SDS Number: 00030197004 Revision Date: 10/4/2018
24 Hour Emergency Phone Numbers
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
Safety Data Sheet
1-800-535-5053
1-352-323-3500
NOTE: The National ResponseCenter emergency
numbers to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this SDS are further described in Section 16.
1. Identification
This Safety Data Sheet is available in American Spanish upon request.
Los Datos de Serguridad pueden obtenerse en Espanol si lo riquiere.
Product Name: Weldwood Contact Cement Spray Adhesive Revision Date:
Product UPC Number:
Product Use/Class: Contact Adhesive
Manufactured For
070798001220
DAP Products Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non - emergency matters)
SDS Coordinator: MSDS@dap.com
Emergency Telephone: 1-800-535-5053,
1-352-323-3500, 1-800-222-1222
Supercedes Date:
SDS No:
Preparer:
2. Hazards Identification
10/4/2018
1/12/2016
00030197004
Regulatory and Environmental
Affairs
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SDS Number: 00030197004 Revision Date: 10/4/2018
GHS Classification
Carc. 2, Comp. Gas, Eye Irrit. 2, Eye Irrit. 2B, Fl Aer, 1, Muta. 1B, Skin Irrit. 2, STOT RE 1, STOT RE 2, STOT SE 3 NE, STOT SE
3 RTI
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
98% of the mixture consists of ingredients of unknown acute toxicity
GHS HAZARD STATEMENTS
Flammable Aerosol, category 1 H222 Extremely flammable aerosol.
Compressed Gas H280 Contains gas under pressure; may explode if heated.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Germ Cell Mutagenicity, category 1B H340 May cause genetic defects .
Carcinogenicity, category 2 H351 Suspected of causing cancer.
STOT, repeated exposure, category 1 H372 Causes damage to organs through prolonged or repeated exposure.
STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated exposure.
Eye Irritation, category 2B H320 Causes eye irritation
GHS LABEL PRECAUTIONARY STATEMENTS
P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P321 Specific treatment (see … on this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362 Take off contaminated clothing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.
P501 Dispose of contents/container to …
GHS SDS PRECAUTIONARY STATEMENTS
P270 Do no eat, drink or smoke when using this product.
3. Composition/Information on Ingredients
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SDS Number: 00030197004 Revision Date: 10/4/2018
Acetone
15-40
GHS02-GHS07
H225-319-336
GHS02-GHS07GHS08
GHS02-GHS07GHS08
S-i-s block coploymer
5-10
No Information
No Information
Hydrocarbon
5-10
No Information
No Information
Petroleum hydrocarbon resin
5-10
No Information
No Information
GHS02-GHS07GHS08
Methyl acetate
3-7
GHS02-GHS07
H225-319-332-336
Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements
67-64-1
n-Hexane 110-54-3 10-30
H225-304-315-336-373
Hydrocarbon Propellant 68476-86-8 10-30
25038-32-8
68003-51-0
68527-25-3
Toluene 108-88-3 3-7
79-20-9
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
H220-332-340
H225-304-315-332-335-336-373
4. First-aid Measures
FIRST AID - INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention immediately. NOTE: Only trained personnel should administer artificial respiration or give oxygen.
FIRST AID - SKIN CONTACT: Wash skin with soap and water for 15 minutes. Get medical aid if symptoms persist. Remove and
wash contaminated clothing. DO NOT try to peel the solidified material from the skin or use solvents or thinners to dissolve it. The
use of vegetable oil or mineral oil is recommended for removal of this material from the skin. Flush exposed area with water while
removing contaminated clothing. Get medical attention if irritation persists. To remove from skin, remove completely with a dry cloth
or paper towel, before washing with detergent and water.
FIRST AID - EYE CONTACT: If material gets into eyes, flush with water immediately for 15 minutes. Consult a physician.
FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire-fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: Containers may explode if exposed to extreme heat.
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces. Cool fire-exposed containers using water spray.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam
6. Accidental Release Measures
ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: NOTE: Review fire hazards before proceeding with clean up.
Immediately eliminate sources of ignition. Keep people away from and upwind of spill/leak. Contain spilled material and remove with
inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal
regulations. Prevent product from entering drains. Soak up with inert absorbent material and dispose of as hazardous waste. Read
all product instructions before using. Personal protective equipment should include impervious gloves, protective eye wear, and
suitable work clothes. Scrape up dried material and place into containers.
7. Handling and Storage
HANDLING: KEEP OUT OF REACH OF CHILDREN!DO NOT TAKE INTERNALLY. Make sure nozzle is directed away from yourself
prior to discharge. Use in well ventilated area. Open all windows and doors or use other means to ensure cross-ventilation and fresh
air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Do not breathe dust. While dry
sanding, use of a NIOSH-approved dust mask is recommended. Empty containers retain product residue (liquid and/or vapor). Vapor
can ignite potentially causing an explosion. Do not use in areas where static sparks may be generated. Intentional misuse by
deliberately concentrating and inhaling vapors may be harmful or fatal. Construction and repair activities can adversely affect indoor
air quality. Consult with occupants or a representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to
determine ways to minimize impact.
STORAGE: Store away from sources of ignition and heat. Keep away from heat and sources of ignition. Protect material from direct
sunlight. Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing. Store away
from caustics and oxidizers. Keep containers tightly closed.
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA
OSHA PEL-CEILING
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SDS Number: 00030197004 Revision Date: 10/4/2018
Acetone 250 ppm TWA 500 ppm STEL 1000 ppm TWA,
2400 mg/m3 TWA
n-Hexane 50 ppm TWA N.E. 500 ppm TWA,
1800 mg/m3 TWA
Hydrocarbon Propellant N.E. N.E. N.E. N.E.
S-i-s block coploymer N.E. N.E. N.E. N.E.
Hydrocarbon N.E. N.E. N.E. N.E.
Petroleum hydrocarbon resin N.E. N.E. N.E. N.E.
Toluene 20 ppm TWA N.E. 200 ppm TWA 300 ppm Ceiling
Methyl acetate 200 ppm TWA 250 ppm STEL 200 ppm TWA, 610
mg/m3 TWA
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established
N.E.
N.E.
N.E.
Personal Protection
RESPIRATORY PROTECTION: When concentrations exceed the exposure limits specified, use of a NIOSH-approved
dust, mist and fume respirator is recommended. Where the protection factor of the respirator may be exceeded, use of
a full facepiece, supplied air, or Self Contained Breathing Apparatus (SCBA) may be necessary. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. If concentrations exceed the exposure limits specified,
use of a NIOSH-approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a
Self Contained Breathing Apparatus (SCBA) may be necessary. If you experience eye watering, headache or dizziness
or if air monitoring demonstrates vapor/mist levels are above applicable limits, wear and appropriate, properly fitted
respirator (NIOSH approved) during and after application. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Solvent-resistant gloves. Wear protective gloves.
EYE PROTECTION: Goggles or safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT: Provide eyewash and solvent impervious apron if body contact may occur.
HYGIENIC PRACTICES: Remove and wash contaminated clothing before re-use.
9. Physical and Chemical Properties
Appearance: Tan Physical State: Aerosol
Odor: Solvent Odor Threshold: Not Established
Density, g/cm3: 0.80 - 0.80 pH: Not Applicable
Freeze Point, °C: Not Established Viscosity (mPa.s): Not Applicable
Solubility in Water: No Information Partition Coeff., n-octanol/water: Not Established
Decomposition Temperature, °C: Not Established Explosive Limits, %: N.E. - N.E.
Boiling Range, °C: N.E. - N.E. Auto-Ignition Temperature, °C Not Established
Minimum Flash Point, °C: Not Applicable Vapor Pressure, mmHg: Not Established
Evaporation Rate: Faster Than n-Butyl Acetate Flash Method: Not Applicable
Vapor Density: Heavier Than Air
Combustibility: Does not support combustion
Flammability, NFPA: Aerosol Level I
(See "Other information" Section for abbreviation legend)
(If product is an aerosol, the flash point stated above is that of the propellant.)
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SDS Number: 00030197004 Revision Date: 10/4/2018
10. Stability and Reactivity
STABILITY: Stable under recommended storage conditions.
CONDITIONS TO AVOID: Do not breathe dust. Avoid dust formation in confined areas. Do not burn or use a cutting torch on the
empty container. Excessive heat or flames, incompatible substances. Keep away from open flames, hot surfaces and sources of
ignition. Keep away from oxidizing agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions. Avoid
contact with skin, eyes and clothing. Do not smoke.
INCOMPATIBILITY: Exothermic reaction with strong acids. Strong oxidizing agents. Strong bases.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx.
11. Toxicological Information
EFFECT OF OVEREXPOSURE - INHALATION: Inhalation of vapors may cause irritation of the nose, throat, lungs and respiratory
tract. Inhalation of vapors in high concentration may cause shortness of breath (lung edema). Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal. Prolonged, repeated or high exposures may cause central nervous
system depression leading to headaches, nausea, drowsiness, dizziness, and possibly narcosis. In extreme cases, may cause loss
of consciousness. Prolonged, repeated, or high exposures may cause irritation to the respiratory tract (nose, mouth, mucous
membranes).
EFFECT OF OVEREXPOSURE - SKIN CONTACT: Harmful if absorbed through the skin. May cause skin irritation. Prolonged and
repeated skin contact may cause dermatitis, drying and defatting due to the solvent properties.
EFFECT OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. Signs and symptoms may include: pain, tears, swelling,
redness and blurred vision.
EFFECT OF OVEREXPOSURE - INGESTION: Harmful or fatal if swallowed. May cause gastrointestinal disturbances with dizziness
and central nervous system depression. If ingested, may cause depressed respiration. Ingestion may cause gastrointestinal
irritation, nausea, vomiting and diarrhea. Aspiration hazard if swallowed. Aspiration of material into the lungs due to vomiting can
cause chemical pneumonitis, which can be fatal.
CARCINOGENICITY: No Information
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated or prolonged exposure may cause irregular heartbeat and heart
failure as well as respiratory system, kidney, cardiovascular and liver damage. May cause kidney and liver damage as well as
developmental and reproductive toxicity. Prolonged or repeated inhalation of dust may cause lung damage. NOTICE: Reports have
associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.
Symptoms include: loss of memory, loss of intellectual ability and loss of coordination. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal. Overexposure or misuse of toluene can cause liver, kidney, and
brain damage as well as cardiac abnormalities. There have been cases of aplastic anemia from toluene in industrial exposures
(ACGIH, 1992). Increased coagulation time and reduced clotting factors have also been found, which are indicators of damage to the
bone marrow (Clayton & Clayton, 1994). n-Hexane exposure can cause nerve damage to arms and legs causing numbness of the
fingers and toes, effect may be permanent. Symptoms include: loss of memory, loss of intellectual ability and loss of coordination.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Inhalation, Skin Contact
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS-No.
67-64-1 Acetone 5250 mg/kg mouse >15688 mg/kg rabbit 50 mg/L Rat
110-54-3 n-Hexane 25000 mg/kg Rat 3000 mg/kg Rabbit > 31.86 mg/L Rat
68476-86-8 Hydrocarbon Propellant N.I. N.I. 1355 mg/L Rat
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
25038-32-8 S-i-s block coploymer N.I. N.I. N.I.
68003-51-0 Hydrocarbon N.I. N.I. N.I.
68527-25-3 Petroleum hydrocarbon resin N.I. N.I. N.I.
108-88-3 Toluene 2600 mg/kg Rat 12000 mg/kg Rabbit 12.5 mg/L Rat
79-20-9 Methyl acetate >6482 mg/kg Rat >5000 mg/kg Rabbit 49.2 mg/L Rabbit
N.I. = No Information
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SDS Number: 00030197004 Revision Date: 10/4/2018
12. Ecological Information
ECOLOGICAL INFORMATION: Ecological injuries are not known or expected under normal use.
13. Disposal Information
DISPOSAL INFORMATION: Residues and spilled material are hazardous waste due to ignitability. Contents under pressure.
Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex
and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. Do not flush into
surface water or sanitary sewer system. Do not empty into drains. Do not re-use empty containers. The container for this product
can present explosion or fire hazards, even when emptied. To avoid risk of injury, do not cut, puncture, or weld on or near this
container. Before disposing of containers, relieve container of any remaining product and pressure. Empty cylinders, once relieved
of all pressure, can be disposed of as non-hazardous waste.
14. Transport Information
SPECIAL TRANSPORT PRECAUTIONS: No Information
DOT UN/NA Number: UN1950
DOT Proper Shipping Name: Aerosols, flammable
DOT Technical Name: N.A.
DOT Hazard Class: 2.1 Flammable gas
Hazard SubClass: N.A.
Packing Group: N.A.
15. Regulatory Information
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
n-Hexane
Toluene
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b) components exist in this product.
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SDS Number: 00030197004 Revision Date: 10/4/2018
16. Other Information
Revision Date: 10/4/2018
Reason for revision: Revision Description Changed
Product Composition Changed
Substance and/or Product Properties Changed in Section(s):
01 - Product Information
02 - Hazards Identification
05 - Flammability Information
09 - Physical & Chemical Information
11 - Toxicological Information
14 - Transportation Information
15 - Regulatory Information
16 - Other Information
Revision Statement(s) Changed
Datasheet produced by: Regulatory Department
Supersedes Date: 1/12/2016
HMIS Ratings:
Health:
2 4 0 X
Flammability: Reactivity: Personal Protection:
VOC Less Water Less Exempt Solvent, g/L:
VOC as Defined by California Consumer Product Regulation, Wt/Wt%:
VOC Actual, Wt/Wt%: 38.3
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
497.4
VOC Material, g/L: 307
38.3
H220 Extremely flammable gas.
H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects.
H373 May cause damage to organs through prolonged or repeated exposure.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS07
GHS08
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
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SDS Number: 00030197004 Revision Date: 10/4/2018
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly
trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific
context of the intended use and (ii) determine if they are appropriate.
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SDS Number: 00030197004 Revision Date: 10/4/2018
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