SDS Number: 00077364004 Revision Date: 6/19/2015
24 Hour Emergency Phone Numbers
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
Safety Data Sheet
1-800-535-5053
1-352-323-3500
NOTE: The National ResponseCenter emergency
numbers to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this SDS are further described in Section 16.
1. Identification
This Safety Data Sheet is available in American Spanish upon request.
Los Datos de Serguridad pueden obtenerse en Espanol si lo riquiere.
Product Name: Fire Stop Silicone Sealant Revision Date: 6/19/2015
Product UPC Number:
Product Use/Class: Caulking Compound
Manufacturer:
Emergency Telephone:
Safety Data Sheet Coordinator:
18806
DAP Products Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non - emergency matters)
1-800-535-5053, 1-352-323-3500, 1-800-222-1222
MSDS@DAP.com
Supercedes Date:
SDS No: 00077364004
Preparer: Regulatory Department
New SDS
2. Hazards Identification
EMERGENCY OVERVIEW: High concentration of vapors may cause irritation to eyes and respiratory system.
GHS Classification
Eye Irrit. 2, Skin Sens. 1, STOT RE 2
Symbol(s) of Product
Signal Word
Warning
GHS HAZARD STATEMENTS
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SDS Number: 00077364004 Revision Date: 6/19/2015
25-50
GHS03
2.5-10
GHS03-GHS07
GHS03-GHS07GHS08
0.1-1.0
GHS03-GHS07
GHS03-GHS05GHS06-GHS08
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Eye Irritation, category 2 H319 Causes serious eye irritation.
STOT, repeated exposure, category 2 H373 May cause damage to organs <or state all organs affected, if known> through
prolonged or repeated exposure <state route of exposure if it is conclusively
proven that no other routes of exposure cause the hazard>.
GHS LABEL PRECAUTIONARY STATEMENTS
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
GHS SDS PRECAUTIONARY STATEMENTS
P363 Wash contaminated clothing before reuse.
3. Composition/Information on Ingredients
Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements
1317-65-3
7631-86-9
Methyltri(ethylmethylketoxime)silane 22984-54-9 2.5-10
14808-60-7
Methyl ethyl ketoxime 96-29-7 0.1-1.0
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
H270-317-319-373
H270-317-318-331-351
4. First-aid Measures
FIRST AID - INHALATION: Material is not likely to present an inhalation hazard at ambient conditions. If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately.
FIRST AID - SKIN CONTACT: Wash skin with soap and water for 15 minutes. Get medical aid if symptoms persist.
FIRST AID - EYE CONTACT: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: None Known.
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam
6. Accidental Release Measures
ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material and remove with inert absorbent.
Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Scrape
up dried material and place into containers. Use personal protective equipment as necessary. In case of spillage, absorb with inert
material and dispose of in accordance with applicable regulations.
7. Handling and Storage
HANDLING: KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes,
skin and clothing. Use only with adequate ventilation. Wash thoroughly after handling. Remove contact lenses before using. Do not
handle contact lenses until all sealant has been cleaned from fingertips, nails and cuticles. Residual sealant may transfer to contact
lenses and cause severe eye irritation.
STORAGE: Avoid excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and
oxidizers.
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SDS Number: 00077364004 Revision Date: 6/19/2015
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA
OSHA PEL-CEILING
Limestone N.E. N.E. 15 mg/m3 TWA
total dust, 5 mg/m3
TWA respirable
fraction
Silica, amorphous N.E. N.E. N.E. N.E.
Methyltri(ethylmethylketoxime)silane N.E. N.E. N.E. N.E.
Quartz 0.025 mg/m3 TWA
respirable fraction
Methyl ethyl ketoxime N.E. N.E. N.E. N.E.
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established
N.E. N.E. N.E.
N.E.
Personal Protection
RESPIRATORY PROTECTION: No personal respiratory protective equipment normally required. National Institute for
Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50
micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour
work shift.
SKIN PROTECTION: Wear nitrile or neoprene gloves.
EYE PROTECTION: Goggles or safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT: Not required under normal use.
HYGIENIC PRACTICES: Wash hands before breaks and at the end of workday. Remove and wash contaminated
clothing before re-use.
9. Physical and Chemical Properties
Appearance: Gray Physical State: Paste
Odor: Plastic-Like Odor Threshold: Not Established
Density, g/cm3: 1.37 - 1.37 pH: Not Established
Freeze Point, °C: Not Established Viscosity (mPa.s): Not Established
Solubility in Water: No Information Partition Coeff., n-octanol/water: Not Established
Decomposition Temperature, °C: Not Established Explosive Limits, %: N.I. - N.I.
Boiling Range, °C: N.I. - N.I. Auto-Ignition Temperature, °C Not Established
Minimum Flash Point, °C: 93.3 Vapor Pressure, mmHg: No Information
Evaporation Rate: Slower Than n-Butyl Acetate Flash Method: Seta Closed Cup
Vapor Density: Heavier Than Air
Combustibility: Does not support combustion
(See "Other information" Section for abbreviation legend)
(If product is an aerosol, the flash point stated above is that of the propellant.)
Flammability: No Information
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SDS Number: 00077364004 Revision Date: 6/19/2015
10. Stability and Reactivity
STABILITY: This product is considered stable under normal and anticipated storage and handling conditions.
CONDITIONS TO AVOID: Oxidizing agents. Excessive heat and freezing.
INCOMPATIBILITY: Keep away from strong oxidizing agents. Incompatible with strong bases and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx.
11. Toxicological Information
EFFECT OF OVEREXPOSURE - INHALATION: During application and cure, this product releases methanol. Inhalation may cause
irritation to the respiratory tract (nose, mouth, mucous membranes). May cause allergic respiratory reaction.
EFFECT OF OVEREXPOSURE - SKIN CONTACT: Direct skin contact may cause irritation. May cause allergic skin reaction.
EFFECT OF OVEREXPOSURE - EYE CONTACT: May cause mild eye irritation.
EFFECT OF OVEREXPOSURE - INGESTION: Single dose oral toxicity is very low. Amounts ingested incidental to industrial
handling are not likely to cause injury; however, ingestion of large amounts may cause injury. Ingestion of large amounts may cause
nausea, gastrointestinal upset, and pain. May cause liver and kidney damage, and central nervous system depression. Ingestion
may result in obstruction when material hardens.
CARCINOGENICITY: No Information
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated or prolonged exposure may cause irritation of eyes and skin.
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. The International Agency for Research
on Cancer (IARC) has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is
carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres
(published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable
crystalline silica as "known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of
Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2).
Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage
may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can
cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury.
Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking
exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that
breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease
endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and
kidney disease.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Inhalation, Skin Contact
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS-No.
1317-65-3 Limestone 6450 mg/kg Rat >2000 mg/kg >20 mg/L
7631-86-9 Silica, amorphous >3300 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L
22984-54-9 Methyltri(ethylmethylketoxime)silane >2520 mg/kg Rat >2000 mg/kg Rat >50 mg/L Rat
14808-60-7 Quartz 500 mg/kg Rat >2000 mg/kg >20 mg/L
96-29-7 Methyl ethyl ketoxime 2326 mg/kg Rat 2702 mg/kg Rabbit >4.83 mg/L Rat
N.I. = No Information
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
12. Ecological Information
ECOLOGICAL INFORMATION: Ecological injuries are not known or expected under normal use.
13. Disposal Information
DISPOSAL INFORMATION: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous
Waste Management Regulation, 40 CFR Section 261. Dispose as hazardous waste according to all local, state, federal and provincial
regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper
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SDS Number: 00077364004 Revision Date: 6/19/2015
waste disposal is with the owner of the waste. Do not flush into surface water or sanitary sewer system.
14. Transport Information
SPECIAL TRANSPORT PRECAUTIONS: No Information
DOT UN/NA Number: N.A.
DOT Proper Shipping Name: Not Regulated.
DOT Technical Name: N.A.
DOT Hazard Class: N.A.
Hazard SubClass: N.A.
Packing Group: N.A.
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Acute Health Hazard, Chronic Health Hazard
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b) components exist in this product.
CALIFORNIA PROPOSITION 65 CARCINOGENS AND REPRODUCTIVE TOXINS
CALIFORNIA PROPOSITION 65:
No Information
International Regulations: As follows -
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
WHMIS Class
Consumer Commodity
16. Other Information
Revision Date:
Reason for revision: HazCom2012/GHS Conversion
Datasheet produced by: Regulatory Department
6/19/2015
HMIS Ratings:
Health: 2 Flammability: 1 Reactivity: 0 Personal Protection: X
VOC Less Water Less Exempt Solvent, g/L
VOC as Defined by California Consumer Product Regulation, Wt/Wt%:
Supersedes Date:
VOC Material, g/L:
New MSDS
25.9
26
1.0
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SDS Number: 00077364004 Revision Date: 6/19/2015
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H270 May cause or intensify fire; oxidiser.
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS03
GHS05
GHS06
GHS07
GHS08
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since thisdocument is intended
only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is
therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the
intended use and (ii) determine if they are appropriate.
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