CRC SL3190 User Manual

Page 1
SAFETY DATA SHEET
www.crcindustries.com
1. Identification
Sta-Plex™ Extreme Pressure Premium Red GreaseProduct identifier
Other means of identification
Product code
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
SL3190, SL3191, SL3195, SL3197
Lubricating grease
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
Not classified.
Category 2ASerious eye damage/eye irritation
Category 1Sensitization, skin
Not classified.
Not classified.
Warning
May cause an allergic skin reaction. Causes serious eye irritation.
Avoid breathing vapors. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. Wear eye/face protection.
If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Wash contaminated clothing before reuse.
Store away from incompatible materials.
Dispose of contents/container in accordance with local/regional/national regulations.
3. Composition/information on ingredients
Mixtures
heavy naphthenic
Material name: Sta-Plex™ Extreme Pressure Premium Red Grease
SL3190, SL3191, SL3195, SL3197 Version #: 01 Issue date: 07-30-2015
CAS number %Common name and synonymsChemical name
64742-52-5Distillates (petroleum), hydrotreated
60 - 70
SDS US
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CAS number %Common name and synonymsChemical name
64742-65-0Distillates (petroleum),
solvent-dewaxed heavy paraffinic
471-34-1Calcium carbonate
68649-42-3Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts
in-1-yl)ethanol
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
95-38-52-(2-cis-Heptadec-8-enyl-2-imidazol
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Move to fresh air. Provide oxygen or artificial respiration if needed. Call a physician if symptoms develop or persist.
Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Rinse mouth. Never give anything by mouth to a victim who is unconscious or is having convulsions. Do not induce vomiting without advice from poison control center. Get medical attention if symptoms occur.
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction. Dermatitis. Rash.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.
20 - 30
5 - 10
3 - 5
1 - 3
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
General fire hazards
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
During fire, gases hazardous to health may be formed.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
The product is immiscible with water and will spread on the water surface.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water.
Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions
Material name: Sta-Plex™ Extreme Pressure Premium Red Grease
SL3190, SL3191, SL3195, SL3197 Version #: 01 Issue date: 07-30-2015
Avoid discharge into drains, water courses or onto the ground. Contact local authorities in case of spillage to drain/aquatic environment.
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7. Handling and storage
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Provide adequate ventilation. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. For product usage instructions, please see the product label.
Store in a cool, dry place out of direct sunlight. Keep container tightly closed. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
471-34-1)
hydrotreated heavy naphthenic (CAS 64742-52-5)
solvent-dewaxed heavy paraffinic (CAS 64742-65-0)
hydrotreated heavy naphthenic (CAS 64742-52-5)
solvent-dewaxed heavy paraffinic (CAS 64742-65-0)
Type
PEL 5 mg/m3 Respirable fraction.Calcium carbonate (CAS
PEL 5 mg/m3 Mist.Distillates (petroleum),
PEL 5 mg/m3 Mist.Distillates (petroleum),
Type
TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),
TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),
ValueComponents
Form
15 mg/m3 Total dust.
2000 mg/m3 500 ppm
2000 mg/m3 500 ppm
ValueComponents
Form
Type
TWA 5 mg/m3 Respirable.Calcium carbonate (CAS
471-34-1)
Ceiling 1800 mg/m3Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5)
STEL 10 mg/m3 Mist.
TWA 5 mg/m3 Mist.
Ceiling 1800 mg/m3Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0)
STEL 10 mg/m3 Mist.
TWA 5 mg/m3 Mist.
Biological limit values
Appropriate engineering controls
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Material name: Sta-Plex™ Extreme Pressure Premium Red Grease
SL3190, SL3191, SL3195, SL3197 Version #: 01 Issue date: 07-30-2015
Wear protective gloves such as: Latex. Rubber.
ValueComponents
Form
10 mg/m3 Total
SDS US
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Other
workplace.
Inhalation
Respiratory protection
Thermal hazards
General hygiene considerations
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.
Wear appropriate thermal protective clothing, when necessary.
Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Solid.
Grease.
Red.
Mild petroleum.
Not available.
Not available.
Not available.
680 °F (360 °C) estimated
475 °F (246.1 °C) Cleveland Open Cup
Slow.
Not available.
Not available.
Not available.
Not available.
Not available.
0.9
Insoluble.
Not available.
500 °F (260 °C) estimated
Not available.
> 21 mm²/s (104 °F (40 °C))
Not available.
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials.
Strong oxidizing agents.
Carbon oxides. Sulfur oxides. Metal oxides.
11. Toxicological information
Information on likely routes of exposure
Prolonged inhalation may be harmful.
Material name: Sta-Plex™ Extreme Pressure Premium Red Grease
SL3190, SL3191, SL3195, SL3197 Version #: 01 Issue date: 07-30-2015
SDS US
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Skin contact
May cause an allergic skin reaction.
Eye contact
Ingestion
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Chronic effects
Acute
Causes serious eye irritation.
Can cause stomach ache and vomiting.
Symptoms related to the physical, chemical and toxicological characteristics
Prolonged or excessive inhalation may cause respiratory tract irritation. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity
May cause an allergic skin reaction. Expected to be a low hazard for usual industrial or commercial handling by trained personnel.
Sta-Plex™ Extreme Pressure Premium Red Grease
Acute
Dermal
LD50 Rabbit 2632 mg/kg estimated
Inhalation
LC50 Rat 60 mg/l estimated
Oral
LD50 Rat 5472 mg/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Prolonged skin contact may cause temporary irritation.
Causes serious eye irritation.
irritation
Not a respiratory sensitizer.
Skin sensitization
Germ cell mutagenicity
May cause an allergic skin reaction.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not available.
US. National Toxicology Program (NTP) Report on Carcinogens
Not available.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Not an aspiration hazard.
Prolonged exposure may cause chronic effects.
Test ResultsProduct Species
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
Sta-Plex™ Extreme Pressure Premium Red Grease
Aquatic
Components Test ResultsSpecies
Calcium carbonate (CAS 471-34-1)
Aquatic
Material name: Sta-Plex™ Extreme Pressure Premium Red Grease
SL3190, SL3191, SL3195, SL3197 Version #: 01 Issue date: 07-30-2015
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
EC50Crustacea 32.6798 mg/l, 48 hours estimatedDaphnia
LC50Fish 179.3869 mg/l, 96 hours estimatedFish
LC50Fish > 56000 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis)
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Components Test ResultsSpecies
Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5)
Aquatic
EC50Crustacea 1000 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 5000 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
Aquatic
EC50Crustacea 1 - 5 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 1 - 5 mg/l, 96 hoursFathead minnow (Pimephales promelas)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
Not readily biodegradable.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from residues / unused products
Hazardous waste code
Contaminated packaging
This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 – 261.33). Empty containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations.
Not regulated.
Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
CERCLA Hazardous Substance List (40 CFR 302.4)
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Listed.
Material name: Sta-Plex™ Extreme Pressure Premium Red Grease
SL3190, SL3191, SL3195, SL3197 Version #: 01 Issue date: 07-30-2015
SDS US
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Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
Food and Drug
Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312 Hazard categories
Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No
SARA 302 Extremely
No
hazardous substance
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))
Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0)
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
Calcium carbonate (CAS 471-34-1) Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3) Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0)
US. Massachusetts RTK - Substance List
Calcium carbonate (CAS 471-34-1)
US. Pennsylvania Worker and Community Right-to-Know Law
Calcium carbonate (CAS 471-34-1)
US. Rhode Island RTK
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
Not determined
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
VOC content (CA)
VOC content (OTC)
Not regulated
Not determined
Not determined
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
Material name: Sta-Plex™ Extreme Pressure Premium Red Grease
SL3190, SL3191, SL3195, SL3197 Version #: 01 Issue date: 07-30-2015
SDS US
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Country(s) or region Inventory name On inventory (yes/no)*
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
NFPA ratings
07-30-2015
Allison Cho
01
Not available.
Health: 1 Flammability: 1 Physical hazard: 0 Personal protection: B
Health: 1 Flammability: 1 Instability: 0
1
01
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
Disclaimer
The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
Material name: Sta-Plex™ Extreme Pressure Premium Red Grease
SL3190, SL3191, SL3195, SL3197 Version #: 01 Issue date: 07-30-2015
SDS US
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