SAFETY DATA SHEET
Revision Date 12-May-2015
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
10 Columbus Blvd.
Hartford, CT 06106 USA
Company Phone Number
24 Hour Emergency Phone Number
DEVCON HOME METAL PATCH & FILL 3 OZ.
50345
None
Filler
No information available
Distributor
ITW Permatex Canada
35 Brownridge Road, Unit 1
Halton Hills, ON Canada L7G 0C6
Telephone: (800) 924-6994
1-87-Permatex
(877) 376-2839
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
Version 1
E-mail address
mail@permatex.com
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Category 4
Acute toxicity - Inhalation (Dusts/Mists) Category 4
Serious eye damage/eye irritation Category 2
Carcinogenicity Category 1B
Specific target organ toxicity (single exposure) Category 3
Flammable liquids
Label elements
Emergency Overview
Danger
_____________________________________________________________________________________________
Category 2
Page 1 / 9
50345 - DEVCON HOME METAL PATCH & FILL 3 OZ.
Revision Date 12-May-2015
_____________________________________________________________________________________________
Harmful if swallowed
Harmful if inhaled
Causes serious eye irritation
May cause cancer
May cause drowsiness or dizziness
Highly flammable liquid and vapor
Appearance Gray Physical state Paste Odor Ketone
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. — No smoking
Take precautionary measures against static discharge
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
In case of fire: Use CO2, dry chemical, or foam for extinction
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Not applicable.
Unknown acute toxicity 48% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
substance(s)
Chemical Name CAS No Weight-% Trade Secret
KAOLIN 1332-58-7 15 - 40 *
METHYL ETHYL KETONE (BUTANONE) 78-93-3 10 - 30 *
_____________________________________________________________________________________________
Page 2 / 9
50345 - DEVCON HOME METAL PATCH & FILL 3 OZ. Revision Date 12-May-2015
_____________________________________________________________________________________________
BARIUM SULFATE 7727-43-7 10 - 30 *
METHYL ISOBUTYL KETONE 108-10-1 5 - 10 *
ALUMINIUM POWDER 7429-90-5 5 - 10 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice
Eye contact
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Get medical advice/attention if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower. Wash with soap and water. If skin irritation persists, call a physician.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
See section 2 for more information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None.
Specific hazards arising from the chemical
Highly flammable.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
_____________________________________________________________________________________________
Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or
clothing. Use personal protective equipment as required. Take precautionary measures
against static discharges.
Page 3 / 9
50345 - DEVCON HOME METAL PATCH & FILL 3 OZ. Revision Date 12-May-2015
_____________________________________________________________________________________________
Environmental precautions
Do not flush into surface water or sanitary sewer system. See Section 12 for additional
ecological information.
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevent further leakage or spillage if safe to do so.
Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with
inert absorbent material. Sweep up and shovel into suitable containers for disposal.
Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Incompatible materials
Store locked up. Keep in a dry, cool and well-ventilated place.
Strong oxidizing agents, Acids, Alkalis
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
KAOLIN
1332-58-7
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
BARIUM SULFATE
7727-43-7
METHYL ISOBUTYL KETONE
108-10-1
ALUMINIUM POWDER
7429-90-5
.
TWA: 2 mg/m3 particulate matter
containing no asbestos and <1%
crystalline silica, respirable fraction
STEL: 300 ppm
TWA: 200 ppm
TWA: 5 mg/m3 inhalable fraction,
particulate matter containing no
asbestos and <1% crystalline silica
STEL: 75 ppm
TWA: 20 ppm
TWA: 1 mg/m3 respirable fraction TWA: 15 mg/m3 total dust
NIOSH IDLH Immediately Dangerous to Life or Health
TWA: 15 mg/m3 total dust
TWA: 5 mg/m3 respirable fraction
(vacated) TWA: 10 mg/m3 total dust
(vacated) TWA: 5 mg/m3 respirable
(vacated) TWA: 200 ppm
(vacated) TWA: 590 mg/m
(vacated) STEL: 300 ppm
(vacated) STEL: 885 mg/m
TWA: 15 mg/m3 total dust
TWA: 5 mg/m3 respirable fraction
(vacated) TWA: 10 mg/m3 total dust
(vacated) TWA: 5 mg/m3 respirable
(vacated) TWA: 205 mg/m
(vacated) STEL: 75 ppm
(vacated) STEL: 300 mg/m
TWA: 5 mg/m3 respirable fraction
(vacated) TWA: 5 mg/m3 Al
fraction
TWA: 200 ppm
TWA: 590 mg/m
fraction
TWA: 100 ppm
TWA: 410 mg/m
(vacated) TWA: 50 ppm
Aluminum
3
3
3
3
3
3
TWA: 10 mg/m3 total dust
TWA: 5 mg/m3 respirable dust
IDLH: 3000 ppm
TWA: 200 ppm
TWA: 590 mg/m
STEL: 300 ppm
STEL: 885 mg/m
TWA: 10 mg/m3 total dust
TWA: 5 mg/m3 respirable dust
IDLH: 500 ppm
TWA: 50 ppm
TWA: 205 mg/m
STEL: 75 ppm
STEL: 300 mg/m
TWA: 5 mg/m3 Al
3
3
3
3
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
_____________________________________________________________________________________________
Page 4 / 9
50345 - DEVCON HOME METAL PATCH & FILL 3 OZ.
Revision Date 12-May-2015
_____________________________________________________________________________________________
Appropriate engineering controls
Engineering Controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
General Hygiene Considerations
Showers
Eyewash stations
Ventilation systems
Wear safety glasses with side shields (or goggles).
Wear protective gloves and protective clothing.
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Property
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Paste
Gray
Ketone
No information available
Values
No information available
No information available
No information available
4 °C / 40 °F
< 1
No information available
No information available
No information available
Not determined
>1
1.51
Slightly soluble
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
Remarks • Method
Ceta Closed Cup
Butyl acetate = 1
Air = 1
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
No information available
No information available
437 g/L
No information available
No information available
10. STABILITY AND REACTIVITY
_____________________________________________________________________________________________
Page 5 / 9
50345 - DEVCON HOME METAL PATCH & FILL 3 OZ. Revision Date 12-May-2015
_____________________________________________________________________________________________
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Strong oxidizing agents, Acids, Alkalis
Hazardous Decomposition Products
Carbon oxides
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
METHYL ISOBUTYL KETONE
108-10-1
May cause irritation of respiratory tract.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis.
May be harmful if swallowed.
= 2483 mg/kg ( Rat ) = 2737 mg/kg
( Rat )
= 2080 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 8.2 mg/L ( Rat ) 4 h
= 5000 mg/kg ( Rabbit ) = 6480
mg/kg ( Rabbit )
= 11700 ppm ( Rat ) 4 h
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
METHYL ISOBUTYL
KETONE
108-10-1
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 2A - Probably Carcinogenic to Humans
Group 2B - Possibly Carcinogenic to Humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Chronic toxicity
Target Organ Effects
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
A3 Group 2B - X
May cause adverse liver effects.
Central nervous system, Eyes, kidney, Liver, Respiratory system, Skin.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
ATEmix (inhalation-dust/mist)
1225 mg/kg
7536 mg/kg
3.5 mg/l
_____________________________________________________________________________________________
Page 6 / 9
50345 - DEVCON HOME METAL PATCH & FILL 3 OZ. Revision Date 12-May-2015
_____________________________________________________________________________________________
ATEmix (inhalation-vapor)
27655 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
70.5% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
METHYL ISOBUTYL KETONE
108-10-1
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Chemical Name Partition coefficient
METHYL ETHYL KETONE (BUTANONE)
78-93-3
METHYL ISOBUTYL KETONE
108-10-1
400: 96 h Pseudokirchneriella
subcapitata mg/L EC50
- 3130 - 3320: 96 h Pimephales
promelas mg/L LC50 flow-through
496 - 514: 96 h Pimephales
promelas mg/L LC50 flow-through
520: 48 h Daphnia magna mg/L
EC50 5091: 48 h Daphnia magna
mg/L EC50 4025 - 6440: 48 h
Daphnia magna mg/L EC50 Static
170: 48 h Daphnia magna mg/L
EC50
0.29
1.19
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Contaminated packaging
US EPA Waste Number
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
METHYL ISOBUTYL
KETONE
108-10-1
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
METHYL ETHYL KETONE (BUTANONE)
78-93-3
BARIUM SULFATE
7727-43-7
ALUMINIUM POWDER
7429-90-5
This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261).
Do not reuse container.
D001
U159 Included in waste streams:
F005, F039
- Included in waste stream:
F039
200.0 mg/L regulatory level U159
- U161
Toxic
Ignitable
Toxic soluble
Ignitable powder
_____________________________________________________________________________________________
Page 7 / 9
50345 - DEVCON HOME METAL PATCH & FILL 3 OZ. Revision Date 12-May-2015
_____________________________________________________________________________________________
14. TRANSPORT INFORMATION
DOT
UN/ID no
Proper shipping name:
Hazard Class
Packing Group
Emergency Response Guide
Number
IATA
UN/ID no
Proper shipping name:
Hazard Class
ERG Code
IMDG
UN/ID no
Proper shipping name:
Hazard Class
Packing Group
EmS-No
1133
Adhesives, Limited Quantity (LQ)
3
II
128
ID 8000
Consumer commodity
9
9L
1133
Adhesives, Limited Quantity (LQ)
3
II
F-E, S-D
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
BARIUM SULFATE - 7727-43-7 1.0
METHYL ISOBUTYL KETONE - 108-10-1 1.0
ALUMINIUM POWDER - 7429-90-5 1.0
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
_____________________________________________________________________________________________
Complies
Complies
Not Listed.
Not Listed.
Complies
Complies
Complies
Not Listed.
Yes
Yes
Yes
No
No
Page 8 / 9
50345 - DEVCON HOME METAL PATCH & FILL 3 OZ.
Revision Date 12-May-2015
_____________________________________________________________________________________________
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
METHYL ISOBUTYL KETONE
108-10-1
5000 lb - RQ 5000 lb final RQ
RQ 2270 kg final RQ
5000 lb - RQ 5000 lb final RQ
RQ 2270 kg final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
METHYL ISOBUTYL KETONE - 108-10-1 Carcinogen
U.S. State Right-to-Know Regulations
Developmental
Chemical Name New Jersey Massachusetts Pennsylvania
KAOLIN
1332-58-7
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
BARIUM SULFATE
7727-43-7
METHYL ISOBUTYL KETONE
108-10-1
ALUMINIUM POWDER
7429-90-5
AMORPHOUS SILICA
61790-53-2
X X X
X X X
X X X
X X X
X X X
X - -
U.S. EPA Label Information
EPA Pesticide Registration Number
NFPA
HMIS
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Health hazards 2 Flammability 3
Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B
Revision Date
Not applicable
12-May-2015
Instability 0
-
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 9 / 9
Loading...