S A F E T Y D A T A S H E E T
C
RL HI-SHEEN GLASS CLEANERProduct identifier
08-24-2018
Revision date
C R LAURENCE CO INC
2503 E. VERNON AVENUE
LOS ANGELES, CA 90058 United States
Company information
General Assistance 800-421-6144
Company phone
1-866-836-8855
Emergency telephone US
1-952-852-4646
Emergency telephone outside
US
04
Version #
08-22-2018
Supersedes date
Cleaner
Recommended use
None known.
Recommended restrictions
2. Hazard(s) identification
Category 1Flammable aerosols
Physical hazards
Not classified.
Health hazards
Not classified.
OSHA defined hazards
Label elements
Signal word
Danger
Hazard statement
Extremely flammable aerosol.
Precautionary statement
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open
flame or other ignition source. Pressurized container: Do not pierce or burn, even after use.
Response
Wash hands after handling.
Storage
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Disposal
Not available.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information
None.
3. Composition/information on ingredients
Mixtures
CAS number %Common name and synonymsChemical name
111-76-2
2.5 - 10
2-Butoxyethanol
106-97-8
1 - 2.5
Butane
64-17-5
1 - 2.5
Ethyl Alcohol
1336-21-6
0.1 - 1
Ammonium Hydroxide
74-98-6
0.1 - 1
Propane
1. Identification
1000000970
P
roduct number
United States
C
Do not pierce or burn, even after use.
R
CRL HI-SHEEN GLASS CLEANER
Product #: 1000000970 Version #: 04 Revision date: 08-24-2018 Issue date: 09-15-2015
S
CRL Catalog Number 3371100
c r l a u r e n c e . c o m
SDS1145_3371100_9/18
Page 1 of 11
4. First-aid measures
Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if
v
ictim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped
w
ith a one-way valve or other proper respiratory medical device. Call a physician or Poison Control
Center immediately. Call a physician if symptoms develop or persist.
Inhalation
T
ake off immediately all contaminated clothing. Call a physician or Poison Control Center
immediately. Get medical attention if irritation develops and persists.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO
NOT delay irrigation or attempt to remove the lens. Call a physician or Poison Control Center
immediately.
Eye contact
I
n the unlikely event of swallowing contact a physician or poison control center. Rinse mouth
t
horoughly. Never give anything by mouth to a victim who is unconscious or is having convulsions.
Do not induce vomiting without advice from poison control center.
Ingestion
D
irect contact with eyes may cause temporary irritation.
Most important
symptoms/effects, acute and
delayed
Treat symptomatically. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim
under observation. Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
In case of shortness of breath, give oxygen. Immediate medical attention is required. Ensure that
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. Keep victim under
observation. Keep victim warm.
General information
5. Fire-fighting measures
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
Unsuitable extinguishing
media
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
During fire, gases hazardous to health may be formed.
Specific hazards arising from
the chemical
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective
clothing will only provide limited protection.
Special protective equipment
and precautions for firefighters
Move containers from fire area if you can do so without risk. Containers should be cooled with
water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials. Move
containers from fire area if you can do so without risk. In the event of fire and/or explosion do not
breathe fumes.
Specific methods
Extremely flammable aerosol.
General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
clean-up. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so without
risk. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Move the cylinder to a safe and open area if the leak is irreparable. Keep combustibles (wood,
paper, oil, etc.) away from spilled material. Prevent entry into waterways, sewer, basements or
confined areas. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or
earth and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. For waste disposal, see section 13 of the SDS. This material and
its container must be disposed of as hazardous waste.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.
Environmental precautions
C A T . N O . 3 3 7 1 1 0 0
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7. Handling and storage
May be ignited by open flame. Pressurized container: Do not pierce or burn, even after use. Do
n
ot use if spray button is missing or defective. Do not spray on a naked flame or any other
incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not
cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of
ignition. All equipment used when handling the product must be grounded. Do not re-use empty
containers. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Use only in
well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial
hygiene practices.
P
recautions for safe handling
Level 1 Aerosol.
Keep locked up. Pressurized container. Protect from sunlight and do not expose to temperatures
exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open
flame, heat or other sources of ignition. This material can accumulate static charge which may
cause spark and become an ignition source. Store in a well-ventilated place. Store away from
incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 240 mg/m32-Butoxyethanol (CAS
111-76-2)
50 ppm
PEL 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
PEL 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 20 ppm2-Butoxyethanol (CAS
111-76-2)
STEL 1000 ppmButane (CAS 106-97-8)
STEL 1000 ppmEthyl Alcohol (CAS 64-17-5)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
TWA 24 mg/m32-Butoxyethanol (CAS
111-76-2)
5 ppm
TWA 1900 mg/m3Butane (CAS 106-97-8)
800 ppm
TWA 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
TWA 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
Biological limit values
ACGIH Biological Exposure Indices
ValueComponents Determinant Specimen Sampling Time
200 mg/g Butoxyacetic
acid (BAA),
with hydrolysis
Creatinine in
urine
*
2-Butoxyethanol (CAS
111-76-2)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
2-Butoxyethanol (CAS 111-76-2) Skin designation applies.
C A T . N O . 3 3 7 1 1 0 0
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US - Tennessee OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
U
S. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
Not available.
Appropriate engineering
controls
I
ndividual protection measures, such as personal protective equipment
Wear tight-fitting goggles or face shield. Wear safety glasses with side shields (or goggles).
Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
s
upplier.
Hand protection
W
ear suitable protective clothing.
Other
If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an
air-supplied respirator.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.
Thermal hazards
Do not get in eyes. Do not get this material in contact with skin. When using do not smoke. Avoid
contact with skin. Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing
and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.
Physical state
Aerosol.
Form
Not available.
Color
Not available.
Odor
Odor threshold
Not available.
pH
Not available.
Melting point/freezing point
Not available.
Initial boiling point and boiling
range
212 °F (100 °C) estimated
Flash point
-156.0 °F (-104.4 °C) Propellant estimated
Evaporation rate
Not available.
Not applicable.
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not available.
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
40 - 50 @20C
Vapor density
Not available.
Relative density
Not available.
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
Not available.
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