SDS Number: 00010002001 Revision Date: 9/12/2018
24 Hour Emergency Phone Numbers
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
Safety Data Sheet
1-800-535-5053
1-352-323-3500
NOTE: The National ResponseCenter emergency
numbers to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this SDS are further described in Section 16.
1. Identification
This Safety Data Sheet is available in American Spanish upon request.
Los Datos de Serguridad pueden obtenerse en Espanol si lo riquiere.
Product Name:
Product UPC Number:
Product Use/Class: Caulking Compound
Manufacturer:
Alex Plus Acrylic Latex Caulk Plus Silicone All Colors
070798181106, 070798181120,
070798181113, 070798181090,
070798181076, 070798181359,
070798181014, 070798181281,
070798181366, 070798181724,
070798181557, 070798114401
DAP Products Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non - emergency matters)
SDS Coordinator: MSDS@dap.com
Emergency Telephone:
Transportation: 1-800-535 -5053
1-352-323-3500
Poison Control: 1-800-222-1222
Revision Date:
Supercedes Date:
SDS No:
Preparer:
9/12/2018
1/12/2016
00010002001
Regulatory and Environmental
Affairs
2. Hazards Identification
Page 1 / 6
SDS Number: 00010002001 Revision Date: 9/12/2018
45-70
No Information
3-7
GHS07
1-5
GHS06
1-5
No Information
0.5-1.5
GHS06
0.5-1.5
GHS07
0.1-1.0
No Information
0.1-1.0
GHS07
0.1-1.0
No Information
GHS Classification
Not a hazardous substance or mixture.
Symbol(s) of Product
None
Signal Word
Not a hazardous substance or mixture.
Possible Hazards
6% of the mixture consists of ingredients of unknown acute toxicity
3. Composition/Information on Ingredients
Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements
1317-65-3
72623-86-0
64741-88-4
27138-31-4
64741-89-5
120-55-8
13463-67-7
14808-60-7
1333-86-4
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
4. First-aid Measures
FIRST AID - INHALATION: Material is not likely to present an inhalation hazard at ambient conditions. If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately.
FIRST AID - SKIN CONTACT: In case of contact, wash skin immediately with soap and water.
FIRST AID - EYE CONTACT: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: No Information
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog
6. Accidental Release Measures
ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Use personal protective equipment as necessary. In case of
spillage, absorb with inert material and dispose of in accordance with applicable regulations. Scrape up dried material and place into
containers.
7. Handling and Storage
HANDLING: KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Use only with adequate ventilation. Ensure fresh
air entry during application and drying. Wash thoroughly after handling.
STORAGE: Avoid excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and
oxidizers.
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA
OSHA PEL-CEILING
Page 2 / 6
SDS Number: 00010002001 Revision Date: 9/12/2018
Limestone N.E. N.E. 15 mg/m3 TWA
total dust, 5 mg/m3
TWA respirable
fraction
Lubricating petroleum oil N.E. N.E. N.E. N.E.
Petroleum distillates N.E. N.E. N.E. N.E.
Dipropylene glycol dibenzoate N.E. N.E. N.E. N.E.
Solvent ref. light paraffinic N.E. N.E. N.E. N.E.
Diethylene glycol dibenzoate N.E. N.E. N.E. N.E.
Titanium dioxide 10 mg/m3 TWA N.E. 15 mg/m3 TWA
total dust
Quartz 0.025 mg/m3 TWA
respirable
particulate matter
Carbon black 3 mg/m3 TWA
inhalable particulate
matter
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established
N.E. 50 µg/m3 TWA N.E.
N.E. 3.5 mg/m3 TWA N.E.
N.E.
N.E.
Personal Protection
RESPIRATORY PROTECTION: No personal respiratory protective equipment normally required. National Institute for
Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50
micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour
work shift.
SKIN PROTECTION: Rubber gloves.
EYE PROTECTION: Goggles or safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT: Not required under normal use.
HYGIENIC PRACTICES: Wash hands before breaks and at the end of workday. Remove and wash contaminated
clothing before re-use.
9. Physical and Chemical Properties
Appearance: Colored Physical State: Paste
Odor: Very Slight Ammonia Odor Threshold: Not Established
Density, g/cm3: 1.60 - 1.67 pH: Between 7.0 and 12.0
Freeze Point, °C: Not Established Viscosity (mPa.s): Not Established
Solubility in Water: No Information Partition Coeff., n-octanol/water: Not Established
Decomposition Temperature, °C: Not Established Explosive Limits, %: Not Established -
Not Established
Boiling Range, °C: N.I. - N.I. Auto-Ignition Temperature, °C Not Established
Minimum Flash Point, °C: 100 Vapor Pressure, mmHg: Not Established
Evaporation Rate: Slower Than n-Butyl Acetate Flash Method: Seta Closed Cup
Vapor Density: Heavier Than Air
Combustibility: Supports combustion
Flammability, NFPA: Non-Flammable
(See "Other information" Section for abbreviation legend)
(If product is an aerosol, the flash point stated above is that of the propellant.)
Page 3 / 6
SDS Number: 00010002001 Revision Date: 9/12/2018
10. Stability and Reactivity
STABILITY: Stable under recommended storage conditions.
CONDITIONS TO AVOID: Excessive heat and freezing.
INCOMPATIBILITY: Incompatible with strong bases and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx.
11. Toxicological Information
EFFECT OF OVEREXPOSURE - INHALATION: Under normal use conditions, this product is not expected to cause adverse health
effects. Inhalation of vapors in high concentration may cause mild irritation of respiratory system (nose, mouth, mucous membranes).
EFFECT OF OVEREXPOSURE - SKIN CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Prolonged or repeated contact with skin may cause mild irritation.
EFFECT OF OVEREXPOSURE - EYE CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Direct eye contact may cause irritation.
EFFECT OF OVEREXPOSURE - INGESTION: Under normal use conditions, this product is not expected to cause adverse health
effects. Single dose oral toxicity is very low. Amounts ingested incidental to industrial handling are not likely to cause injury; however,
ingestion of large amounts may cause injury.
CARCINOGENICITY: No Information
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated or prolonged exposure may cause mild irritation of eyes and
skin. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC
Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The
National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th
Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica,
quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause
noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious
chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in
delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, nonspecific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested
by fibrosis of the lungs, skin and other internal organs) and kidney disease.
PRIMARY ROUTE(S) OF ENTRY: Inhalation, Skin Contact
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS-No.
1317-65-3 Limestone 6450 mg/kg Rat >2000 mg/kg >20 mg/L
72623-86-0 Lubricating petroleum oil >5000 mg/kg Rat >2000 mg/kg Rabbit N.I.
64741-88-4 Petroleum distillates >5000 mg/kg Rat >2000 mg/kg Rabbit 2.18 mg/L Rat
27138-31-4 Dipropylene glycol dibenzoate 5368 mg/kg Rat >2000 mg/kg Rabbit >200 mg/L Rat
64741-89-5 Solvent ref. light paraffinic >15000 mg/kg Rat >5000 mg/kg Rabbit 2.18 mg/L Rat
120-55-8 Diethylene glycol dibenzoate 2830 mg/kg Rat 2000 mg/kg Rabbit >200 mg/L Rat
13463-67-7 Titanium dioxide >10000 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L
14808-60-7 Quartz 500 mg/kg Rat >2000 mg/kg >20 mg/L
1333-86-4 Carbon black >8000 mg/kg Rat >3000 mg/kg Rabbit > 20 mg/L
N.I. = No Information
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
Page 4 / 6
SDS Number: 00010002001 Revision Date: 9/12/2018
12. Ecological Information
ECOLOGICAL INFORMATION: Ecological injuries are not known or expected under normal use.
13. Disposal Information
DISPOSAL INFORMATION: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous
Waste Management Regulation, 40 CFR Section 261. Dispose as hazardous waste according to all local, state, federal and provincial
regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper
waste disposal is with the owner of the waste.
14. Transport Information
SPECIAL TRANSPORT PRECAUTIONS: No Information
DOT UN/NA Number: N.A.
DOT Proper Shipping Name: Not Regulated
DOT Technical Name: N.A.
DOT Hazard Class: N.A.
Hazard SubClass: N.A.
Packing Group: N.A.
15. Regulatory Information
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b) components exist in this product.
Page 5 / 6
SDS Number: 00010002001 Revision Date: 9/12/2018
16. Other Information
Revision Date: 9/12/2018
Reason for revision: Revision Description Changed
Product Composition Changed
Substance and/or Product Properties Changed in Section(s):
01 - Product Information
05 - Flammability Information
09 - Physical & Chemical Information
14 - Transportation Information
15 - Regulatory Information
16 - Other Information
Revision Statement(s) Changed
Datasheet produced by: Regulatory Department
Supersedes Date: 1/12/2016
HMIS Ratings:
Health:
1 1 0 X
Flammability: Reactivity: Personal Protection:
VOC Less Water Less Exempt Solvent, g/L:
VOC as Defined by California Consumer Product Regulation, Wt/Wt%:
VOC Actual, Wt/Wt%: 1.6
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
37.5
VOC Material, g/L: 27
0.8
GHS06
GHS07
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly
trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific
context of the intended use and (ii) determine if they are appropriate.
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