
S A F E T Y D A T A S H E E T
C
RL HI-SHEEN GLASS CLEANERProduct identifier
08-24-2018
Revision date
C R LAURENCE CO INC
2503 E. VERNON AVENUE
LOS ANGELES, CA 90058 United States
Company information
General Assistance 800-421-6144
Company phone
1-866-836-8855
Emergency telephone US
1-952-852-4646
Emergency telephone outside
US
04
Version #
08-22-2018
Supersedes date
Cleaner
Recommended use
None known.
Recommended restrictions
2. Hazard(s) identification
Category 1Flammable aerosols
Physical hazards
Not classified.
Health hazards
Not classified.
OSHA defined hazards
Label elements
Signal word
Danger
Hazard statement
Extremely flammable aerosol.
Precautionary statement
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open
flame or other ignition source. Pressurized container: Do not pierce or burn, even after use.
Response
Wash hands after handling.
Storage
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Disposal
Not available.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information
None.
3. Composition/information on ingredients
Mixtures
CAS number %Common name and synonymsChemical name
111-76-2
2.5 - 10
2-Butoxyethanol
106-97-8
1 - 2.5
Butane
64-17-5
1 - 2.5
Ethyl Alcohol
1336-21-6
0.1 - 1
Ammonium Hydroxide
74-98-6
0.1 - 1
Propane
1. Identification
1000000970
P
roduct number
United States
C
Do not pierce or burn, even after use.
R
CRL HI-SHEEN GLASS CLEANER
Product #: 1000000970 Version #: 04 Revision date: 08-24-2018 Issue date: 09-15-2015
S
CRL Catalog Number 3371100
c r l a u r e n c e . c o m
SDS1145_3371100_9/18
Page 1 of 11

4. First-aid measures
Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if
v
ictim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped
w
ith a one-way valve or other proper respiratory medical device. Call a physician or Poison Control
Center immediately. Call a physician if symptoms develop or persist.
Inhalation
T
ake off immediately all contaminated clothing. Call a physician or Poison Control Center
immediately. Get medical attention if irritation develops and persists.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO
NOT delay irrigation or attempt to remove the lens. Call a physician or Poison Control Center
immediately.
Eye contact
I
n the unlikely event of swallowing contact a physician or poison control center. Rinse mouth
t
horoughly. Never give anything by mouth to a victim who is unconscious or is having convulsions.
Do not induce vomiting without advice from poison control center.
Ingestion
D
irect contact with eyes may cause temporary irritation.
Most important
symptoms/effects, acute and
delayed
Treat symptomatically. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim
under observation. Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
In case of shortness of breath, give oxygen. Immediate medical attention is required. Ensure that
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. Keep victim under
observation. Keep victim warm.
General information
5. Fire-fighting measures
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
Unsuitable extinguishing
media
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
During fire, gases hazardous to health may be formed.
Specific hazards arising from
the chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective
clothing will only provide limited protection.
Special protective equipment
and precautions for firefighters
Move containers from fire area if you can do so without risk. Containers should be cooled with
water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials. Move
containers from fire area if you can do so without risk. In the event of fire and/or explosion do not
breathe fumes.
Specific methods
Extremely flammable aerosol.
General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
clean-up. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so without
risk. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Move the cylinder to a safe and open area if the leak is irreparable. Keep combustibles (wood,
paper, oil, etc.) away from spilled material. Prevent entry into waterways, sewer, basements or
confined areas. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or
earth and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. For waste disposal, see section 13 of the SDS. This material and
its container must be disposed of as hazardous waste.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.
Environmental precautions
C A T . N O . 3 3 7 1 1 0 0
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7. Handling and storage
May be ignited by open flame. Pressurized container: Do not pierce or burn, even after use. Do
n
ot use if spray button is missing or defective. Do not spray on a naked flame or any other
incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not
cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of
ignition. All equipment used when handling the product must be grounded. Do not re-use empty
containers. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Use only in
well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial
hygiene practices.
P
recautions for safe handling
Level 1 Aerosol.
Keep locked up. Pressurized container. Protect from sunlight and do not expose to temperatures
exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open
flame, heat or other sources of ignition. This material can accumulate static charge which may
cause spark and become an ignition source. Store in a well-ventilated place. Store away from
incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 240 mg/m32-Butoxyethanol (CAS
111-76-2)
50 ppm
PEL 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
PEL 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 20 ppm2-Butoxyethanol (CAS
111-76-2)
STEL 1000 ppmButane (CAS 106-97-8)
STEL 1000 ppmEthyl Alcohol (CAS 64-17-5)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
TWA 24 mg/m32-Butoxyethanol (CAS
111-76-2)
5 ppm
TWA 1900 mg/m3Butane (CAS 106-97-8)
800 ppm
TWA 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
TWA 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
Biological limit values
ACGIH Biological Exposure Indices
ValueComponents Determinant Specimen Sampling Time
200 mg/g Butoxyacetic
acid (BAA),
Creatinine in
urine
*
2-Butoxyethanol (CAS
111-76-2)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
2-Butoxyethanol (CAS 111-76-2) Skin designation applies.
C A T . N O . 3 3 7 1 1 0 0
Page 3 of 11

US - Tennessee OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
U
S. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
Not available.
Appropriate engineering
controls
I
ndividual protection measures, such as personal protective equipment
Wear tight-fitting goggles or face shield. Wear safety glasses with side shields (or goggles).
Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
s
upplier.
Hand protection
W
ear suitable protective clothing.
Other
If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an
air-supplied respirator.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.
Thermal hazards
Do not get in eyes. Do not get this material in contact with skin. When using do not smoke. Avoid
contact with skin. Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing
and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.
Physical state
Aerosol.
Form
Not available.
Color
Not available.
Odor
Odor threshold
Not available.
pH
Not available.
Melting point/freezing point
Not available.
Initial boiling point and boiling
range
212 °F (100 °C) estimated
Flash point
-156.0 °F (-104.4 °C) Propellant estimated
Evaporation rate
Not available.
Not applicable.
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not available.
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
40 - 50 @20C
Vapor density
Not available.
Relative density
Not available.
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
Not available.
C A T . N O . 3 3 7 1 1 0 0
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Other information
Not explosive.
Explosive properties
Flammability class
F
lammable IB estimated
Heat of combustion (NFPA
30B)
2.53 kJ/g estimated
Not oxidizing.
Oxidizing properties
Specific gravity
0.971 estimated
VOC (Weight %)
7.73 % estimated
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Reactivity
Risk of ignition.
Chemical stability
Hazardous polymerization does not occur.
Possibility of hazardous
reactions
Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Conditions to avoid
Strong oxidizing agents. Do not mix with other chemicals.
Incompatible materials
No hazardous decomposition products are known.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
No adverse effects due to inhalation are expected.
Skin contact
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.
Direct contact with eyes may cause temporary irritation.
Expected to be a low ingestion hazard.
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Test ResultsProduct Species
CRL HI-SHEEN GLASS CLEANER
Dermal
Acute
LD50 Rat 8100 mg/kg
Inhalation
LC50 Rat 68 mg/l/4h
Test ResultsComponents Species
2-Butoxyethanol (CAS 111-76-2)
Dermal
Acute
LD50 Guinea pig 7.3 ml/kg, 4 Days
0.23 ml/kg, 24 Hours
Rabbit 435 mg/kg, 24 Hours
0.68 ml/kg, 24 Hours
0.63 ml/kg
Rat > 2000 mg/kg, 24 Hours
Inhalation
LC50 Rabbit 400 ppm, 7 Hours
Rat 450 ppm, 4 Hours
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Test ResultsComponents Species
Oral
L
D100 Rabbit 695 mg/kg
L
D50 Dog > 695 mg/kg
Guinea pig 1414 mg/kg
Mouse 1519 mg/kg
R
at 1746 mg/kg
Butane (CAS 106-97-8)
I
nhalation
A
cute
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
Ethyl Alcohol (CAS 64-17-5)
Inhalation
Acute
LC50 Cat 85.41 mg/l, 4.5 Hours
43.68 mg/l, 6 Hours
Mouse > 60000 ppm
79.43 mg/l, 134 Minutes
Rat > 115.9 mg/l, 4 Hours
51.3 mg/l, 6 Hours
Oral
LD50 Monkey 6000 mg/kg
Mouse 10500 ml/kg
Pig > 5000 mg/kg
Rat 10470 mg/kg
7800 ml/kg
Propane (CAS 74-98-6)
Inhalation
Acute
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
* Estimates for product may be based on additional component data not shown.
658 mg/l/4h
Prolonged skin contact may cause temporary irritation.
Skin corrosion/irritation
Harmful in contact with eyes.
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Not a respiratory sensitizer.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Hazardous by OSHA criteria. Hazardous by WHMIS criteria. Cancer hazard.
IARC Monographs. Overall Evaluation of Carcinogenicity
2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
C A T . N O . 3 3 7 1 1 0 0
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US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Hazardous by OSHA criteria. Can cause adverse reproductive effects - such as birth defects,
miscarriages, or infertility.
Reproductive toxicity
S
pecific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity repeated exposure
Not classified.
Not an aspiration hazard.
Chronic effects
Hazardous by WHMIS criteria. May be harmful if absorbed through skin.
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.
Prolonged or repeated exposure may cause lung injury.
Reproductive toxicity.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
Product Test ResultsSpecies
CRL HI-SHEEN GLASS CLEANER
Aquatic
EC50Crustacea 16068 mg/L, 48 HoursDaphnia
LC50Fish 928 mg/L, 96 HoursFish
Components Test ResultsSpecies
2-Butoxyethanol (CAS 111-76-2)
Aquatic
LC50Fish 1250 mg/l, 96 hoursInland silverside (Menidia beryllina)
Ammonium Hydroxide (CAS 1336-21-6)
Aquatic
EC50Crustacea 0.66 mg/L, 48 HoursDaphnia
LC50Fish 15 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis)
Ethyl Alcohol (CAS 64-17-5)
Aquatic
EC50Crustacea 7700 - 11200 mg/l, 48 hoursWater flea (Daphnia magna)
* Estimates for product may be based on additional component data not shown.
LC50Fish > 100.1 mg/l, 96 hoursFathead minnow (Pimephales promelas)
No data is available on the degradability of this product.
Persistence and degradability
No data available.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Butoxyethanol 0.83
Butane 2.89
Ethyl Alcohol -0.31
Propane 2.36
No data available.
Mobility in soil
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents
under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance
with local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.
Local disposal regulations
C A T . N O . 3 3 7 1 1 0 0
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C A T . N O . 3 3 7 1 1 0 0
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
e
mptied. Empty containers should be taken to an approved waste handling site for recycling or
d
isposal. Do not re-use empty containers.
Contaminated packaging
14. Transport information
D
OT
UN1950
UN number
Aerosols, flammable
UN proper shipping name
2.1
Class
Transport hazard class(es)
-
Subsidiary risk
2.1
Label(s)
Not applicable.
Packing group
Read safety instructions, SDS and emergency procedures before handling.
Special precautions for user
N82
Special provisions
306
Packaging exceptions
None
Packaging non bulk
None
Packaging bulk
This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity.
Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond
mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20
and may be used now in place of the "Consumer Commodity ORM-D" marking.
IATA
UN1950
UN number
Aerosols, flammable
UN proper shipping name
2.1
Class
Transport hazard class(es)
-
Subsidiary risk
2.1
Label(s)
Not applicable.
Packing group
No.
Environmental hazards
10L
ERG Code
Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Special precautions for user
Allowed with restrictions.
Passenger and cargo
aircraft
Other information
Allowed with restrictions.
Cargo aircraft only
LTD QTY
Packaging Exceptions
IMDG
UN1950
UN number
AEROSOLS
UN proper shipping name
2.1
Class
Transport hazard class(es)
-
Subsidiary risk
None
Label(s)
Not applicable.
Packing group
No.
Marine pollutant
Environmental hazards
F-D, S-U
EmS
Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Special precautions for user
LTD QTY
Packaging Exceptions
Not applicable.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
Page 8 of 11

D
OT
IATA; IMDG
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Ammonium Hydroxide (CAS 1336-21-6) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
No
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
2-Butoxyethanol 111-76-2 2.5 - 10
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
Not regulated.
Safe Drinking Water Act
(SDWA)
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
C A T . N O . 3 3 7 1 1 0 0
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C A T . N O . 3 3 7 1 1 0 0
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
US. Massachusetts RTK - Substance List
2-Butoxyethanol (CAS 111-76-2)
Ammonium Hydroxide (CAS 1336-21-6)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. New Jersey Worker and Community Right-to-Know Act
2-Butoxyethanol (CAS 111-76-2)
Ammonium Hydroxide (CAS 1336-21-6)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Butoxyethanol (CAS 111-76-2)
Ammonium Hydroxide (CAS 1336-21-6)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Rhode Island RTK
Ammonium Hydroxide (CAS 1336-21-6)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
09-15-2015
Issue date
08-24-2018
Revision date
Version #
04
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Disclaimer
Page 10 of 11

C A T . N O . 3 3 7 1 1 0 0
Hazard(s) identification: Hazard statement
Hazard(s) identification: Prevention
Hazard(s) identification: Response
Hazard(s) identification: Storage
Physical & Chemical Properties: Multiple Properties
Revision information
Page 11 of 11