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SAFETY DATA SHEET
Revision Date 29-Jan-2015 Version 1
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
10 Columbus Blvd.
Hartford, CT 06106 USA
DEVCON HOME BLUE THREADLOCKER 6 ML
24345
None
Sealant
No information available
Distributor
ITW Permatex Canada
35 Brownridge Road, Unit 1
Halton Hills, ON Canada L7G 0C6
Telephone: (800) 924-6994
Company Phone Number
24 Hour Emergency Phone Number
1-87-Permatex
(877) 376-2839
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Category 4
Acute toxicity - Dermal Category 4
Acute toxicity - Inhalation (Dusts/Mists) Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Carcinogenicity Category 2
Specific target organ toxicity (repeated exposure) Category 2
Label elements
Emergency Overview
Warning
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Harmful if swallowed
Harmful in contact with skin
Harmful if inhaled
Causes skin irritation
Causes serious eye irritation
Suspected of causing cancer
May cause damage to organs through prolonged or repeated exposure
Appearance Blue
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Use only outdoors or in a well-ventilated area
Wear eye/face protection
Do not breathe dust/fume/gas/mist/vapors/spray
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
Call a POISON CENTER or doctor/physician if you feel unwell
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
In case of fire: Use CO2, dry chemical, or foam for extinction
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Physical state Liquid Odor Mild
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Not applicable.
Unknown acute toxicity 96.726% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
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Chemical Name CAS No Weight-% Trade Secret
POLYGLYCOL DIMETHACRYLATE 25852-47-5 40 - 70 *
POLYGLYCOL OLEATE 9004-96-0 10 - 30 *
DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 1 - 5 *
SACCHARIN 81-07-2 1 - 5 *
TITANIUM DIOXIDE 13463-67-7 0.1 - 1 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice
Eye contact
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Get medical advice/attention if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician.
Wash contaminated clothing before reuse.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person.
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
See section 2 for more information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None.
Specific hazards arising from the chemical
None in particular.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
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Personal precautions
Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin.
Use personal protective equipment as required.
Environmental precautions
Environmental precautions
Do not flush into surface water or sanitary sewer system. See Section 12 for additional
ecological information.
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevent further leakage or spillage if safe to do so.
Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel
into suitable containers for disposal.
Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Storage Conditions
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials
Strong oxidizing agents, Peroxides, Reducing agent
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
TITANIUM DIOXIDE
13463-67-7
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information
Appropriate engineering controls
Engineering Controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
.
TWA: 10 mg/m
3
TWA: 15 mg/m3 total dust
(vacated) TWA: 10 mg/m3 total dust
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Showers
Eyewash stations
Ventilation systems
Wear safety glasses with side shields (or goggles).
Wear protective gloves and protective clothing.
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
IDLH: 5000 mg/m
3
General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
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Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Property Values Remarks • Method
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Liquid
Blue
Mild
No information available
Does not apply
No information available
> 149 °C / 300 °F
> 93 °C / > 199 °F
No information available
No information available
No information available
No information available
n/d
>1 Air = 1
1.00-1.15
Insoluble
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
No information available
No information available
<2%
No information available
No information available
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Excessive heat.
Incompatible materials
Strong oxidizing agents, Peroxides, Reducing agent
Hazardous Decomposition Products
Carbon oxides
11. TOXICOLOGICAL INFORMATION
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Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
DIMETHYLBENZYL
HYDROPEROXIDE
80-15-9
TITANIUM DIOXIDE
13463-67-7
May cause irritation of respiratory tract.
Contact with eyes may cause irritation.
May cause skin irritation and/or dermatitis.
Ingestion may cause irritation to mucous membranes.
= 382 mg/kg ( Rat ) = 0.126 mL/kg ( Rabbit ) = 220 ppm ( Rat ) 4 h
> 10000 mg/kg ( Rat ) - -
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
SACCHARIN
81-07-2
TITANIUM DIOXIDE
13463-67-7
IARC (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans
Not classifiable as a human carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
- Group 3 - -
- Group 2B - X
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
ATEmix (inhalation-dust/mist)
618 mg/kg
1778 mg/kg
0.8 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
None known
95.986% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
DIMETHYLBENZYL
HYDROPEROXIDE
80-15-9
SACCHARIN
81-07-2
Persistence and degradability
No information available.
Bioaccumulation
No information available.
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- 3.9: 96 h Oncorhynchus mykiss
mg/L LC50 static
- 18300: 96 h Pimephales promelas
mg/L LC50
7: 24 h Daphnia magna mg/L EC50
-
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Mobility
No information available.
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging
US EPA Waste Number
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
DIMETHYLBENZYL
HYDROPEROXIDE
80-15-9
Do not reuse container.
Not applicable
- - - U096
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
DIMETHYLBENZYL HYDROPEROXIDE
80-15-9
Toxic
Ignitable
14. TRANSPORT INFORMATION
DOT
Proper shipping name:
IATA
Proper shipping name:
Not regulated
Not regulated
IMDG
Proper shipping name:
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
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Complies
Complies
Does not comply
Complies
Complies
Complies
Complies
Complies
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AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
DIMETHYLBENZYL HYDROPEROXIDE - 80-15-9 1.0
SACCHARIN - 81-07-2 1.0
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Yes
No
No
No
No
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
DIMETHYLBENZYL
HYDROPEROXIDE
80-15-9
10 lb - RQ 10 lb final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
TITANIUM DIOXIDE - 13463-67-7 Carcinogen
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
DIMETHYLBENZYL
HYDROPEROXIDE
80-15-9
SACCHARIN
81-07-2
TITANIUM DIOXIDE
13463-67-7
1,4-NAPHTHOQUINONE
130-15-4
U.S. EPA Label Information
EPA Pesticide Registration Number
Not applicable
NFPA Health hazards 2 Flammability 1 Instability 0
HMIS Health hazards 2 Flammability 1
X X X
X X X
X X X
X X X
Physical hazards 0 Personal protection B
RQ 4.54 kg final RQ
-
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
29-Jan-2015
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Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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