SDS Number: 00008684001 Revision Date: 5/19/2015
Hydrotreated middle distillate
10-25
GHS06
H331
24 Hour Emergency Phone Numbers:
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Safety
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
Data
NOTE: The National ResponseCenter
emergency numbers to be used only in the
Sheet
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.
event of chemical emergencies involving a spill,
leak, fire, exposure or accident involving
chemicals.
1-800-535-5053
1-352-323-3500
1. Identification
This Material Safety Data Sheet is available in American Spanish upon request.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: 100% Silicone Window & Door White Revision Date: 5/19/2015
Product UPC Number:
Product Use/Class: Caulking Compound
Manufacturer:
08646
DAP Products Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)
Supercedes Date:
SDS No: 00008684001
No Information
Preparer: Regulatory Department
2. Hazards Identification
EMERGENCY OVERVIEW: Under normal use conditions, this product is not expected to cause adverse health effects. High
concentration of vapors may cause irritation to eyes and respiratory system.
GHS Classification
Not a hazardous substance or mixture.
Symbol(s) of Product
Not a hazardous substance or mixture.
Signal Word
Not a hazardous substance or mixture.
3. Composition/Information on Ingredients
Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements
64742-46-7
Page 1 / 6
SDS Number: 00008684001 Revision Date: 5/19/2015
Silica, amorphous
2.5-10
GHS07
H332
Ethyltriacetoxysilane
2.5-10
GHS07
H302-312-315-319-332
Silanetriol, methyl-, triaceta
2.5-10
GHS07
H302-312-315-319-332
Titanium dioxide
0.1-1.0
No Information
No Information
7. Handling and Storage
7631-86-9
17689-77-9
4253-34-3
13463-67-7
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
4. First-aid Measures
FIRST AID - INHALATION: Material is not likely to present an inhalation hazard at ambient conditions. If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately.
FIRST AID - SKIN CONTACT: Wash skin with soap and water for 15 minutes. Get medical aid if symptoms persist.
FIRST AID - EYE CONTACT: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known.
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog
6. Accidental Release Measures
ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material and remove with inert absorbent.
Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Scrape up
dried material and place into containers. Use personal protective equipment as necessary. In case of spillage, absorb with inert
material and dispose of in accordance with applicable regulations.
HANDLING: KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes,
skin and clothing. Use only with adequate ventilation. Ensure fresh air entry during application and drying. Wash thoroughly after
handling. Remove contact lenses before using. Do not handle contact lenses until all sealant has been cleaned from fingertips, nails
and cuticles. Residual sealant may transfer to contact lenses and cause severe eye irritation.
STORAGE: Avoid excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and
oxidizers.
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA
OSHA PEL-CEILING
Hydrotreated middle distillate N.E. N.E. N.E. N.E.
Silica, amorphous N.E. N.E. N.E. N.E.
Ethyltriacetoxysilane N.E. N.E. N.E. N.E.
Silanetriol, methyl-, triaceta N.E. N.E. N.E. N.E.
Titanium dioxide 10 mg/m3 TWA N.E. 15 mg/m3 TWA
N.E.
total dust
Page 2 / 6
SDS Number: 00008684001 Revision Date: 5/19/2015
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation Sk
= Skin Sensitizer N.E. = Not Established
Personal Protection
RESPIRATORY PROTECTION: No personal respiratory protective equipment normally required.
SKIN PROTECTION: Wear nitrile or neoprene gloves.
EYE PROTECTION: Goggles or safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT: Not required under normal use.
HYGIENIC PRACTICES: Wash hands before breaks and at the end of workday. Remove and wash contaminated
clothing before re-use.
9. Physical and Chemical Properties
Appearance: White Physical State: Paste
Odor: Acetic Acid Odor Threshold: Not Established
Density, g/cm3: 0.96 - 0.96 pH: Not Established
Freeze Point, °C: Not Established Viscosity (mPa.s): Not Established
Solubility in Water: Not Established Partition Coeff., n-octanol/water: Not Established
Decomposition Temperature, °C: Not Established Explosive Limits, %: N.I. - N.I.
Boiling Range, °C: N.I. - N.I. Auto-Ignition Temperature, °C Not Established
Minimum Flash Point, °C: 93.3 Vapor Pressure, mmHg: No Information
Evaporation Rate: Slower Than n-Butyl Acetate Flash Method: Seta Closed Cup
Vapor Density: Heavier Than Air
Combustibility: Does not Support Combustion
(See "Other information" Section for abbreviation legend)
(If product is an aerosol, the flash point stated above is that of the propellant.)
10. Stability and Reactivity
STABILITY: Stable under recommended storage conditions.
CONDITIONS TO AVOID: Oxidizing agents. Excessive heat and freezing.
INCOMPATIBILITY: Incompatible with strong bases and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx.
11. Toxicological Information
EFFECT OF OVEREXPOSURE - INHALATION: Under normal use conditions, this product is not expected to cause adverse health
effects. During application and cure, this product releases methanol. During application and cure, this product releases acetic acid.
Inhalation of vapors in high concentration may cause mild irritation of respiratory system (nose, mouth, mucous membranes).
EFFECT OF OVEREXPOSURE - SKIN CONTACT: Under normal use conditions, this product is not expected to cause adverse
Page 3 / 6
SDS Number: 00008684001 Revision Date: 5/19/2015
health effects. Prolonged or repeated contact with skin may cause mild irritation.
EFFECT OF OVEREXPOSURE - EYE CONTACT: Under normal use conditions, this product is not expected to cause adverse health
effects. Direct eye contact may cause irritation.
EFFECT OF OVEREXPOSURE - INGESTION: Under normal use conditions, this product is not expected to cause adverse health
effects. Single dose oral toxicity is very low. Amounts ingested incidental to industrial handling are not likely to cause injury; however,
ingestion of large amounts may cause injury. Ingestion may result in obstruction when material hardens.
CARCINOGENICITY: No Information
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Inhalation, Skin Contact
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS-No.
64742-46-7 Hydrotreated middle distillate 7400 mg/kg Rat >2000 mg/kg Rabbit 4.6 mg/L Rat
7631-86-9 Silica, amorphous >3300 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L
17689-77-9 Ethyltriacetoxysilane 1460 mg/kg Rat 1060 mg/kg Rabbit 11.6 mg/kg Rat
4253-34-3 Silanetriol, methyl-, triaceta 1602 mg/kg Rat 1060 mg/kg Rabbit 11.6 mg/L
13463-67-7 Titanium dioxide >10000 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L
N.I. = No Information
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
12. Ecological Information
ECOLOGICAL INFORMATION: Ecological injuries are not known or expected under normal use.
13. Disposal Information
DISPOSAL METHOD: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste
Management Regulation, 40 CFR Section 261. Dispose as hazardous waste according to all local, state, federal and provincial
regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper
waste disposal is with the owner of the waste.
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material and remove with inert absorbent.
Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Scrape up
dried material and place into containers. Use personal protective equipment as necessary. In case of spillage, absorb with inert
material and dispose of in accordance with applicable regulations.
14. Transport Information
SPECIAL TRANSPORT PRECAUTIONS: No Information
DOT Proper Shipping Name: Not Regulated
DOT Technical Name: N.A. Hazard SubClass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: N.A.
Packing Group: N.A.
Page 4 / 6
SDS Number: 00008684001 Revision Date: 5/19/2015
International Regulations: As follows -
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Acute Health Hazard, Chronic Health Hazard
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA12(b) components exist in this product in concentrations at or above their thresholds.
CALIFORNIA PROPOSITION 65 CARCINOGENS
WARNING: This product contains chemicals known to the State of California to cause cancer.
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
This product does not contain any chemicals known to the State of California to cause birth defects or other reproductive harm.
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
WHMIS Class
Consumer COmmodity
16. Other Information
Revision Date:
Reason for revision: HazCom2012/GHS Conversion
Datasheet produced by: Regulatory Department
5/19/2015
HMIS Ratings:
Health: 1 Flammability: 1 Reactivity: 0 Personal Protection: X
VOC Less Water Less Exempt, g/L:
VOC as Defined by California Consumer Product Regulation, Wt/Wt%:
Supersedes Date:
VOC, Material, g/L:
No Information
28.9
29
3.0
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
Page 5 / 6
SDS Number: 00008684001 Revision Date: 5/19/2015
H331 Toxic if inhaled.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS06
GHS07
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since thisdocument is
intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is
therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended
use and (ii) determine if they are appropriate.
Page 6 / 6
Loading...