SDS Number: 00077365004 Revision Date: 2/23/2018
24 Hour Emergency Phone Numbers
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
Safety Data Sheet
1-800-535-5053
1-352-323-3500
NOTE: The National ResponseCenter emergency
numbers to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this SDS are further described in Section 16.
1. Identification
This Safety Data Sheet is available in American Spanish upon request.
Los Datos de Serguridad pueden obtenerse en Espanol si lo riquiere.
Product Name:
Product UPC Number:
Product Use/Class: Caulking Compound
Manufactured For
Blockade Fire-Rated Intumescent Acrylic
Latex Sealant
070798188587
DAP Products Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non - emergency matters)
SDS Coordinator: MSDS@dap.com
Emergency Telephone: 1-800-535-5053,
1-352-323-3500, 1-800-222-1222
Revision Date:
Supercedes Date:
SDS No:
Preparer:
2/23/2018
7/14/2015
00077365004
Regulatory and Environmental
Affairs
2. Hazards Identification
EMERGENCY OVERVIEW: Under normal use conditions, this product is not expected to cause adverse health effects.
Page 1 / 7
SDS Number: 00077365004 Revision Date: 2/23/2018
Zinc borate
10-25
No Information
No Information
Graphite
2.5-10
No Information
No Information
Butene, homopolymer
2.5-10
GHS06-GHS08
H304-315-331
Limestone
2.5-10
No Information
No Information
Soda lime borosilicate glass
2.5-10
No Information
No Information
Propylene glycol
1.0-2.5
No Information
No Information
Iron oxide
1.0-2.5
GHS06
H319-330
GHS05-GHS06GHS08
Sulfuric acid
0.1-1.0
GHS05-GHS06
H314-330
Quartz
0.1-1.0
GHS07
H302
GHS Classification
Acute Tox. 4 Inhalation, Carc. 1B
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
20% of the mixture consists of ingredients of unknown acute toxicity
GHS HAZARD STATEMENTS
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
Carcinogenicity, category 1B H350 May cause cancer.
GHS LABEL PRECAUTIONARY STATEMENTS
P201 Obtain special instructions before use.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P405 Store locked up.
P501 Dispose of contents/container to …
3. Composition/Information on Ingredients
Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements
1332-07-6
7782-42-5
9003-29-6
1317-65-3
65997-17-3
57-55-6
1309-37-1
Sulfuric acid 7664-93-9 1.0-2.5
7697-37-2
14808-60-7
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
H314-330-350
4. First-aid Measures
FIRST AID - INHALATION: Material is not likely to present an inhalation hazard at ambient conditions. If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately.
FIRST AID - SKIN CONTACT: No health hazards are known to exist. In case of contact, wash skin immediately with soap and water.
FIRST AID - EYE CONTACT: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: No Information
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Page 2 / 7
SDS Number: 00077365004 Revision Date: 2/23/2018
6. Accidental Release Measures
ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material and remove with inert absorbent.
Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Scrape
up dried material and place into containers. Use personal protective equipment as necessary. In case of spillage, absorb with inert
material and dispose of in accordance with applicable regulations.
7. Handling and Storage
HANDLING: KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Use only with adequate ventilation. Ensure fresh
air entry during application and drying. Wash thoroughly after handling.
STORAGE: Avoid excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and
oxidizers.
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA
Zinc borate N.E. N.E. N.E. N.E.
Graphite 2 mg/m3 TWA all
forms except
graphite fibers
respirable
particulate matter
Butene, homopolymer N.E. N.E. N.E. N.E.
Limestone N.E. N.E. 15 mg/m3 TWA
Soda lime borosilicate glass N.E. N.E. N.E. N.E.
Propylene glycol N.E. N.E. N.E. N.E.
Iron oxide 5 mg/m3 TWA
respirable
particulate matter
Sulfuric acid 0.2 mg/m3 TWA
thoracic particulate
matter
Sulfuric acid 0.2 mg/m3 TWA
thoracic particulate
matter
Quartz 0.025 mg/m3 TWA
respirable
particulate matter
N.E. 15 mg/m3 TWA
synthetic total dust,
5 mg/m3 TWA
synthetic respirable
fraction
total dust, 5 mg/m3
TWA respirable
fraction
N.E. 10 mg/m3 TWA
fume, 15 mg/m3
TWA total dust
Rouge, 5 mg/m3
TWA respirable
fraction Rouge
N.E. 1 mg/m3 TWA N.E.
N.E. 1 mg/m3 TWA N.E.
N.E. 50 µg/m3 TWA N.E.
OSHA PEL-CEILING
N.E.
N.E.
N.E.
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established
Personal Protection
RESPIRATORY PROTECTION: No personal respiratory protective equipment normally required. National Institute for
Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50
micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour
work shift.
SKIN PROTECTION: Rubber gloves.
Page 3 / 7
SDS Number: 00077365004 Revision Date: 2/23/2018
EYE PROTECTION: Goggles or safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT: Not required under normal use.
HYGIENIC PRACTICES: Wash hands before breaks and at the end of workday. Remove and wash contaminated
clothing before re-use.
9. Physical and Chemical Properties
Appearance: Red Physical State: Paste
Odor: Slight Odor Threshold: Not Established
Density, g/cm3: 1.38 - 1.38 pH: Between 7.0 and 12.0
Freeze Point, °C: Not Established Viscosity (mPa.s): Not Established
Solubility in Water: No Information Partition Coeff., n-octanol/water: Not Established
Decomposition Temperature, °C: Not Established Explosive Limits, %: N.I. - N.I.
Boiling Range, °C: N.I. - N.I. Auto-Ignition Temperature, °C Not Established
Minimum Flash Point, °C: 93.3 Vapor Pressure, mmHg: Not Established
Evaporation Rate: Slower Than n-Butyl Acetate Flash Method: Seta Closed Cup
Vapor Density: Heavier Than Air
Combustibility: Does not support combustion
Flammability: Non-Flammable
(See "Other information" Section for abbreviation legend)
(If product is an aerosol, the flash point stated above is that of the propellant.)
10. Stability and Reactivity
STABILITY: Stable under recommended storage conditions.
CONDITIONS TO AVOID: Excessive heat and freezing.
INCOMPATIBILITY: Incompatible with strong bases and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx.
11. Toxicological Information
EFFECT OF OVEREXPOSURE - INHALATION: Under normal use conditions, this product is not expected to cause adverse health
effects. Inhalation of vapors in high concentration may cause mild irritation of respiratory system (nose, mouth, mucous membranes).
EFFECT OF OVEREXPOSURE - SKIN CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Prolonged or repeated contact with skin may cause mild irritation.
EFFECT OF OVEREXPOSURE - EYE CONTACT: Under normal use conditions, this product is not expected to cause adverse
health effects. Direct eye contact may cause irritation.
EFFECT OF OVEREXPOSURE - INGESTION: Under normal use conditions, this product is not expected to cause adverse health
effects. Single dose oral toxicity is very low. Amounts ingested incidental to industrial handling are not likely to cause injury; however,
ingestion of large amounts may cause injury.
CARCINOGENICITY: No Information
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated or prolonged exposure may cause mild irritation of eyes and
skin. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC
Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The
National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th
Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica,
quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause
noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious
chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in
delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-
Page 4 / 7
SDS Number: 00077365004 Revision Date: 2/23/2018
specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested
by fibrosis of the lungs, skin and other internal organs) and kidney disease.
PRIMARY ROUTE(S) OF ENTRY: Inhalation, Skin Contact
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
1332-07-6 Zinc borate N.I. N.I. N.I.
7782-42-5 Graphite N.I. N.I. N.I.
9003-29-6 Butene, homopolymer 10000 mg/kg Rat >2000 mg/kg Rat >3.8 mg/L Rat
1317-65-3 Limestone 6450 mg/kg Rat >2000 mg/kg >20 mg/L
65997-17-3 Soda lime borosilicate glass >2000 mg/kg Rat >2000 mg/kg >20 mg/L
57-55-6 Propylene glycol 22000 mg/kg Rat >2000 mg/kg Rabbit >20 mg/L
1309-37-1 Iron oxide >10000 mg/kg Rat >2000 mg/kg >20 mg/L
7664-93-9 Sulfuric acid 2140 mg/kg Rat N.I. 173.5 mg/L Rat
7664-93-9 Sulfuric acid 2140 mg/kg Rat N.I. .5 mg/L Rat
14808-60-7 Quartz 500 mg/kg Rat >2000 mg/kg >20 mg/L
N.I. = No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Ecological injuries are not known or expected under normal use.
13. Disposal Information
DISPOSAL INFORMATION: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous
Waste Management Regulation, 40 CFR Section 261. Dispose as hazardous waste according to all local, state, federal and provincial
regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper
waste disposal is with the owner of the waste.
14. Transport Information
SPECIAL TRANSPORT PRECAUTIONS: No Information
DOT UN/NA Number: N.A.
DOT Proper Shipping Name: Not Regulated.
DOT Technical Name: N.A.
DOT Hazard Class: N.A.
Hazard SubClass: N.A.
Packing Group: N.A.
15. Regulatory Information
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
Sulfuric acid
Chlorothalonil
Page 5 / 7
SDS Number: 00077365004 Revision Date: 2/23/2018
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b) components exist in this product.
16. Other Information
Revision Date: 2/23/2018
Reason for revision: Revision Description Changed
Product Composition Changed
Substance and/or Product Properties Changed in Section(s):
01 - Product Information
02 - Hazards Identification
09 - Physical & Chemical Information
15 - Regulatory Information
16 - Other Information
Revision Statement(s) Changed
Datasheet produced by: Regulatory Department
Supersedes Date: 7/14/2015
HMIS Ratings:
Health: 1 Flammability: 0 Reactivity: 0 Personal Protection: X
VOC Less Water Less Exempt Solvent, g/L:
VOC Material, g/L:
VOC as Defined by California Consumer Product Regulation, Wt/Wt%:
VOC Actual, Wt/Wt%:
46.0
31
1.3
2.3
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H350 May cause cancer.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS05
GHS06
GHS07
GHS08
Page 6 / 7
SDS Number: 00077365004 Revision Date: 2/23/2018
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since thisdocument is intended
only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is
therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the
intended use and (ii) determine if they are appropriate.
Page 7 / 7
Loading...