SAFTEY DATA SHEET – REDDY INSULATION FOAM SEALANT.
Common Name:
REDDY INSULATION FOAM SEALANT
Manufacturer:
DAP FOAM
SDS Revision Date:
3/14/2016
SDS Format:
GHS-US
Item Number(s):
Manufacturer Model
Number(s):
DAP PRODUCTS INC
SAFETY DATA SHEET
ACC. TO OSHA HCS (29 CFR 1910.1200) AND WHMIS 2015 REGULATIONS
PRINTING DATE: 03/14/2016
REVISION: 03/14/2016
1 IDENTIFICATION
PRODUCT IDENTIFIER:
TRADE NAME: REDDY INSULATION FOAM SEALANT
PRODUCT CODE: EHS 9885
RECOMMENDED USE AND RESTRICTION ON USE:
RECOMMENDED USE: SEALANT
RESTRICTIONS ON USE: SEE SECTIONS 8 AND 10 FOR FURTHER INFORMATION.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CONVENIENCE PRODUCTS, FOAM PRODUCTS DIVISION
866 HORAN DRIVE
FENTON, MO 63026-2614
PHONE: 636-349-5855
TOLL-FREE: 1-800-325-6180
EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
+1 (800)255-3924
+1 (813)248-0585
2 HAZARD(S) IDENTIFICATION
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. AEROSOL 1:
H222: EXTREMELY FLAMMABLE AEROSOL.
PRESS. GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
ACUTE TOX. 4:
H332: HARMFUL IF INHALED.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
RESP. SENS. 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
SKIN SENS. 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
MUTA. 1B:
H340: MAY CAUSE GENETIC DEFECTS.
REPR. 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT SE 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
STOT RE 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELING:
DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
DIMETHYL METHYLPHOSPHONATE
4,4'-METHYLENEDIPHENYL DIISOCYANATE
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H332: HARMFUL IF INHALED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H340: MAY CAUSE GENETIC DEFECTS.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P260: DO NOT BREATHE MIST/VAPORS/SPRAY.
P284: [IN CASE OF INADEQUATE VENTILATION] WEAR RESPIRATORY PROTECTION.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272:
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/DOCTOR.
P304+P341:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
P312: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P405: STORE LOCKED UP.
P410+P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
P403+P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
0 % OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN TOXICITY.
3 COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL CHARACTERIZATION: MIXTURES
COMPONENTS:
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES 25-40%
RESP. SENS. 1, H334; STOT RE 2, H373 ACUTE TOX. 4,
H332; SKIN IRRIT. 2, H315; EYE IRRIT. 2, H319;
SKIN SENS. 1, H317; STOT SE 3, H335
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE 10-20%
RESP. SENS. 1, H334; STOT RE 2, H373 ACUTE TOX. 4,
H332; SKIN IRRIT. 2, H315; EYE IRRIT. 2, H319;
SKIN SENS. 1, H317; STOT SE 3, H335
13674-84-5 TRIS(2-CHLORISOPROPYL)-PHOSPHATE 10-20%
ACUTE TOX. 4, H302
115-10-6 DIMETHYL ETHER 5-<10%
FLAM. GAS 1, H220
PRESS. GAS, H280
75-28-5 ISOBUTANE 2.5-5%
FLAM. GAS 1, H220
PRESS. GAS, H280
74-98-6 PROPANE 2.5-5%
FLAM. GAS 1, H220
PRESS. GAS, H280
756-79-6 DIMETHYL METHYLPHOSPHONATE 0.1-1%
MUTA. 1B, H340; REPR. 2, H361
EYE IRRIT. 2A, H319
FLAM. LIQ. 4, H227
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD STATEMENTS REFER TO SECTION 16.
FOR THE LISTED INGREDIENT(S), THE IDENTITY AND/OR EXACT PERCENTAGE(S) ARE
BEING WITHHELD AS A TRADE SECRET.
4 FIRST-AID MEASURES
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE
MEDICAL OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
DO NOT PULL SOLIDIFIED PRODUCT AWAY FROM THE SKIN.
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
IMMEDIATELY REMOVE CONTACT LENSES IF POSSIBLE.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. THEN CONSULT
A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASTHMA ATTACKS
HEADACHE
BREATHING DIFFICULTY
ALLERGIC REACTIONS
COUGHING
NAUSEA
GASTRIC OR INTESTINAL DISORDERS WHEN INGESTED.
IRRITANT TO SKIN AND MUCOUS MEMBRANES.
IRRITANT TO EYES.
DIZZINESS
DISORIENTATION
DANGER:
DANGER OF IMPAIRED BREATHING.
DANGER OF DISTURBED CARDIAC RHYTHM.
DANGER OF PULMONARY EDEMA.
DANGER OF PNEUMONIA.
DANGER OF CONVULSION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
SEVERE ALLERGIC SKIN REACTION, BRONCHIAL SPASMS AND ANAPHYLACTIC SHOCK ARE
POSSIBLE.
TREAT SKIN AND MUCOUS MEMBRANE WITH ANTIHISTAMINE AND CORTICOID
PREPARATIONS.
IN CASES OF IRRITATION TO THE LUNGS, INITIAL TREATMENT WITH CORTICAL
STEROID INHALANTS.
MONITOR CIRCULATION.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
CONTAINS ISOCYANATES. MAY PRODUCE AN ALLERGIC REACTION.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER
SPRAY OR ALCOHOL RESISTANT FOAM.
WATER IN FLOODING QUANTITIES.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: NONE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
DURING HEATING OR IN CASE OF FIRE POISONOUS GASES ARE PRODUCED.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO.
LEAKING GAS FIRE: DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY.
COOL ENDANGERED RECEPTACLES WITH WATER SPRAY.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF FUMES/DUST/
AEROSOL.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION.
KEEP AWAY FROM IGNITION SOURCES.
PROTECT FROM HEAT.
ISOLATE AREA AND PREVENT ACCESS.
KEEP PEOPLE AT A DISTANCE AND STAY UPWIND.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO SOLIDIFY. PICK UP MECHANICALLY.
SEND FOR RECOVERY OR DISPOSAL IN SUITABLE RECEPTACLES.
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
7 HANDLING AND STORAGE
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
USE ONLY IN WELL VENTILATED AREAS.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PROTECT AGAINST ELECTROSTATIC CHARGES.
KEEP RESPIRATORY PROTECTIVE DEVICE AVAILABLE.
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
120 DEG. F / 49 DEG. C, I.E. ELECTRIC LIGHTS. DO NOT PIERCE OR BURN,
EVEN AFTER USE.
DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
EMERGENCY COOLING MUST BE AVAILABLE IN CASE OF NEARBY FIRE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED
CONTAINERS.
PROVIDE VENTILATION FOR RECEPTACLES.
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM OXIDIZING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
STORE IN A COOL PLACE. HEAT WILL INCREASE PRESSURE AND MAY LEAD TO THE
RECEPTACLE BURSTING.
SPECIFIC END USE(S): NO RELEVANT INFORMATION AVAILABLE.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
PEL (USA):
CEILING LIMIT VALUE: 0.2 MG/M3, 0.02 PPM
REL (USA):
LONG-TERM VALUE: 0.05 MG/M3, 0.005 PPM
CEILING LIMIT VALUE: 0.2* MG/M3, 0.02* PPM
*10-MIN
TLV (USA):
LONG-TERM VALUE: 0.051 MG/M3, 0.005 PPM
EL (CANADA):
LONG-TERM VALUE: 0.005 PPM
CEILING LIMIT VALUE: 0.01 PPM
SKIN; S
EV (CANADA):
LONG-TERM VALUE: 0.005 PPM
CEILING LIMIT VALUE: 0.02 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 0.005 PPM
115-10-6 DIMETHYL ETHER:
WEEL (USA):
LONG-TERM VALUE: 1000 PPM
EL (CANADA):
LONG-TERM VALUE: 1000 PPM
75-28-5 ISOBUTANE:
TLV (USA):
SHORT-TERM VALUE: 2370 MG/M3, 1000 PPM
EV (CANADA):
LONG-TERM VALUE: 800 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 1000 PPM
74-98-6 PROPANE:
PEL (USA):
LONG-TERM VALUE: 1800 MG/M3, 1000 PPM
REL (USA):
LONG-TERM VALUE: 1800 MG/M3, 1000 PPM
TLV (USA): REFER TO APPENDIX F INTLVS AND BEIS BOOK
EL (CANADA):
LONG-TERM VALUE: 1000 PPM
EV (CANADA):
LONG-TERM VALUE: 1000 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 1000 PPM
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES FOR HANDLING CHEMICALS SHOULD BE
FOLLOWED.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE EYES AND SKIN.
CLEAN SKIN THOROUGHLY IMMEDIATELY AFTER HANDLING THE PRODUCT.
ENGINEERING CONTROLS: NO RELEVANT INFORMATION AVAILABLE.
BREATHING EQUIPMENT:
COMBINED ORGANIC VAPOR AND PARTICULATE RESPIRATOR IS RECOMMENDED FOR USE
DURING ALL PROCESSING ACTIVITIES.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE
SUBSTANCE/ THE PREPARATION.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
AVOID RELEASE TO THE ENVIRONMENT.
RISK MANAGEMENT MEASURES: SEE SECTION 7 FOR ADDITIONAL INFORMATION.
9 PHYSICAL AND CHEMICAL PROPERTIES
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: AEROSOL
COLOR: AMBER COLORED
ODOR: LIGHT
PETROLEUM-LIKE
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: -42 DEG. C (-44 DEG. F) (PROPELLANT)
FLASH POINT: -104 DEG. C (-155 DEG. F) (PROPELLANT)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: NOT DETERMINED.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO IGNITING: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/VAPOR
MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: NOT DETERMINED.
UPPER: NOT DETERMINED.
VAPOR PRESSURE: NOT DETERMINED.
DENSITY AT 20 DEG. C (68 DEG. F): 1.01 G/CM3 (8.428 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
VOC (CALIFORNIA): 155 G/L (EPA METHOD 24)
OTHER INFORMATION: NO RELEVANT INFORMATION AVAILABLE.
10 STABILITY AND REACTIVITY
REACTIVITY: NO RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
DEVELOPS READILY FLAMMABLE GASES / FUMES.
FLAMMABLE.
REACTS WITH OXIDIZING AGENTS.
CAN FORM EXPLOSIVE MIXTURES IN AIR IF HEATED ABOVE FLASH POINT AND/OR WHEN
SPRAYED OR ATOMIZED.
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
CONTACT WITH ACIDS RELEASES TOXIC GASES.
TOXIC FUMES MAY BE RELEASED IF HEATED ABOVE THE DECOMPOSITION POINT.
CONDITIONS TO AVOID:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
STORE AWAY FROM OXIDIZING AGENTS.
INCOMPATIBLE MATERIALS: NO RELEVANT INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
NITROGEN OXIDES (NOX)
HYDROGEN CYANIDE (PRUSSIC ACID)
PHOSPHORUS OXIDES (E.G. P2O5)
11 TOXICOLOGICAL INFORMATION
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE:
ORAL:
LD50: 2200 MG/KG (MOUSE)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION:
SENSITIZATION POSSIBLE THROUGH INHALATION.
SENSITIZATION POSSIBLE THROUGH SKIN CONTACT.
SUBACUTE TO CHRONIC TOXICITY:
INHALATION OF CONCENTRATED VAPORS AS WELL AS ORAL INTAKE WILL LEAD TO
ANAESTHESIA-LIKE CONDITIONS AND HEADACHE, DIZZINESS, ETC.
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS ARE LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
VAPORS HAVE NARCOTIC EFFECT.
REPEATED DOSE TOXICITY:
REPEATED EXPOSURES MAY RESULT IN SKIN AND/OR RESPIRATORY SENSITIVITY.
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
MUTA. 1B, REPR. 2
GERM CELL MUTAGENICITY: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT-SINGLE EXPOSURE: MAY CAUSE RESPIRATORY IRRITATION.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
12 ECOLOGICAL INFORMATION
TOXICITY:
AQUATIC TOXICITY:
THE PRODUCT CONTAINS MATERIALS THAT ARE HARMFUL TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY: NO RELEVANT INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
AVOID TRANSFER INTO THE ENVIRONMENT.
HARMFUL TO AQUATIC ORGANISMS
THIS STATEMENT WAS DEDUCED FROM PRODUCTS WITH A SIMILAR STRUCTURE OR
COMPOSITION.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO RELEVANT INFORMATION AVAILABLE.
13 DISPOSAL CONSIDERATIONS
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM. CAN BE DISPOSED OF WITH HOUSEHOLD GARBAGE
AFTER SOLIDIFICATION FOLLOWING CONSULTATION WITH THE WASTE DISPOSAL
FACILITY OPERATOR AND THE PERTINENT AUTHORITIES AND ADHERING TO THE
NECESSARY TECHNICAL REGULATIONS.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
14 TRANSPORT INFORMATION
UN-NUMBER:
DOT, ADR, IMDG, IATA: UN1950
UN PROPER SHIPPING NAME:
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG (66 LB) AND INNER PACKAGINGS
LESS THAN 1 L (0.3 GAL).
DOT: AEROSOLS
ADR: 1950 AEROSOLS
IMDG: AEROSOLS
IATA: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE GAS, CLASS/DIVISION 2.1
CLASS: 2.1
LABEL: 2.1
ADR: CLASS 2.1, FLAMMABLE GASES
CLASS: 2 5F GASES
LABEL 2.1
IMDG, IATA: CLASS 2.1 - FLAMMABLE GASES
CLASS: 2.1
LABEL: 2.1
PACKING GROUP:
THIS UN-NUMBER IS NOT ASSIGNED A PACKING GROUP.
AEROSOLS ARE NOT ASSIGNED A PACKING GROUP.
DOT, ADR, IMDG, IATA: NOT REGULATED.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES
DANGER CODE (KEMLER):
EMS NUMBER: F-D,S-U
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
15 REGULATORY INFORMATION
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS ARE LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES CBD
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE D, CBD
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
9016-87-9 DIPHENYLMETHANEDIISOCYANATE,ISOMERES AND HOMOLOGUES 3
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE 3
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS ARE LISTED.
CANADA:
CANADIAN SUBSTANCE LISTINGS:
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 0.1%):
101-68-8 4,4'-METHYLENEDIPHENYL DIISOCYANATE
CANADIAN INGREDIENT DISCLOSURE LIST (LIMIT 1%):
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
16 OTHER INFORMATION
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL NOT
ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
DATE OF PREPARATION / LAST REVISION: 03/14/2016 / -
ABBREVIATIONS AND ACRONYMS:
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
FLAM. GAS 1: FLAMMABLE GASES, HAZARD CATEGORY 1
FLAM. AEROSOL 1: FLAMMABLE AEROSOLS, HAZARD CATEGORY 1
PRESS. GAS:
GASES UNDER PRESSURE: COMPRESSED GAS
FLAM. LIQ. 4: FLAMMABLE LIQUIDS, HAZARD CATEGORY 4
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2A
RESP. SENS. 1: SENSITISATION - RESPIRAT., HAZARD CATEGORY 1
SKIN SENS. 1: SENSITISATION - SKIN, HAZARD CATEGORY 1
MUTA. 1B: GERM CELL MUTAGENICITY, HAZARD CATEGORY 1B
REPR. 2: REPRODUCTIVE TOXICITY, HAZARD CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
STOT RE 2:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 2
SOURCES:
SDS PREPARED BY:
CHEMTEL INC.
1305 NORTH FLORIDA AVENUE
TAMPA, FLORIDA USA
33602-2902
TOLL FREE NORTH AMERICA: 1-888-255-3924
INTL.: +01 813-248-0573
WEBSITE: WWW.CHEMTELINC.COM
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