SDS Number: 00011608001 Revision Date: 6/19/2015
24 Hour Emergency Phone Numbers
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
Safety Data Sheet
1-800-535-5053
1-352-323-3500
NOTE: The National ResponseCenter emergency
numbers to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this SDS are further described in Section 16.
1. Identification
This Safety Data Sheet is available in American Spanish upon request.
Los Datos de Serguridad pueden obtenerse en Espanol si lo riquiere.
Product Name:
Product UPC Number:
Product Use/Class: Caulking Compound
Manufacturer:
Emergency Telephone:
Safety Data Sheet Coordinator:
DAP 3.0 Gutter & Flashing Sealant Crystal
Clear
18377
DAP Products Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non - emergency matters)
1-800-535-5053, 1-352-323-3500, 1-800-222-1222
MSDS@DAP.com
Revision Date: 6/19/2015
Supercedes Date:
SDS No: 00011608001
Preparer: Regulatory Department
New SDS
2. Hazards Identification
EMERGENCY OVERVIEW: Under normal use conditions, this product is not expected to cause adverse health effects. High
concentration of vapors may cause irritation to eyes and respiratory system.
GHS Classification
Eye Irrit. 2, Skin Irrit. 2
Symbol(s) of Product
Signal Word
Warning
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SDS Number: 00011608001 Revision Date: 6/19/2015
25-50
GHS03-GHS07
1.0-2.5
GHS03-GHS07
1.0-2.5
GHS03-GHS07
1.0-2.5
GHS03-GHS06
1.0-2.5
GHS03-GHS07
GHS HAZARD STATEMENTS
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
GHS LABEL PRECAUTIONARY STATEMENTS
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362 Take off contaminated clothing.
3. Composition/Information on Ingredients
Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements
Proprietary
68583-49-3 2.5-10 GHS03-GHS07 H270-315-319-335
2768-02-7
13822-56-5
Proprietary
7631-86-9
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
4. First-aid Measures
FIRST AID - INHALATION: Material is not likely to present an inhalation hazard at ambient conditions. If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately.
FIRST AID - SKIN CONTACT: Wash skin with soap and water for 15 minutes. Get medical aid if symptoms persist.
FIRST AID - EYE CONTACT: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: No special protective measures against fire required.
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam
6. Accidental Release Measures
ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material and remove with inert absorbent.
Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Scrape
up dried material and place into containers. Use personal protective equipment as necessary. In case of spillage, absorb with inert
material and dispose of in accordance with applicable regulations.
7. Handling and Storage
HANDLING: KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes,
skin and clothing. Use only with adequate ventilation. Ensure fresh air entry during application and drying. Wash thoroughly after
handling. Remove contact lenses before using. Do not handle contact lenses until all sealant has been cleaned from fingertips, nails
and cuticles. Residual sealant may transfer to contact lenses and cause severe eye irritation.
STORAGE: Avoid excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and
oxidizers.
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA
OSHA PEL-CEILING
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SDS Number: 00011608001 Revision Date: 6/19/2015
Proprietary Phthalate Esters N.E. N.E. N.E. N.E.
Cyclotetrasiloxane, octamethyl-, reaction
prods. with silica
Organosilane Ester N.E. N.E. N.E. N.E.
3-(trimethoxysilyl)propylamine N.E. N.E. N.E. N.E.
Proprietary Phthalate Esters N.E. N.E. N.E. N.E.
Silica, amorphous N.E. N.E. N.E. N.E.
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established
N.E. N.E. N.E. N.E.
Personal Protection
RESPIRATORY PROTECTION: No personal respiratory protective equipment normally required.
SKIN PROTECTION: Wear nitrile or neoprene gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not
suitable protection against phthalates such as diisodecyl phthalate and diisononyl phthalate; neoprene is recommended.
EYE PROTECTION: Goggles or safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT: Not required under normal use.
HYGIENIC PRACTICES: Wash hands before breaks and at the end of workday. Remove and wash contaminated
clothing before re-use.
9. Physical and Chemical Properties
Appearance: Clear Physical State: Paste
Odor: Slight Odor Threshold: Not Established
Density, g/cm3: 1.04 - 1.04 pH: Not Established
Freeze Point, °C: Not Established Viscosity (mPa.s): Not Established
Solubility in Water: No Information Partition Coeff., n-octanol/water: Not Established
Decomposition Temperature, °C: Not Established Explosive Limits, %: N.I. - N.I.
Boiling Range, °C: N.I. - N.I. Auto-Ignition Temperature, °C Not Established
Minimum Flash Point, °C: 93.3 Vapor Pressure, mmHg: No Information
Evaporation Rate: Slower Than n-Butyl Acetate Flash Method: Pensky-Martens
Closed Cup
Vapor Density: Heavier Than Air
Combustibility: Does not support combustion
(See "Other information" Section for abbreviation legend)
(If product is an aerosol, the flash point stated above is that of the propellant.)
Flammability: No Information
10. Stability and Reactivity
STABILITY: Stable under recommended storage conditions.
CONDITIONS TO AVOID: Excessive heat and freezing.
INCOMPATIBILITY: Incompatible with strong bases and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx.
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SDS Number: 00011608001 Revision Date: 6/19/2015
11. Toxicological Information
EFFECT OF OVEREXPOSURE - INHALATION: Under normal use conditions, this product is not expected to cause adverse health
effects. During application and cure, this product releases methanol. Methanol may affect the brain or nervous system causing
dizziness, headache or nausea. Inhalation of vapors in high concentration may cause mild irritation of respiratory system (nose,
mouth, mucous membranes).
EFFECT OF OVEREXPOSURE - SKIN CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Prolonged or repeated contact with skin may cause mild irritation.
EFFECT OF OVEREXPOSURE - EYE CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Direct eye contact may cause irritation.
EFFECT OF OVEREXPOSURE - INGESTION: Under normal use conditions, this product is not expected to cause adverse health
effects. Single dose oral toxicity is very low. Amounts ingested incidental to industrial handling are not likely to cause injury; however,
ingestion of large amounts may cause injury. Ingestion may result in obstruction when material hardens.
CARCINOGENICITY: No Information
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated or prolonged exposure may cause irritation of eyes and skin. A
mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory animals. No
effects on reproductive parameters were seen. However, a small but statistically significant increase in early offspring mortality was
seen at high oral doses. The significance of this to humans is uncertain.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Inhalation, Skin Contact
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS-No.
68515-49-1 Proprietary Phthalate Esters >60000 mg/kg Rat 16000 mg/kg Rabbit >12.54 mg/L Rat
68583-49-3 Cyclotetrasiloxane, octamethyl-, reaction
2768-02-7 Organosilane Ester 11000 mg/kg Rat 3259.2 mg/kg Rabbit >20 mg/L
13822-56-5 3-(trimethoxysilyl)propylamine 2968 mg/kg Rat 11292 mg/kg Rabbit N.I.
68515-48-0 Proprietary Phthalate Esters 2550 mg/kg Rat >3160 mg/kg Rabbit > 4.4 mg/L Rat
7631-86-9 Silica, amorphous >3300 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L
N.I. = No Information
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
>5000 mg/kg Rat N.I. N.I.
prods. with silica
12. Ecological Information
ECOLOGICAL INFORMATION: Ecological injuries are not known or expected under normal use.
13. Disposal Information
DISPOSAL INFORMATION: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous
Waste Management Regulation, 40 CFR Section 261. Dispose as hazardous waste according to all local, state, federal and provincial
regulations. Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions
are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste.
14. Transport Information
SPECIAL TRANSPORT PRECAUTIONS: No Information
DOT UN/NA Number: N.A.
DOT Proper Shipping Name: Not Regulated
DOT Technical Name: N.A.
DOT Hazard Class: N.A.
Hazard SubClass: N.A.
Packing Group: N.A.
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SDS Number: 00011608001 Revision Date: 6/19/2015
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Acute Health Hazard, Chronic Health Hazard
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b) components exist in this product.
CALIFORNIA PROPOSITION 65 CARCINOGENS AND REPRODUCTIVE TOXINS
CALIFORNIA PROPOSITION 65:
No Information
International Regulations: As follows -
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
WHMIS Class
Consumer Commodity
16. Other Information
Revision Date:
Reason for revision: HazCom2012/GHS Conversion
Datasheet produced by: Regulatory Department
6/19/2015
HMIS Ratings:
Health: 1 Flammability: 1 Reactivity: 0 Personal Protection: X
VOC Less Water Less Exempt Solvent, g/L
VOC as Defined by California Consumer Product Regulation, Wt/Wt%:
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H270 May cause or intensify fire; oxidiser.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
Supersedes Date:
VOC Material, g/L:
New MSDS
23.7
24
2.3
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SDS Number: 00011608001 Revision Date: 6/19/2015
GHS03
GHS06
GHS07
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since thisdocument is intended
only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is
therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the
intended use and (ii) determine if they are appropriate.
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