Diversey 2853280 User Manual

SAFETY DATA SHEET
Liqu-A-Klor Liquid-Bactericide Disinfectant and Sanitizer
Version Number: 3 Preparation date: 2015-02-27
1. IDENTIFICATION
Product name: Product Code: SDS #: Recommended use:
Uses advised against:
Manufacturer, importer, supplier:
US Headquarters Diversey, Inc. P.O. Box 19747 Charlotte, NC 28219-0747 Phone: 1-888-352-2249 SDS Internet Address: www.diversey.com
Emergency telephone number:
Liqu-A-Klor Liquid-Bactericide Disinfectant and Sanitizer 02853280, 100839975 MS0800350
• Disinfectant
• This product is intended to be diluted prior to use
Uses other than those identified are not recommended
1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)
2. HAZARDS IDENTIFICATION
Classification for the undiluted product
Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Metal Corrosion: Category 1
Signal Word: Danger.
Precautionary Statements
Avoid contact with eyes, skin and clothing. Causes burns/ serious damage to mouth, throat and stomach. Keep container tightly closed. Keep only in original container. Do not breathe spray. Wash affected areas thoroughly after handling. Wear chemical-splash goggles, chemical-resistant gloves and protective footwear. IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or water. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water for at least 15 minutes. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Immediately call a Poison Center (1-800-851-7145) or physician. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Store in corrosive-resistant container with a resistant inner liner. Dispose of in accordance with all federal, state and local applicable regulations.
Health hazards not otherwise classified (HHNOC) - Not applicable Physical hazards not otherwise classified (PHNOC) - Not applicable
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Classification for the diluted product @ 1:512
This product, when diluted as stated on the label, is not classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and current Canadian Controlled Products Regulations (CPR).
Precautionary Statements
None required.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Classified Ingredients
Ingredient(s) CAS # Weight %
Sodium hypochlorite 7681-52-9 5 - 10%
Sodium hydroxide 1310-73-2 > 0.1% - < 1%
*Exact percentages are being withheld as trade secret information
4. FIRST AID MEASURES
Undiluted Product:
Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least
15 minutes.
Skin: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water for at least 15 minutes. Inhalation: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Ingestion: IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or
water.
Most Important Symptoms/Effects: No information available. Immediate medical attention and special treatment needed Not applicable. Aggravated Medical Conditions: Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may be
more susceptible to irritating effects.
Diluted Product:
Eyes: Rinse with plenty of water If irritation occurs and persists, get medical attention. Skin: Rinse with plenty of water If irritation occurs and persists, get medical attention. Inhalation: No specific first aid measures are required Ingestion: Rinse mouth with water.
5. FIRE-FIGHTING MEASURES
Specific methods: Suitable extinguishing media: Specific hazards:
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear. Extinguishing media which must not be used for safety reasons: No information available.
No special methods required The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Corrosive material (See sections 8 and 10).
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Environmental precautions and clean-up methods:
Put on appropriate personal protective equipment (see Section 8.). Clean-up methods - large spillage. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use a water rinse for final clean-up.
7. HANDLING AND STORAGE
Handling: Avoid contact with skin, eyes and clothing. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation.
Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Mix only with water. Do not mix with acids or acid detergents. Do not mix with any other product or chemical. Product residue may remain on/in empty containers. All precautions for handling
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the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage: Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. Aerosol Level (if applicable) : Not applicable
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Ingredient(s) CAS # ACGIH OSHA
Sodium hypochlorite 7681-52-9 - -
Sodium hydroxide 1310-73-2 2 mg/m3 (Ceiling) 2 mg/m3 (TWA)
.
Undiluted Product:
Engineering measures to reduce exposure:
Good general ventilation should be sufficient to control airborne levels Respiratory protection is not required if good ventilation is maintained.
Personal Protective Equipment
Eye protection: Hand protection: Skin and body protection: Respiratory protection:
Hygiene measures:
Chemical-splash goggles. Chemical-resistant gloves. Protective footwear. If major exposure is possible, wear suitable protective clothing and footwear. In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Handle in accordance with good industrial hygiene and safety practice.
Diluted Product:
Personal Protective Equipment
Eye protection: Hand protection: Skin and body protection: Respiratory protection: Hygiene measures:
No personal protective equipment required under normal use conditions. No personal protective equipment required under normal use conditions. No personal protective equipment required under normal use conditions. No personal protective equipment required under normal use conditions. Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Physical State: Liquid Color: Clear Yellow Evaporation Rate: No information available Odor: Chlorine Odor threshold: No information available. Boiling point/range: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Solubility: Completely Soluble Solubility in other solvents: No information available Relative Density (relative to water): 1.08 Density: 9.01 lbs/gal 1.08 Vapor density: No information available Bulk density: No information available Vapor pressure: No information available. Flash point: > 200 °F > 93.3 °C Partition coefficient (n-octanol/water): No information available Dilution Flash Point: > 200 °F > 93.3 °C Viscosity: No information available Elemental Phosphorus: 0 % by wt. VOC: 0 % * pH: 12.2 VOC % by wt. at use dilution 0 % * Dilution pH: 12 @ 1:512 Flammability (Solid or Gas): Not applicable Metal Corrosion: Not determined Explosion limits: - upper: Not determined - lower: Not determined
* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508
10. STABILITY AND REACTIVITY
Reactivity: Stability: Hazardous decomposition products: Materials to avoid: Conditions to avoid:
Not Applicable The product is stable None reasonably foreseeable. Do not mix with any other product or chemical. Ammonia. Acids. Reacts with acids releasing chlorine. No information available.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure:
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Eye contact, Skin contact, Inhalation, Ingestion
Delayed, immediate, or chronic effects and symptoms from short and long-term exposure Skin contact: Corrosive. Causes severe burns. Symptoms may include burns, blisters, redness and pain (which may be delayed). Eye contact: Corrosive. Causes serious eye damage. Symptoms may include pain, burning sensation, redness, watering, blurred
vision or loss of vision.
Ingestion: Causes burns/ serious damage to mouth, throat and stomach. Symptoms may include stomach pain and nausea. Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Symptoms may include coughing and
difficulty breathing.
Sensitization: No known effects. Target Organs (SE): None known Target Organs (RE): None known
Numerical measures of toxicity
12. ECOLOGICAL INFORMATION
Ecotoxicity: No information available. Persistence and Degradability: No information available. Bioaccumulation: No information available.
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products: PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Local/Municipal
ordinances regarding disposal of pesticide wastes. Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste reporesentative at the nearest EPA Regional Office for guidance. This product, as sold, if discarded or disposed, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Dispose in compliance with all Federal, state, provincial, and local laws and regulations. This product, when diluted as stated on this SDS, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations.
Contaminated Packaging: Do not re-use empty containers. RCRA Hazard Class (undiluted product): Not Regulated
RCRA Hazard Class (diluted product): Not Regulated
14. TRANSPORT INFORMATION
DOT/TDG/IMDG: Proper shipping descriptions can vary by pack size. Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up to date shipping information.
DOT (Ground) Bill of Lading Description:
IMDG (Ocean) Bill of Lading Description:
UN1791, HYPOCHLORITE SOLUTION, 8, III UN1791, HYPOCHLORITE SOLUTION, 8, III, MARINE POLLUTANT
15. REGULATORY INFORMATION
International Inventories at CAS# Level
All components of this product are listed on the following inventories: U.S.A. (TSCA).
U.S. Regulations EPA Reg. No. : 875-190
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.
DANGER: CORROSIVE. May cause severe skin and eye irritation or chemical burns to broken skin. Causes eye damage. Do not get in eyes, on skin or on clothing. Wear goggles or face shield and rubber gloves when handling this product. Wash thoroughly with soap and water after handling
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and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and wash clothing before reuse. Avoid breathing vapors. Vacate poorly ventilated areas as soon as possible. Do not return until odors have dissipated. PHYSICAL AND CHEMICAL HAZARDS: STRONG OXIDIZING AGENT. Mix only with water according to label directions. Mixing this product with gross filth such as feces, urine, etc., or with ammonia, acids, detergents or other chemicals may release hazardous gases, which are irritating to eyes, lungs and mucous membranes. ENVIRONMENTAL HAZARDS: This pesticide is toxic to fish and aquatic organisms.
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65.
RIGHT TO KNOW (RTK)
CERCLA/ SARA
SARA 311/312 Hazard Categories
Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:
Water 7732-18-5 - - - -
Sodium hypochlorite 7681-52-9 X X X X
Sodium hydroxide 1310-73-2 X X X X
Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313
Sodium hypochlorite 7681-52-9 5 - 10% 100
Sodium hydroxide 1310-73-2 > 0.1% - < 1% 1000
Immediate: Delayed: Fire: Reactivity: Sudden Release of Pressure:
X
-
-
-
-
Canadian Regulations
WHMIS hazard class: Not for sale in Canada.
16. OTHER INFORMATION
NFPA (National Fire Protection Association)
Rating Scale: (Low Hazard) 0 - 4 (Extreme Hazard)
Health 3 Flammability 0 Instability 0
Version Number: 3 Preparation date: 2015-02-27
Reason for revision: Prepared by: Additional advice:
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
Not applicable NAPRAC
• Does not contain an added fragrance
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