SAFETY DATA SHEET
Revision Date 27-Sep-2018 Version 8
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
6875 Parkland Blvd.
Solon, OH 44139 USA
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
DEVCON HOME PLASTIC WELDER (ACTIVATOR)
22045V
Activator
No information available
May Also Be Distributed by:
ITW Permatex Canada
101-2360 Bristol Circle
Oakville, ON Canada L6H 6M5
Telephone: (800) 924-6994
E-mail address: mail@permatex.com
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2B
Skin sensitization Category 1
Flammable liquids
Label elements
Emergency Overview
Signal word
Danger
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
Highly flammable liquid and vapor
Category 2
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22045V - DEVCON HOME PLASTIC WELDER
Revision Date 27-Sep-2018
(ACTIVATOR)
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Appearance White Physical state Viscous liquid
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Do not eat, drink or smoke when using this product
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Use non-sparking tools
Take precautionary measures against static discharge
Precautionary Statements - Response
Specific treatment (see supplemental first aid instructions on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Take off contaminated clothing and wash before reuse
If skin irritation or rash occurs: Get medical advice/attention
Precautionary Statements - Storage
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Odor Methyl methacrylate
Other Information
- Not applicable
Unknown acute toxicity 20 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance(s)
Chemical Name CAS No Weight-%
METHYL METHACRYLATE 80-62-6 60 - 100
4. FIRST AID MEASURES
Description of first aid measures
General advice
Eye contact
_____________________________________________________________________________________________
In case of accident or unwellness, seek medical advice immediately (show directions for
use or safety data sheet if possible).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
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22045V - DEVCON HOME PLASTIC WELDER
Revision Date 27-Sep-2018
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advice/attention.
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Wash
contaminated clothing before reuse.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.
May cause allergic skin reaction.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None
Specific hazards arising from the chemical
Highly flammable. Vapors may travel to source of ignition and flash back.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or
clothing. Use personal protective equipment as required. Wash thoroughly after handling.
See Section 12 for additional Ecological Information.
Prevent further leakage or spillage if safe to do so.
Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with
inert absorbent material. Sweep up and shovel into suitable containers for disposal.
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22045V - DEVCON HOME PLASTIC WELDER
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Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Remove all sources of ignition. Keep away from heat/sparks/open flames/hot surfaces. - No
smoking.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric
motors and static electricity). Store locked up.
Incompatible materials
Strong oxidizing agents, Reducing agents
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
METHYL METHACRYLATE
80-62-6
NIOSH IDLH Immediately Dangerous to Life or Health
.
STEL: 100 ppm
TWA: 50 ppm
TWA: 100 ppm
TWA: 410 mg/m
(vacated) TWA: 100 ppm
(vacated) TWA: 410 mg/m
3
IDLH: 1000 ppm
TWA: 100 ppm
3
TWA: 410 mg/m
3
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate engineering controls
Engineering Controls
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
Wear safety glasses with side shields (or goggles).
Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Viscous liquid
White
Methyl methacrylate
0.75 ppm
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Property Values Remarks • Method
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Other Information
No information available
No information available
101 °C / 214 °F
12 °C / 54 °F Tag Closed Cup
>1 Butyl acetate = 1
No information available
12.5%
1.6%
28 mmHg @ 68°F
>3 Air = 1
0.95
Slightly soluble
No information available
No information available
421°C (789.8°F)
No information available
No information available
No information available
No information available
No information available
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
No information available
No information available
<50 g/L
No information available
No information available
10. STABILITY AND REACTIVITY
Reactivity
Stable under normal conditions
Chemical stability
Stable under recommended storage conditions
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Strong oxidizing agents, Reducing agents
Hazardous Decomposition Products
Carbon oxides
Nitrogen oxides (NOx)
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
May cause irritation of respiratory tract.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis. May cause sensitization by skin contact.
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Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
METHYL METHACRYLATE
80-62-6
Ingestion may cause irritation to mucous membranes.
= 7900 mg/kg ( Rat ) = 7872 mg/kg
( Rat )
> 5 g/kg ( Rabbit ) = 4632 ppm ( Rat ) 4 h
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
METHYL METHACRYLATE
80-62-6
IARC (International Agency for Research on Cancer)
Not classifiable as a human carcinogen
Target Organ Effects
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
- Group 3 - -
Eyes, Respiratory system, Skin.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
ATEmix (inhalation-vapor)
7872 mg/kg
5005 mg/kg
4632 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
20 % of the mixture consists of component(s) of unknown hazards to the aquatic environment
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Chemical Name Partition coefficient
METHYL METHACRYLATE
80-62-6
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Contaminated packaging
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Do not reuse container.
0.7
US EPA Waste Number
D001
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Revision Date 27-Sep-2018
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This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
METHYL METHACRYLATE
80-62-6
Toxic
Ignitable
14. TRANSPORT INFORMATION
DOT
UN/ID No
Proper shipping name:
Hazard Class
Packing Group
Emergency Response Guide
Number
IATA
UN/ID No
Proper shipping name:
Hazard Class
ERG Code
1133
Adhesives, Limited Quantity (LQ)
3
II
128
ID 8000
Consumer commodity
9
9L
IMDG
UN/ID No
Proper shipping name:
Hazard Class
Packing Group
EmS-No
1133
Adhesives, Limited Quantity (LQ)
3
II
F-E, S-D
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
Complies
Complies
Complies
Complies
Complies
Complies
Complies
Complies
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
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22045V - DEVCON HOME PLASTIC WELDER
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METHYL METHACRYLATE - 80-62-6 1.0
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Yes
No
Yes
No
No
Chemical Name CWA - Reportable
Quantities
METHYL METHACRYLATE
80-62-6
1000 lb - - X
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
METHYL METHACRYLATE
80-62-6
1000 lb - RQ 1000 lb final RQ
RQ 454 kg final RQ
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
METHYL METHACRYLATE
80-62-6
X X X
U.S. EPA Label Information
EPA Pesticide Registration Number
Not applicable
WHMIS Hazard Class
B2 - Flammable liquid, D2B - Toxic materials
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health hazards 2 Flammability 3 Instability 0
HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B
-
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
27-Sep-2018
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
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SAFETY DATA SHEET
Revision Date 27-Sep-2018 Version 8
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
6875 Parkland Blvd.
Solon, OH 44139 USA
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
DEVCON HOME PLASTIC WELDER (ADHESIVE)
22045
Adhesive
No information available
May Also Be Distributed by:
ITW Permatex Canada
101-2360 Bristol Circle
Oakville, ON Canada L6H 6M5
Telephone: (800) 924-6994
E-mail address: mail@permatex.com
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Skin sensitization Category 1
Carcinogenicity Category 2
Specific target organ toxicity (single exposure) Category 3
Flammable liquids
Label elements
Emergency Overview
Signal word
Danger
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
Suspected of causing cancer
May cause respiratory irritation
Highly flammable liquid and vapor
_____________________________________________________________________________________________
Category 2
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22045 - DEVCON HOME PLASTIC WELDER
Revision Date 27-Sep-2018
(ADHESIVE)
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Appearance Off-white Physical state Viscous liquid
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Wash face, hands and any exposed skin thoroughly after handling
Contaminated work clothing should not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Use non-sparking tools
Take precautionary measures against static discharge
Precautionary Statements - Response
Immediately call a POISON CENTER or doctor/physician
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
If skin irritation or rash occurs: Get medical advice/attention
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
In case of fire: Use CO2, dry chemical, or foam to extinguish.
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep cool
Odor Methyl methacrylate
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
- Not applicable
Unknown acute toxicity 16 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance(s)
Chemical Name CAS No Weight-%
METHYL METHACRYLATE 80-62-6 30 - 60
METHACRYLIC ACID 79-41-4 5 - 10
DIMETHYLBENZYL
HYDROPEROXIDE
_____________________________________________________________________________________________
80-15-9 1 - 5
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CUMENE 98-82-8 0.1 - 1
4. FIRST AID MEASURES
Description of first aid measures
General advice
Eye contact
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Get medical advice/attention if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Take off
contaminated clothing and wash before reuse.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.
May cause allergic skin reaction.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None
Specific hazards arising from the chemical
Highly flammable. Vapors may travel to source of ignition and flash back.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
_____________________________________________________________________________________________
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or
clothing. Wash thoroughly after handling.
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(ADHESIVE)
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Environmental precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevent further leakage or spillage if safe to do so.
Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with
inert absorbent material. Sweep up and shovel into suitable containers for disposal.
Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Storage Conditions
Incompatible materials
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Take precautionary measures against static discharges. Keep away from heat, sparks,
flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity).
Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric
motors and static electricity). Store locked up.
Strong oxidizing agents, Reducing agents
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
METHYL METHACRYLATE
80-62-6
METHACRYLIC ACID
79-41-4
CUMENE
98-82-8
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information
Appropriate engineering controls
Engineering Controls
.
STEL: 100 ppm
TWA: 50 ppm
TWA: 20 ppm (vacated) TWA: 20 ppm
TWA: 50 ppm TWA: 50 ppm
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Showers
Eyewash stations
Ventilation systems
TWA: 100 ppm
TWA: 410 mg/m
(vacated) TWA: 100 ppm
(vacated) TWA: 410 mg/m
(vacated) TWA: 70 mg/m
(vacated) S*
TWA: 245 mg/m
(vacated) TWA: 50 ppm
(vacated) TWA: 245 mg/m
(vacated) S*
S*
3
3
IDLH: 1000 ppm
TWA: 100 ppm
3
3
3
TWA: 410 mg/m
TWA: 20 ppm
TWA: 70 mg/m
IDLH: 900 ppm
TWA: 50 ppm
TWA: 245 mg/m
3
3
3
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
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Skin and body protection
Respiratory protection
General Hygiene Considerations
Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Property Values Remarks • Method
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Viscous liquid
Off-white
Methyl methacrylate
0.75 ppm
No information available
No information available
101 °C / 214 °F
12 °C / 54 °F
> 1 Butyl acetate = 1
No information available
12.5%
1.6%
28 mmHg @ 68°F
>3 Air = 1
0.95
Slightly soluble
No information available
No information available
421°C (789.8°F)
No information available
No information available
No information available
No information available
No information available
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
No information available
No information available
<50 g/l
No information available
No information available
10. STABILITY AND REACTIVITY
Reactivity
Stable under normal conditions
Chemical stability
Stable under recommended storage conditions
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
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Heat, flames and sparks.
Incompatible materials
Strong oxidizing agents, Reducing agents
Hazardous Decomposition Products
Carbon oxides
Nitrogen oxides (NOx)
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
METHYL METHACRYLATE
80-62-6
METHACRYLIC ACID
79-41-4
DIMETHYLBENZYL
HYDROPEROXIDE
80-15-9
CUMENE
98-82-8
May cause irritation of respiratory tract.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis. May cause sensitization by skin contact.
Ingestion may cause irritation to mucous membranes.
= 7900 mg/kg ( Rat ) = 7872 mg/kg
( Rat )
= 1060 mg/kg ( Rat ) 500 - 1000 mg/kg ( Rabbit ) = 500
= 382 mg/kg ( Rat ) = 0.126 mL/kg ( Rabbit ) = 220 ppm ( Rat ) 4 h
= 1400 mg/kg ( Rat ) = 12300 µL/kg ( Rabbit ) > 3577 ppm ( Rat ) 6 h = 39000
> 5 g/kg ( Rabbit ) = 4632 ppm ( Rat ) 4 h
= 7.1 mg/L ( Rat ) 4 h
mg/kg ( Rabbit )
mg/m3 ( Rat ) 4 h
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
METHYL METHACRYLATE
80-62-6
CUMENE
98-82-8
IARC (International Agency for Research on Cancer)
Not classifiable as a human carcinogen
Group 2B - Possibly Carcinogenic to Humans
NTP (National Toxicology Program)
Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Target Organ Effects
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
- Group 3 - -
- Group 2B Reasonably Anticipated X
Eyes, Respiratory system, Skin.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
ATEmix (inhalation-dust/mist)
ATEmix (inhalation-vapor)
3826 mg/kg
3352 mg/kg
18.7 mg/l
6708 mg/l
12. ECOLOGICAL INFORMATION
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Ecotoxicity
31.5 % of the mixture consists of component(s) of unknown hazards to the aquatic environment
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Chemical Name Partition coefficient
METHYL METHACRYLATE
80-62-6
METHACRYLIC ACID
79-41-4
CUMENE
98-82-8
0.7
0.93
3.7
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging
US EPA Waste Number
Do not reuse container.
D001
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
METHYL METHACRYLATE
80-62-6
DIMETHYLBENZYL HYDROPEROXIDE
80-15-9
CUMENE
98-82-8
Toxic
Ignitable
Toxic
Ignitable
Toxic
Ignitable
14. TRANSPORT INFORMATION
DOT
UN/ID No
Proper shipping name:
Hazard Class
Packing Group
Emergency Response Guide
Number
1133
Adhesives, Limited Quantity (LQ)
3
II
128
IATA
UN/ID No
Proper shipping name:
Hazard Class
ID 8000
Consumer commodity
9
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ERG Code
9L
IMDG
UN/ID No
Proper shipping name:
Hazard Class
Packing Group
EmS-No
1133
Adhesives, Limited Quantity (LQ)
3
II
F-E, S-D
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
Complies
Complies
Complies
Not determined
Complies
Complies
Complies
Complies
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
METHYL METHACRYLATE - 80-62-6 1.0
DIMETHYLBENZYL HYDROPEROXIDE - 80-15-9 1.0
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
Yes
No
Yes
No
No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Chemical Name CWA - Reportable
Quantities
METHYL METHACRYLATE
80-62-6
1000 lb - - X
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
METHYL METHACRYLATE
80-62-6
1000 lb - RQ 1000 lb final RQ
RQ 454 kg final RQ
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DIMETHYLBENZYL
HYDROPEROXIDE
80-15-9
CUMENE
98-82-8
10 lb - RQ 10 lb final RQ
5000 lb - RQ 5000 lb final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name
CUMENE - 98-82-8
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
METHYL METHACRYLATE
80-62-6
BUTYLATED HYDROXY
TOLUENE
128-37-0
METHACRYLIC ACID
79-41-4
DIMETHYLBENZYL
HYDROPEROXIDE
80-15-9
CUMENE
98-82-8
U.S. EPA Label Information
EPA Pesticide Registration Number
Not applicable
X X X
X X X
X X X
X X X
X X X
RQ 4.54 kg final RQ
RQ 2270 kg final RQ
California Proposition 65
Carcinogen
WHMIS Hazard Class
B2 - Flammable liquid, D2B - Toxic materials
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health hazards 2 Flammability 3 Instability 0
HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
27-Sep-2018
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
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