SDS Number: 00017077001 Revision Date: 9/6/2018
24 Hour Emergency Phone Numbers
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
Safety Data Sheet
1-800-535-5053
1-352-323-3500
NOTE: The National ResponseCenter emergency
numbers to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this SDS are further described in Section 16.
1. Identification
This Safety Data Sheet is available in American Spanish upon request.
Los Datos de Serguridad pueden obtenerse en Espanol si lo riquiere.
Product Name: Alex Plus Spackling Revision Date:
Product UPC Number:
Product Use/Class: Spackling Compound
Manufacturer:
070798187443, 070798187450,
070798187467, 070798187474
DAP Products Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non - emergency matters)
SDS Coordinator: MSDS@dap.com
Emergency Telephone:
Transportation: 1-800-535 -5053
1-352-323-3500
Poison Control: 1-800-222-1222
Supercedes Date:
SDS No:
Preparer:
2. Hazards Identification
9/6/2018
8/11/2017
00017077001
Regulatory and Environmental
Affairs
Page 1 / 6
SDS Number: 00017077001 Revision Date: 9/6/2018
60-80
No Information
0.1-1.0
GHS07
GHS Classification
Carc. 1A
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
2% of the mixture consists of ingredients of unknown acute toxicity
GHS HAZARD STATEMENTS
Carcinogenicity, category 1A H350 May cause cancer.
GHS LABEL PRECAUTIONARY STATEMENTS
P201 Obtain special instructions before use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
3. Composition/Information on Ingredients
Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements
1317-65-3
14808-60-7
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
4. First-aid Measures
FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is
experienced, get medical attention immediately.
FIRST AID - SKIN CONTACT: Wash skin with soap and water for 15 minutes. Get medical aid if symptoms persist.
FIRST AID - EYE CONTACT: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: No Information
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog
6. Accidental Release Measures
ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: In case of spillage, absorb with inert material and dispose of in
accordance with applicable regulations.
7. Handling and Storage
HANDLING: KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Use only with adequate ventilation. Ensure fresh
air entry during application and drying. Do not breathe dust. Removal of this product after use will result in the generation of Dust. If
dry-sanded, exposure to dust may result in the build-up of material in eyes, ears, nose, and mouth which may cause irritation. While
dry sanding, use of a NIOSH-approved dust mask is recommended. Wash thoroughly after handling.
STORAGE: Avoid excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and
oxidizers. Keep containers tightly closed.
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SDS Number: 00017077001 Revision Date: 9/6/2018
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA
OSHA PEL-CEILING
Limestone N.E. N.E. 15 mg/m3 TWA
total dust, 5 mg/m3
TWA respirable
fraction
Quartz 0.025 mg/m3 TWA
respirable
particulate matter
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established
N.E. 50 µg/m3 TWA N.E.
N.E.
Personal Protection
RESPIRATORY PROTECTION: When concentrations exceed the exposure limits specified, use of a NIOSH-approved
dust, mist and fume respirator is recommended. Where the protection factor of the respirator may be exceeded, use of
a full facepiece, supplied air, or Self Contained Breathing Apparatus (SCBA) may be necessary. If concentrations
exceed the exposure limits specified, use of a NIOSH-approved supplied air respirator is recommended. Where the
protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. Use an
approved NIOSH/OSHA respirator if dry sanded. National Institute for Occupational Safety and Health (NIOSH) has
recommended that the permissible exposure limit be changed to 50 micrograms respirable free silica per cubic meter of
air (0.05 mg/m3) as determined by a full shift sample up to 10-hour work shift. A respiratory protection program that
meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a
respirator's use.
SKIN PROTECTION: Wear protective gloves.
EYE PROTECTION: Safety glasses with side-shields.
OTHER PROTECTIVE EQUIPMENT: Not required under normal use.
HYGIENIC PRACTICES: Remove and wash contaminated clothing before re-use.
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SDS Number: 00017077001 Revision Date: 9/6/2018
9. Physical and Chemical Properties
Appearance: White to Off-White Physical State: Paste
Odor: Very Slight Ammonia Odor Threshold: Not Established
Density, g/cm3: 1.88 - 1.88 pH: Between 7.0 and 12.0
Freeze Point, °C: Not Established Viscosity (mPa.s): Not Established
Solubility in Water: No Information Partition Coeff., n-octanol/water: Not Established
Decomposition Temperature, °C: Not Established Explosive Limits, %: N.I. - N.I.
Boiling Range, °C: N.I. - N.I. Auto-Ignition Temperature, °C Not Established
Minimum Flash Point, °C: 100 Vapor Pressure, mmHg: Not Established
Evaporation Rate: Slower Than n-Butyl Acetate Flash Method: Seta Closed Cup
Vapor Density: Heavier Than Air
Combustibility: Does not support combustion
(See "Other information" Section for abbreviation legend)
(If product is an aerosol, the flash point stated above is that of the propellant.)
Flammability: Non-Flammable
10. Stability and Reactivity
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID: Do not breathe dust. Avoid dust formation in confined areas. Excessive heat and freezing.
INCOMPATIBILITY: Incompatible with strong bases and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx.
11. Toxicological Information
EFFECT OF OVEREXPOSURE - INHALATION: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous
membranes). Prolonged, repeated, or high exposures may cause irritation to the respiratory tract (nose, mouth, mucous
membranes). Dust from dry sanding may cause eye, skin, nose, throat and respiratory tract irritation.
EFFECT OF OVEREXPOSURE - SKIN CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Prolonged or repeated contact with skin may cause mild irritation. May cause skin irritation in susceptible persons.
EFFECT OF OVEREXPOSURE - EYE CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Direct eye contact may cause irritation. May cause eye irritation.
EFFECT OF OVEREXPOSURE - INGESTION: Under normal use conditions, this product is not expected to cause adverse health
effects. Single dose oral toxicity is very low. Amounts ingested incidental to industrial handling are not likely to cause injury; however,
ingestion of large amounts may cause injury. Ingestion may result in obstruction when material hardens.
CARCINOGENICITY: No Information
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: Contains Crystalline Silica which has been determined to be carcinogenic
to humans (1) by IARC when in respirable form. Risk of cancer depends upon duration and level of inhalation exposure to dust from
sanding the dried paint or spray mist. The International Agency for Research on Cancer (IARC) has determined that crystalline silica
in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to
humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the
use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists
(ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable
crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust
may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a
respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough,
shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease.
Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable
crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as
scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease.
Prolonged or repeated inhalation of dust may cause lung damage.
PRIMARY ROUTE(S) OF ENTRY: Inhalation, Skin Absorption, Skin Contact
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SDS Number: 00017077001 Revision Date: 9/6/2018
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
1317-65-3 Limestone 6450 mg/kg Rat >2000 mg/kg >20 mg/L
14808-60-7 Quartz 500 mg/kg Rat >2000 mg/kg >20 mg/L
N.I. = No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Ecological injuries are not known or expected under normal use.
13. Disposal Information
DISPOSAL INFORMATION: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous
Waste Management Regulation, 40 CFR Section 261. Dispose as hazardous waste according to all local, state, federal and provincial
regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper
waste disposal is with the owner of the waste.
14. Transport Information
SPECIAL TRANSPORT PRECAUTIONS: No Information
DOT UN/NA Number: N.A.
DOT Proper Shipping Name: Not Regulated.
DOT Technical Name: N.A.
DOT Hazard Class: N.A.
Hazard SubClass: N.A.
Packing Group: N.A.
15. Regulatory Information
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b) components exist in this product.
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SDS Number: 00017077001 Revision Date: 9/6/2018
16. Other Information
Revision Date: 9/6/2018
Reason for revision: Substance and/or Product Properties Changed in Section(s):
11 - Toxicological Information
15 - Regulatory Information
Product Composition Changed
Datasheet produced by: Regulatory Department
Supersedes Date: 8/11/2017
HMIS Ratings:
Health:
1 0 0 X
Flammability: Reactivity: Personal Protection:
VOC Less Water Less Exempt Solvent, g/L:
VOC Material, g/L: 20
VOC as Defined by California Consumer Product Regulation, Wt/Wt%:
VOC Actual, Wt/Wt%: 1.1
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302 Harmful if swallowed.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS07
36.0
0.1
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly
trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific
context of the intended use and (ii) determine if they are appropriate.
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