ACGIH OSHA
Dodecylbenzene sulfonic acid 68584-22-5 - -
Propylene glycol 57-55-6 - -
Sodium methyl ester and fatty acids 149458-07-1 - -
Alcohol ethoxylates 68439-46-3 - ­Alkyl poly glycoside 110615-47-9 - -
Ammonium laureth sulfate 67762-19-0 - -
Sodium xylene sulfonate 1300-72-7 - -
Ethyl alcohol 64-17-5 1000 ppm (STEL) 1000 ppm (TWA)
Magnesium oxide 1309-48-4 10 mg/m3 (TWA) 15 mg/m3 (TWA)
Sulfuric acid 7664-93-9 0.2 mg/m3 (TWA) 1 mg/m3 (TWA)
Sulphur dioxide 7446-09-5 0.25 ppm (STEL) 5 ppm (TWA)
.
1900 mg/m3 (TWA)
13 mg/m3 (TWA)
Undiluted Product:
Engineering measures to reduce exposure:
Good general ventilation should be sufficient to control airborne levels Respiratory protection is not required if good ventilation is maintained.
Personal Protective Equipment
Eye protection: Hand protection: Skin and body protection: Respiratory protection: Hygiene measures:
Chemical-splash goggles. Chemical-resistant gloves. No special requirements under normal use conditions. No special requirements under normal use conditions. Handle in accordance with good industrial hygiene and safety practice.
Diluted Product:
Personal Protective Equipment
Eye protection: Hand protection: Skin and body protection: Respiratory protection: Hygiene measures:
No special requirements under normal use conditions. No special requirements under normal use conditions. No special requirements under normal use conditions. No special requirements under normal use conditions. Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Physical State: Liquid Color: Clear Dark Blue Evaporation Rate: No information available Odor: Floral Odor threshold: No information available. Boiling point/range: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Solubility: Completely Soluble Solubility in other solvents: No information available Relative Density (relative to water): 1.093 Density: 9.12 lbs/gal 1.093 Kg/L Vapor density: No information available Bulk density: No information available Vapor pressure: No information available. Flash point: > 200 °F > 93.3 °C Partition coefficient (n-octanol/water): No information available Dilution Flash Point: > 200 °F > 93.3 °C Viscosity: No information available Elemental Phosphorus: 0.00 % by wt. VOC: 2.09 % *
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pH: 6.44 VOC % by wt. at use dilution 0 % * Dilution pH: 6.37 @ 1:640 Flammability (Solid or Gas): Not applicable Metal Corrosion: Not determined Explosion limits: - upper: Not determined - lower: Not determined
* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508
10. STABILITY AND REACTIVITY
Reactivity: Stability: Hazardous decomposition products: Materials to avoid: Conditions to avoid:
Not Applicable The product is stable None reasonably foreseeable. None known. No information available.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure:
Skin contact, Inhalation, Ingestion, Eye contact
Delayed, immediate, or chronic effects and symptoms from short and long-term exposure Skin contact: Causes skin irritation. Symptoms may include pain (which may be delayed), redness, and/or discomfort. Eye contact: Corrosive. Causes serious eye damage. Symptoms may include pain, burning sensation, redness, watering, blurred
vision or loss of vision.
Ingestion: Causes burns/ serious damage to mouth, throat and stomach. Symptoms may include stomach pain and nausea. Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Symptoms may include coughing and
difficulty breathing.
Sensitization: No known effects.
Ingredient(s) CAS # NTP IARC OSHA
Ethyl alcohol 64-17-5 -
Sulfuric acid 7664-93-9 X 1
This product contains sulfuric acid. Strong inorganic sulfuric acid mists are classified as known human carcinogens by IARC and NTP. However, this product is not intended to be sprayed or misted. Therefore, this product will not form sulfuric acid mists under normal use conditions or foreseeable emergencies
Numerical measures of toxicity
ATE - Oral (mg/kg): ATE - Dermal (mg/kg): ATE - Inhalatory, gases (mg/l): ATE - Inhalatory, mists (mg/l):
3800 2100 >2500 >20
12. ECOLOGICAL INFORMATION
Ecotoxicity: No information available. Persistence and Degradability: No information available. Bioaccumulation: No information available.
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products: This product, as sold, if discarded or disposed, is not a hazardous waste according to Federal
regulations (40 CFR 261.4 (b)(4)). Dispose in compliance with all Federal, state, provincial, and local laws and regulations. This product, when diluted as stated on this SDS, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations.
Contaminated Packaging: Do not re-use empty containers. RCRA Hazard Class (undiluted product): Not Regulated
RCRA Hazard Class (diluted product): Not Regulated
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14. TRANSPORT INFORMATION
DOT/TDG/IMDG: Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up
to date shipping information.
DOT (Ground) Bill of Lading Description:
IMDG (Ocean) Bill of Lading Description:
CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID CLEANING, WASHING, BUFFING, OR POLISHING COMPOUNDS LIQUID
15. REGULATORY INFORMATION
International Inventories at CAS# Level
All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL).
U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65.
RIGHT TO KNOW (RTK)
Sodium methyl ester and fatty acids 149458-07-1 - - - -
Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:
Water 7732-18-5 - - - -
Dodecylbenzene sulfonic acid 68584-22-5 - - - -
Propylene glycol 57-55-6 - X X -
Alcohol ethoxylates 68439-46-3 - - - ­Alkyl poly glycoside 110615-47-9 - - - -
Ammonium laureth sulfate 67762-19-0 - - - -
Sodium xylene sulfonate 1300-72-7 - - - -
Ethyl alcohol 64-17-5 X X X -
Magnesium oxide 1309-48-4 X X X -
Sulfuric acid 7664-93-9 X X X X
Sulphur dioxide 7446-09-5 X X X X
CERCLA/ SARA
Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313
Sulfuric acid 7664-93-9 > 0.1% - < 1% 1000 1000 X
Sulphur dioxide 7446-09-5 > 0.1% - < 1% 500
SARA 311/312 Hazard Categories
Immediate: Delayed: Fire: Reactivity: Sudden Release of Pressure:
Canada
Ingredient(s) CAS # NPRI
Ethyl alcohol 64-17-5 X
Sulfuric acid 7664-93-9 X
Sulphur dioxide 7446-09-5 X
NFPA Health 3 Flammability 0 Instability 0
x
-
-
-
-
16. OTHER INFORMATION
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Version Number: 2 Preparation date: 2014-09-10
Reason for revision: Prepared by: Additional advice:
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
Not applicable NAPRAC
• Contains an added fragrance, see "Odor" heading in section 9 for specific description
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