Dawn 4853, 4852, 4854 User Manual

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SAFETY DATA SHEET
Issuing Date: 09-Jan-2015
Product Name
Product Code(s) Product ID: Product Type: Recommended Use Restrictions on Use Manufacturer
Revision Date: 07-Apr-2015
1. IDENTIFICATION
Dawn ProfessionalÒ Heavy Duty Degreaser 6-10 15154367_PROF_NG Finished Product - Professional Use Only Degreaser Use only as directed on label. Procter & Gamble Professional
2 P&G Plaza Cincinnati, Ohio 45202
Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5
1-800-332-7787
Version 2
E-mail Address Emergency Telephone
pgsds.im@pg.com Transportation (24 HR)
CHEMTREC - 1-800-424-9300 (U.S./ Canada) or 1-703-527-3887 Mexico toll free in country: 800-681-9531
2. HAZARD IDENTIFICATION
This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Hazard Category
Eye Damage / Irritation Signal Word
Hazard Statements Hazard pictograms
Category 2A WARNING
Causes serious eye irritation
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Precautionary Statements ­Prevention
Precautionary Statements ­Response
Precautionary Statements ­Storage
Precautionary Statements ­Disposal
Hazards not otherwise classified (HNOC)
None
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF SWALLOWED: Drink 1 or 2 glasses of water
None
Dispose of contents/container in accordance with local regulation
None
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation Hazardous ingredients
Chemical Name Synonyms Trade Secret CAS-No Weight %
2-(2-Butoxyethoxy ethanol) Diethylene
glycol monobutyl ether
Benzenesulfonic acid,
(1-methylethyl)-, sodium salt (1:1)
Tetrasodium
ethylenediaminetetraacetate
Sodium carbonate - No 497-19-8 1 - 5
Benzenesulfonic acid,
mono-C10-16-alkyl derivs., sodium
salts
None.
- No 112-34-5 5 - 10
- No 28348-53-0 5 - 10
- No 64-02-8 1 - 5
- No 68081-81-2 1 - 5
4. FIRST AID MEASURES
First aid measures for different exposure routes Eye contact Skin contact Ingestion
Inhalation Most important symptoms/effects,
acute and delayed
Rinse with plenty of water. Get medical attention immediately if irritation persists. Rinse with plenty of water. Get medical attention if irritation develops and persists. Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if
symptoms occur. Move to fresh air. If symptoms persist, call a physician. None under normal use conditions.
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Indication of immediate medical attention and special treatment needed, if necessary
Revision Date: 07-Apr-2015
Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Unsuitable Extinguishing Media Special hazard Special protective equipment for
fire-fighters Specific hazards arising from the
chemical
Personal precautions, protective equipment and emergency procedures Personal precautions Advice for emergency responders
Dry chemical, CO 2, alcohol-resistant foam or water spray. None. None known. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear. None.
6. ACCIDENTAL RELEASE MEASURES
Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Use personal protective equipment as required.
Methods and materials for containment and cleaning up Methods for containment
Methods for cleaning up
Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).
7. HANDLING AND STORAGE
Precautions for safe handling Advice on safe handling
Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible products
Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children.
Keep containers tightly closed in a dry, cool and well-ventilated place. None known.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure Guidelines
.
Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL
2-(2-Butoxyethoxy ethanol)
Diethylene glycol monobutyl ether
112-34-5 TWA: 10 ppm inhalable
fraction and vapor
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No relevant exposure guidelines for other ingredients
Exposure controls Engineering Measures Distribution, Workplace and Household Settings:
Ensure adequate ventilation
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction
Personal Protective Equipment Eye Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Use appropriate eye protection
Hand Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Protective gloves
Revision Date: 07-Apr-2015
Skin and Body Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Wear suitable protective clothing
Respiratory Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
In case of insufficient ventilation wear suitable respiratory equipment
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State @20°C Appearance Odor Odor threshold
Property
pH value Melting/freezing point Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limits in Air
Upper flammability limit
Lower Flammability Limit Vapor pressure Vapor density Relative density Water solubility Solubility in other solvents
liquid purple Scented No information available
Values
10.4 No information available No information available > 93.3 °C / > 200 °F No information available No information available
No information available No information available No information available No information available
1.12 100% No information available
Note
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Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature Viscosity of Product
VOC Content (%)
No information available No information available No information available . No information available
Products comply with US state and federal regulations for VOC content in consumer products.
Reactivity Stability Hazardous polymerization Hazardous Reactions Conditions to Avoid Materials to avoid Hazardous Decomposition Products
None under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. None under normal processing. None under normal processing. None in particular. None under normal use.
11. TOXICOLOGICAL INFORMATION
Product Information Information on likely routes of exposure
.
10. STABILITY AND REACTIVITY
Inhalation Skin contact Ingestion Eye contact
No known effect. No known effect. No known effect. Causes serious eye irritation.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity
Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Respiratory sensitization Germ cell mutagenicity Neurological Effects Reproductive toxicity Developmental toxicity Teratogenicity STOT - single exposure STOT - repeated exposure Target Organ Effects Aspiration hazard Carcinogenicity
No known effect. No known effect. Causes serious eye irritation. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect.
Component Information
Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation
2-(2-Butoxyethoxy ethanol)
Diethylene glycol monobutyl ether
Benzenesulfonic acid,
(1-methylethyl)-, sodium salt (1:1)
Tetrasodium
ethylenediaminetetraacetate
Sodium carbonate 497-19-8 2800 mg/kg bw (Guideline
112-34-5 2410 mg/kg (rat) - -
28348-53-0 5160.00 mg/kg (rat) - -
64-02-8 > 1780 mg/kg bw - -
not indicated; rat)
> 2000 mg/kg bw (EPA 16
CFR 1500.40; rabbit)
-
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Benzenesulfonic acid,
mono-C10-16-alkyl derivs., sodium
salts
68081-81-2 1090.00 mg/kg (rat) - -
12. ECOLOGICAL INFORMATION
Ecotoxicity
The product is not expected to be hazardous to the environment.
Persistence and degradability Bioaccumulative potential Mobility Other adverse effects
No information available. No information available. No information available. No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment Waste from Residues / Unused
Products Contaminated packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Codes (non-household setting)
331
14. TRANSPORT INFORMATION
DOT IMDG IATA
Not regulated Not regulated Not regulated
15. REGULATORY INFORMATION
U.S. Federal Regulations SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
Chemical Name CAS-No SARA 313 - Threshold Values %
2-(2-Butoxyethoxy ethanol) Diethylene glycol
monobutyl ether
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
112-34-5 1.0
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following substance(s) which are either listed as hazardous air pollutants (HAPS) or VOC's per the Clean Air Act:
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Chemical Name CAS-No CAA (Clean Air Act) - 1990
2-(2-Butoxyethoxy ethanol) Diethylene glycol
monobutyl ether
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
California Proposition 65
This product is not subject to warning labeling under California Proposition 65.
U.S. State Regulations (RTK)
Chemical Name CAS-No New Jersey
2-(2-Butoxyethoxy ethanol) Diethylene glycol
monobutyl ether
Chemical Name CAS-No Pennsylvania
2-(2-Butoxyethoxy ethanol) Diethylene glycol
monobutyl ether
2-Aminoethanol 141-43-5 X
112-34-5 X
112-34-5 X
112-34-5 X
Revision Date: 07-Apr-2015
Hazardous Air Pollutants
International Inventories
United States
All intentionally-added components of this product(s) are listed on the US TSCA Inventory.
Canada
This product is in compliance with CEPA for import by P&G.
Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act
16. OTHER INFORMATION
HMIS Ratings Health hazard Flammability Physical hazard
NFPA Ratings Health hazard Flammability Instability
Issuing Date: Revision Date: Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text
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End of SDS
Revision Date: 07-Apr-2015
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