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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date: 8/25/1998
Revision Date: 3/30/2016
Rev : 4
1 Identification of Substance
Product Identifier
Trade Name: Ball Pen Ink # 13194-01 Item #: 1886A Blue
Registration Number
The ingredients of this ink have been pre-registered according to 1907/2006/EC
(Reach)
Relevant identified uses of the substance or mixture and uses advised against
Currently no such applications are identified
Application of the Substance/the Preparation Ball Pen ink
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Chad Labs Corporation
128 Research Drive
Milford, CT 06460
Phone: (203) 877-3891
Fax: (203) 876-0578
www.chadlabs.com
Further Information Obtainable From:
Technical Service, A. Chugani
Phone: (203) 877-3891, ext. 13
Email: [email protected]
Emergency Telephone Number:
EMERGENCY Tel. No. for US and Canada:
(800) 535-5053 (INFOTRAC)
All other countries
001-352-323-3500 (INFOTRAC)
2 Hazards Indentification
Classification of the substance or mixture
Hazard Description:
Information Pertaining to Particular Dangers for Man and Environment:
Exposure limits in air
Health effects or risks from exposure: Non-hazardous
Symptoms of over exposure for each potential route of exposure:
Harmful if swallowed.
Irritating to skin
Irritating to eyes
Classification System:
The classification was made according to the latest editions of international
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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
substances lists and expanded upon from company and literature data.
NFPA Ratings (scale 0-4)
HMIS Ratings (scale 0-4)
3 Composition/Information on Ingredients
Chemical Characterization: Mixtures
Mixture, of the following substances: containing “Hazardous”, “non-hazardous”
substances and coloring agents. According to Regulations (EC) No. 1907/2006 In
addition Classification according to EU directives 67/548/EEC or 1999/45/EC
Description: Mixture of the substances listed below with non-hazardous additions.
Dangerous Components:
Chemical Name
Ethylene Glycol Monophenyl Ether 122-99-6 >= 40.0 - <= 55.0%
Diethylene Glycol Monophenyl Ether 104-68-7 >= 2.0 - <= 5.0%
Propylene Glycol 000057-55-6 >= 0.2- <= 5.0%
Special polyol Resin and Polymer NA & 9003-39-8 >= 15.0 - <= 25.0%
blend
Solvent Blue Dye 3468-11-9 >= 5.0 - <= 20.0%
Solvent violet Dye 1328-51-4 >= 1.0 - <= 10.0%
Proprietary pH buffering agent 102-60-3, 61791-14-8 >= 1.0 - <= 8.0%
Blend 6178846-3, 25322-68-3
Additional Information: For the wording of the listed risk phrases refer to section 16.
CAS Number Content (W/W)
4 First Aid Measures
Description of First Aid Measures
General Information:
Exposure limits in air.
Acute: None known
Chronic: None known
After Inhalation:
Little hazard exists at room temperature. Remove individual to an uncontaminated
atmosphere and administer oxygen or artificial respiration as needed.
After Skin Contact:
No expected absorption through skin. Remove contaminated clothing and wash affected
area with plenty of water and soap. Colors the skin and may cause drying.
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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
After Eye Contact:
Flush eyes for at least 15 minutes with large amounts of water. Get medical attention
if eye pain persists.
After Swallowing:
No expected issues. Call a physician.
Information for Doctor:
Most important symptoms and affects, both acute and delayed
No further relevant information is available.
Indication of any immediate medical attention and special treatment needed
Do not induce vomiting unless directed to do so by medical personnel.
5 Fire Fighting Measures
Extinguishing Media
Suitable Extinguishing Agents: Use fire fighting measures that suit the environment.
Water, foam, carbon dioxide are effective agents.
Special hazards arising from the substance or mixture: No further relevant
information is available.
Advice for Fire Fighters
Protective Equipment: Fire fighters should be fitted with self-contained breathing
apparatus to avoid inhalation of products of combustion.
6 Accidental Release Measures
Personal precautions, protective equipment and, emergency procedures: Not required.
Environmental Precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/surface or ground water.
Methods and Material for Containment and Cleaning Up:
Soak up all spills on paper, sawdust, earth or other suitable absorbents and scoop
into closed containers. Wash down spill area with plenty of water.
Reference to Other Sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and Storage
Handling:
Precautions for Safe Handling:
Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols.
Local exhaust as needed to remove fumes if any.
Information about fire and explosion protection: No special measure required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by Storerooms and Receptacles: Do not store outside. Keep
container closed when not in use.
Information about Storage in One Common Storage Facility: Not required.
Further Information about Storage Conditions: Do not expose to extreme temperatures.
Specific End Use(s): No further relevant information is available.
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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
8 Exposure Controls/Personal Protection
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Safety Data Sheet
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Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
Additional Information about Design of Technical Facilities: No further data; see
item 7.
Control Parameters
Components with Limit Values that Require Monitoring at the Workplace: None.
Additional Information: The lists that were valid during the creation were used as
basis.
Exposure Controls
Personal Protection Equipment:
General Protective and Hygienic Measures:
Keep away from foodstuffs, beverages, and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Respiratory Protection:
Necessary only if the ink is heated. Use an approved respirator for organic vapors
and fumes.
Protection of Hands:
The glove material has to be impermeable and resistant to the product/the
substance/the preparation.
Selection of the glove material on consideration of the penetration times, rates of
diffusion and the degradation.
Material of Gloves:
The selection of the suitable gloves does not only depend on the material, but also
on further marks of quality and varies from manufacturer to manufacturer. As the
product is a preparation of several substances, the resistance of the glove material
cannot be calculated in advance and has therefore to be checked prior to the
application. Medical quality plastic gloves are used in the making of the ink.
Penetration Time of Glove Material:
The exact break through time has to be found out by the manufacturer of the
protective gloves and has to be observed.
Eye Protection:
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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
9 Physical and Chemical Properties
Information on Basic Physical and Chemical Properties
General Information
Appearance:
Form: Thick Blue paste
Color: Blue
Odor: Mild
Odor Threshold: Not determined
Important Information on Protection of Health and
Environment and on Safety Not Applicable
pH @ 25
Change in Condition
Flash Point: > 250
Flammable limits in air Lower: 0.95% (V) Literature
Upper: No tested data available
Ignition Temperature: 923
Decomposition Temperature: Not determined
Self-Igniting: No
Danger of Explosion: None known
Vapor Pressure: 0.004 MMHg @25
Density: Not determined
Relative Density: Not determined
Vapor Density: (Air=1) 4.77 @25
Evaporation Rate (Butyl Acetate = 1): Approx. 0.005
°
C: 7.5 ± 1
Melting Point/Melting Range: N/A
°
°
F
F
°
F
Boiling Point/Boiling Range: > 471
°
C
°
C
Solubility in/Miscibility with Water: 2.5%
Segregation Coefficient (n-octanol/water): Not determined
Specific Gravity: (Water = 1) 1.130 - 1.190
Surface Tension @ 25
Viscosity:
Dynamic @ 25
Kinematic: Not determined
°
C: 35 Min
°
C: 9,500 – 12,500 CPS
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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
Other Information No further relevant information available
10 Stability and Reactivity
Reactivity
Chemical Stability
Thermal Decomposition/Conditions to be Avoided:
No thermal decomposition known. No conditions to be avoided. Avoid strong oxidizing
agent materials.
Possibility of Hazardous Reactions: This ink is stable. There are no known dangerous
reactions.
Conditions to Avoid: No further relevant information available.
Incompatible Materials: No further relevant information available.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxides and oxides of nitrogen. No hazardous polymerization
will occur.
11 Toxicological Information
Information on Toxicological Effects
Acute Toxicity:
None known.
Primary Irritant Effect:
On the Skin: Irritant to skin.
On the Eyes: Irritant to eyes.
Sensitization: No sensitizing effects known.
Additional Toxicological Information:
Harmful
Irritant
12 Ecological Information
Toxicity
Aquatic Toxicity: Toxic for any animals/fish, etc.
Persistance and Degradability: No further relevant information available.
Behavior in Environmental Systems: No further relevant information available.
Bioacummulative Potential: No further relevant information available.
Mobility in Soil: No further relevant information available.
Additional Ecological Information:
General Notes:
Slightly hazardous in water. Do not allow product to reach ground water, water
course or sewage system, even in small quantities. Danger to drinking water and also
poisonous for fish and plankton in water bodies. Toxic for aquatic organisms.
Results of PBT and vPvB Assessment
PBT: Not applicable.
vPvB: Not applicable.
Other Adverse Effects: No further relevant information available.
13 Disposal Considerations
Waste Treatment Methods
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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to
reach sewage system. Remove to an approved landfill site. Dispose of all wastes in
accordance with federal, state, and local regulations.
European Waste Catalog
Uncleaned Packaging:
Recommendation: Disposal must be made according to official regulations.
14 Transport Information
This material is not flammable or hazardous.
Shipping code: 55
Land Transport ADR/RID (cross-border)
ADR/RID Class:
Maritime Transport IMDG
IMDG Class:
Maritime Pollutant: No
Not classified as a dangerous good under transport regulations (Non-Hazardous)
Air Transport ICAO-TI and IATA-DGR
IATA/ICAO Class:
Packaging Group:
Not classified as a dangerous good under transport regulations (Non-hazardous)
Special Precautions for User: Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not
applicable.
15 Regulatory Information
Safety, Health, and Environmental Regulations/Legislation Specific for the Substance
or Mixture
National Regulations:
Technical Instructions (air):
Water Hazard Class: Water hazard class (self assessment): hazardous for water.
Chemical Safety Assessment: A Chemical Safety Assessment has not been carried out.
Sara
Section 355 (extremely hazardous substances):
None of the ingredients are listed.
Section 313 (specific toxic chemical listings):
None of the ingredients are listed.
TSCA (Toxic Substances Control Act):
None of the ingredients are listed.
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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
Chemicals Known to Cause Cancer.
Proposition 65
None of the ingredients are listed.
Chemicals Known to Cause Reproductive Toxicity for Females:
None of the ingredients listed.
Chemicals Known to Cause Reproductive Toxicity for Males:
None of the ingredients listed.
Chemicals Known to Cause Developmental Toxicity:
None of the ingredients listed.
Cancergenity Categories
EPA (Environmental Protection Agency)
None of the ingredients are listed.
IARC (International Agency for Research on Cancer)
None of the ingredients are listed.
NTP (National Toxicology Program)
None of the ingredients are listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients are listed.
MAK (German Maximum Workplace Concentration)
None of the ingredients are listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients are listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients are listed.
16 Other Information
Product Related Hazard Information:
The product has been classified and marked in accordance with directives on hazardous
materials.
Risk Phrases:
Harmful if swallowed.
Irritating to skin.
Risk of serious damage to eyes.
Toxic to aquatic organisms.
Safety Phrases:
Do not breathe vapor.
In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
Wear suitable protective clothing, gloves and eye/face protection.
Use appropriate container to avoid environmental contamination.
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Safety Data Sheet
acc. to 1907/2006/EC, Article 31
Issue Date 8/25/1998
Revision Date 3/30/16
Rev.: 4
Ball Pen Ink # 13194-01 Item #: 1886A Blue
All information, recommendations and suggestions appearing herein concerning this
product are based upon data obtained from the manufacturer and/or recognized
technical sources. However, Chad Labs Corporation makes no warranty, representation
or guarantee as to the accuracy, sufficiency or completeness of the material set
forth herein. It is the user’s responsibility to determine the safety, toxicity and
suitability of his/her own use, handling and disposal of the product. Additional
product literature may be available upon request. Since actual use by others is
beyond our control, neither warranty, express or implied, is made by Chad Labs
Corporation as to the effects of such use, the results to be obtained or the safety
and toxicity of the product nor does Chad Labs Corporation assume any liability
arising out of use by others of the product referred herein. The data in this MSDS
relate only to the specific material designated herein and do not relate to use in
combination with any other material or in any process.
End of MSDS
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