CRC SL3155 User Manual

Page 1
SAFETY DATA SHEET
www.crcindustries.com
1. Identification
Product identifier Super White™ Multi-Purpose Lithium Grease
Other means of identification
Product code
Recommended use
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
SL3150, SL3151, SL3155, SL3159, SL3360, SL3361
Multi-purpose grease
None known.
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
Not classified.
Category 1Sensitization, skin
Category 3Hazardous to the aquatic environment, acute
hazard
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.
Warning
May cause an allergic skin reaction. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.
Avoid breathing vapors. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. Avoid release to the environment.
If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Wash contaminated clothing before reuse.
Store away from incompatible materials.
Dispose of contents/container in accordance with local/regional/national regulations.
None known.
3. Composition/information on ingredients
Mixtures
Material name: Super White™ Multi-Purpose Lithium Grease
SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015
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CAS number %Chemical name Common name and synonyms
64742-52-5Distillates (petroleum), hydrotreated
heavy naphthenic
1314-13-2Zinc oxide
57855-77-3Calcium
bis(dinonylnaphthalenesulphonate)
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing is difficult, trained personnel should give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Call a physician if symptoms develop or persist.
Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Continue rinsing. Get medical attention if irritation develops and persists.
Rinse mouth. Drink 1 or 2 glasses of water. Never give anything by mouth to a victim who is unconscious or is having convulsions. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. If ingestion of a large amount does occur, call a poison control center immediately.
Irritation of eyes and mucous membranes. May cause an allergic skin reaction. Rash. Skin irritation. Dermatitis.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.
80 - 90
3 - 5
< 1
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
General fire hazards
Use fire-extinguishing media appropriate for surrounding materials.
None known.
During fire, gases hazardous to health may be formed.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
The product is immiscible with water and will spread on the water surface. Stop the flow of material, if this is without risk. Collect spill using a vacuum cleaner with a HEPA filter. Avoid dust formation. Place all material into loosely covered plastic containers for later disposal. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewer, basements or confined areas.
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. Inform appropriate managerial or supervisory personnel of all environmental releases.
7. Handling and storage
Precautions for safe handling
Material name: Super White™ Multi-Purpose Lithium Grease
SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015
Avoid contact with eyes, skin, and clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Use care in handling/storage. For product usage instructions, please see the product label.
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Conditions for safe storage,
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
workplace.
including any incompatibilities
Keep container tightly closed. Store away from incompatible materials (see Section 10 of the SDS). Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place.
8. Exposure controls/personal protection
Occupational exposure limits
hydrotreated heavy naphthenic (CAS 64742-52-5)
13463-67-7)
hydrotreated heavy naphthenic (CAS 64742-52-5)
13463-67-7)
Type
ValueComponents
Form
PEL 5 mg/m3 Mist.Distillates (petroleum),
2000 mg/m3 500 ppm
PEL 15 mg/m3 Total dust.Titanium dioxide (CAS
PEL 5 mg/m3 Respirable fraction.Zinc oxide (CAS 1314-13-2)
5 mg/m3 Fume. 15 mg/m3 Total dust.
Type
ValueComponents
Form
TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),
TWA 10 mg/m3Titanium dioxide (CAS
STEL 10 mg/m3 Respirable fraction.Zinc oxide (CAS 1314-13-2) TWA 2 mg/m3 Respirable fraction.
Type
ValueComponents
Form
Ceiling 1800 mg/m3Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5)
STEL 10 mg/m3 Mist.
TWA 5 mg/m3 Mist.
Ceiling 15 mg/m3 Dust.Zinc oxide (CAS 1314-13-2)
STEL 10 mg/m3 Fume.
TWA 5 mg/m3 Dust.
Biological limit values
Appropriate engineering controls
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Neoprene.
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.
Thermal hazards
General hygiene considerations
Wear appropriate thermal protective clothing, when necessary.
Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the
5 mg/m3 Fume.
Material name: Super White™ Multi-Purpose Lithium Grease
SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015
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9. Physical and chemical properties
Ingestion
Inhalation
Skin contact
Eye contact
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Other information
Pour point
Solid.
Grease.
White.
Petroleum.
Not available.
Not available.
Not available.
680 °F (360 °C) estimated
475 °F (246.1 °C) Cleveland Open Cup
Very slow.
Not available.
Not available.
Not available.
1066.6 hPa estimated
> 5 (air = 1)
0.9
Insoluble.
Not available.
500 °F (260 °C) estimated
Not available.
145 - 185 cSt (104 °F (40 °C))
Not available.
0 °F (-17.8 °C)
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials.
Strong oxidizing agents.
Carbon oxides. Metal oxides.
11. Toxicological information
Information on likely routes of exposure
Expected to be a low ingestion hazard.
Health injuries are not known or expected under normal use.
May cause an allergic skin reaction.
Direct contact with eyes may cause temporary irritation.
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
Material name: Super White™ Multi-Purpose Lithium Grease
SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015
Rash. Irritation of eyes and mucous membranes. Skin irritation. May cause an allergic skin reaction. Dermatitis.
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Acute toxicity
May cause an allergic skin reaction.
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Chronic effects
Acute
Acute
Acute
Super White™ Multi-Purpose Lithium Grease
Acute
Dermal
LD50 Rabbit
Oral
LD50 Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Prolonged skin contact may cause temporary irritation.
Direct contact with eyes may cause temporary irritation.
irritation
Not available.
Skin sensitization
Germ cell mutagenicity
May cause an allergic skin reaction.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
Not likely, due to the form of the product.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Not likely, due to the form of the product.
Prolonged exposure may cause chronic effects.
Test ResultsProduct Species
> 2000 mg/kg
> 5000 mg/kg
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
Super White™ Multi-Purpose Lithium Grease
Aquatic
Components Test ResultsSpecies
Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5)
Aquatic
Titanium dioxide (CAS 13463-67-7)
Chronic
Aquatic
Harmful to aquatic life with long lasting effects.
EC50Crustacea 3.3075 mg/l, 48 hours estimatedDaphnia
LC50Fish 37.1245 ppm, 96 hours estimatedFish
EC50Crustacea 1000 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 5000 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
EC50Other 5.83 mg/l, 72 hoursPseudokirchnerella subcapitata
NOECOther 0.984 mg/l, 72 hoursPseudokirchnerella subcapitata
Material name: Super White™ Multi-Purpose Lithium Grease
SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015
LC50Crustacea 3 mg/l, 48 hoursCeriodaphnia dubia
5.5 ppm, 48 hoursWater flea (Daphnia magna)
LC50Fish 1000 mg/l, 96 hoursFathead minnow (Pimephales promelas)
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Components Test ResultsSpecies
Acute
Bioconcentration factor (BCF)
Zinc oxide (CAS 1314-13-2)
Aquatic
EC50Crustacea 0.098 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 1.1 ppm, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
Titanium dioxide 352
Mobility in soil
Other adverse effects
Not readily biodegradable.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from residues / unused products
Hazardous waste code
Contaminated packaging
This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 – 261.33). Empty containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations.
Not regulated.
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Zinc oxide (CAS 1314-13-2)
CERCLA Hazardous Substance List (40 CFR 302.4)
Zinc oxide (CAS 1314-13-2)
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.
Material name: Super White™ Multi-Purpose Lithium Grease
SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015
SDS US
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Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
Food and Drug
Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312 Hazard categories
Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No
SARA 302 Extremely
No
hazardous substance
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
Titanium dioxide (CAS 13463-67-7) Zinc oxide (CAS 1314-13-2)
US. Massachusetts RTK - Substance List
Titanium dioxide (CAS 13463-67-7) Zinc oxide (CAS 1314-13-2)
US. Pennsylvania Worker and Community Right-to-Know Law
Zinc oxide (CAS 1314-13-2) Titanium dioxide (CAS 13463-67-7)
US. Rhode Island RTK
Zinc oxide (CAS 1314-13-2)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
100 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
VOC content (CA)
VOC content (OTC)
Not regulated
< 0.1 %
< 0.1 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
Material name: Super White™ Multi-Purpose Lithium Grease
SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015
SDS US
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Country(s) or region Inventory name On inventory (yes/no)*
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
NFPA ratings
01-19-2015
Allison Cho
01
Not available.
Health: 1 Flammability: 1 Physical hazard: 0 Personal protection: B
Health: 1 Flammability: 1 Instability: 0
1
01
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
Disclaimer
CRC cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
Material name: Super White™ Multi-Purpose Lithium Grease
SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015
SDS US
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