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SAFETY DATA SHEET
Revision Date 15-May-2015
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
10 Columbus Blvd.
Hartford, CT 06106 USA
Company Phone Number
24 Hour Emergency Phone Number
WELD IT ALL PURPOSE ADHESIVE
18245
None
Adhesive
No information available
Distributor
ITW Permatex Canada
35 Brownridge Road, Unit 1
Halton Hills, ON Canada L7G 0C6
Telephone: (800) 924-6994
1-87-Permatex
(877) 376-2839
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
Version 1
E-mail address
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation Category 2
Reproductive toxicity Category 1B
Specific target organ toxicity (single exposure) Category 3
Flammable liquids
Label elements
Emergency Overview
Danger
Causes serious eye irritation
May damage fertility or the unborn child
May cause drowsiness or dizziness
Highly flammable liquid and vapor
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Category 2
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Physical state Liquid Odor KetoneAppearance Clear
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. — No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
In case of fire: Use CO2, dry chemical, or foam for extinction
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
Harmful to aquatic life with long lasting effects.
Unknown acute toxicity 33% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
substance(s)
Chemical Name CAS No Weight-% Trade Secret
ACETONE 67-64-1 30 - 60 *
METHYL ETHYL KETONE (BUTANONE) 78-93-3 10 - 30 *
DIBUTYL PHTHALATE 84-74-2 1 - 5 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
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Description of first aid measures
General advice
Eye contact
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Get medical advice/attention if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician.
Wash contaminated clothing before reuse.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
See section 2 for more information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None.
Specific hazards arising from the chemical
Highly flammable.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Methods and material for containment and cleaning up
Ensure adequate ventilation, especially in confined areas. Use personal protective
equipment as required. Avoid contact with skin, eyes and inhalation of vapors. Wash
thoroughly after handling. Remove all sources of ignition.
See Section 12 for additional ecological information. Do not flush into surface water or
sanitary sewer system.
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Methods for containment
Methods for cleaning up
Prevent further leakage or spillage if safe to do so.
Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with
inert absorbent material. Sweep up and shovel into suitable containers for disposal.
Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Take precautionary measures against static discharges. Keep away from heat/sparks/open
flames/hot surfaces. — No smoking.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric
motors and static electricity).
Incompatible materials
Strong oxidizing agents, Bases, Acids, Amines
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
ACETONE
67-64-1
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
DIBUTYL PHTHALATE
84-74-2
.
STEL: 750 ppm
TWA: 500 ppm
STEL: 300 ppm
TWA: 200 ppm
TWA: 5 mg/m
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate engineering controls
Engineering Controls
Showers
Eyewash stations
Ventilation systems
TWA: 1000 ppm
TWA: 2400 mg/m
(vacated) TWA: 750 ppm
(vacated) TWA: 1800 mg/m
(vacated) STEL: 2400 mg/m3 The
acetone STEL does not apply to the
cellulose acetate fiber industry. It is
in effect for all other sectors
(vacated) STEL: 1000 ppm
TWA: 200 ppm
TWA: 590 mg/m
(vacated) TWA: 200 ppm
(vacated) TWA: 590 mg/m
(vacated) STEL: 300 ppm
3
(vacated) STEL: 885 mg/m
TWA: 5 mg/m
(vacated) TWA: 5 mg/m
3
3
3
3
3
3
3
IDLH: 2500 ppm
TWA: 250 ppm
TWA: 590 mg/m
IDLH: 3000 ppm
TWA: 200 ppm
TWA: 590 mg/m
STEL: 300 ppm
STEL: 885 mg/m
IDLH: 4000 mg/m
TWA: 5 mg/m
3
3
3
3
3
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Wear safety glasses with side shields (or goggles).
Wear protective gloves and protective clothing.
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Respiratory protection
General Hygiene Considerations
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Property
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Liquid
Clear
Ketone
No information available
Values
No information available
No information available
55 °C / 131 °F
-20 °C / -4 °F
< 1
No information available
No information available
No information available
No information available
>1
0.88
Slightly soluble
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
Remarks • Method
Tag Closed Cup
Ether = 1
Air = 1
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
No information available
No information available
1.611 lb/gal
No information available
No information available
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Keep away from all heat sources, open flames and other sources of ignition.
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Incompatible materials
Strong oxidizing agents, Bases, Acids, Amines
Hazardous Decomposition Products
Carbon oxides
Nitrogen oxides (NOx)
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
ACETONE
67-64-1
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
DIBUTYL PHTHALATE
84-74-2
Harmful by inhalation. May cause drowsiness or dizziness.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis.
Ingestion may cause irritation to mucous membranes.
= 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h
= 2483 mg/kg ( Rat ) = 2737 mg/kg
( Rat )
= 6300 mg/kg ( Rat ) > 20 mL/kg ( Rabbit ) > 15.68 mg/L ( Rat ) 4 h
= 5000 mg/kg ( Rabbit ) = 6480
mg/kg ( Rabbit )
= 11700 ppm ( Rat ) 4 h
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
Target Organ Effects
No information available.
No information available.
No information available.
Central nervous system, Eyes, Gastrointestinal tract (GI), Respiratory system, Skin.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
ATEmix (inhalation-dust/mist)
ATEmix (inhalation-vapor)
4154 mg/kg
16359 mg/kg
116.2 mg/l
39195 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
33% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
ACETONE
67-64-1
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
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- 4.74 - 6.33: 96 h Oncorhynchus
mykiss mL/L LC50 6210 - 8120: 96
h Pimephales promelas mg/L LC50
static 8300: 96 h Lepomis
macrochirus mg/L LC50
- 3130 - 3320: 96 h Pimephales
promelas mg/L LC50 flow-through
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10294 - 17704: 48 h Daphnia
magna mg/L EC50 Static 12600 -
12700: 48 h Daphnia magna mg/L
EC50
520: 48 h Daphnia magna mg/L
EC50 5091: 48 h Daphnia magna
mg/L EC50 4025 - 6440: 48 h
Daphnia magna mg/L EC50 Static
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DIBUTYL PHTHALATE
84-74-2
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Chemical Name Partition coefficient
ACETONE
67-64-1
METHYL ETHYL KETONE (BUTANONE)
78-93-3
DIBUTYL PHTHALATE
84-74-2
1.2: 72 h Desmodesmus
subspicatus mg/L EC50 0.4: 96 h
Pseudokirchneriella subcapitata
mg/L EC50 static
0.71 - 1.2: 96 h Pimephales
promelas mg/L LC50 flow-through
0.31 - 5.45: 96 h Pimephales
promelas mg/L LC50 static 1.24: 96
h Oncorhynchus mykiss mg/L LC50
flow-through 1.24 - 5.3: 96 h
Oncorhynchus mykiss mg/L LC50
static 1.38 - 1.74: 96 h Lepomis
macrochirus mg/L LC50
flow-through 0.42 - 1.28: 96 h
Lepomis macrochirus mg/L LC50
static
3.4: 48 h Daphnia magna mg/L
EC50 2.99: 48 h Daphnia magna
mg/L EC50 Static
-0.24
0.29
5.38
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Contaminated packaging
US EPA Waste Number
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
ACETONE
67-64-1
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
DIBUTYL PHTHALATE
84-74-2
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
ACETONE
67-64-1
METHYL ETHYL KETONE (BUTANONE)
78-93-3
This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261).
Do not reuse container.
D001
- Included in waste stream:
F039
U159 Included in waste streams:
F005, F039
- Included in waste stream:
F039
200.0 mg/L regulatory level U159
- U002
- U069
Ignitable
Toxic
Ignitable
14. TRANSPORT INFORMATION
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DOT
UN/ID no
Proper shipping name:
Hazard Class
Packing Group
Emergency Response Guide
1133
Adhesives, Limited Quantity (LQ)
3
II
128
Number
IATA
UN/ID no
Proper shipping name:
Hazard Class
ERG Code
ID 8000
Consumer commodity
9
9L
IMDG
UN/ID no
Proper shipping name:
Hazard Class
Packing Group
EmS-No
1133
Adhesives, Limited Quantity (LQ)
3
II
F-E, S-D
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Complies
Complies
Complies
Complies
Complies
Complies
Complies
Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
DIBUTYL PHTHALATE - 84-74-2 1.0
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Yes
Yes
Yes
No
No
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Chemical Name CWA - Reportable
DIBUTYL PHTHALATE
84-74-2
Quantities
10 lb X X X
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
ACETONE
67-64-1
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
DIBUTYL PHTHALATE
84-74-2
5000 lb - RQ 5000 lb final RQ
RQ 2270 kg final RQ
5000 lb - RQ 5000 lb final RQ
RQ 2270 kg final RQ
10 lb - RQ 10 lb final RQ
RQ 4.54 kg final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
DIBUTYL PHTHALATE - 84-74-2 Developmental
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
ACETONE
67-64-1
METHYL ETHYL KETONE
(BUTANONE)
78-93-3
DIBUTYL PHTHALATE
84-74-2
U.S. EPA Label Information
EPA Pesticide Registration Number
X X X
X X X
X X X
Not applicable
Female Reproductive
Male Reproductive
NFPA
HMIS
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
Health hazards 2 Flammability 3
Health hazards 2 Flammability 3
15-May-2015
Instability 0
Physical hazards 0 Personal protection B
-
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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