CRC Heavy Duty Degreaser DATA SHEET

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SAFETY DATA SHEET

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1. Identification

Heavy Duty DegreaserProduct identifier

Other means of identification

Product Code

Recommended use

Recommended restrictions

Manufacturer/Importer/Supplier/Distributor information

Manufactured or sold by:

Company name

Address

Telephone

General Information

Technical Assistance

Customer Service

24-Hour Emergency

(CHEMTREC)

Website

No. 03095 (Item# 1003364)

General purpose degreaser

None known.

CRC Industries, Inc.

885 Louis Dr.

Warminster, PA 18974 US

215-674-4300

800-521-3168

800-272-4620

800-424-9300 (US)

703-527-3887 (International)

2. Hazard(s) identification

Physical hazards

Health hazards

Environmental hazards

OSHA defined hazards

Label elements

Signal word

Hazard statement

Precautionary statement

Prevention

Compressed gasGases under pressure

Category 2Skin corrosion/irritation

Category 2BSerious eye damage/eye irritation

Category 1BSensitization, skin

Category 1BCarcinogenicity

Category 3 narcotic effectsSpecific target organ toxicity, single exposure

Category 2Hazardous to the aquatic environment, acute

hazard

Category 2Hazardous to the aquatic environment,

long-term hazard

Not classified.

Danger

Contains gas under pressure; may explode if heated. Causes skin irritation. May cause an allergic skin reaction. Causes eye irritation. May cause drowsiness or dizziness. May cause cancer. Toxic to aquatic life with long lasting effects.

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49°C/120°F. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. Avoid release to the environment.

Material name: Heavy Duty Degreaser

No. 03095 (Item# 1003364) Version #: 03 Revision date: 12-19-2017 Issue date: 05-19-2014

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Response

CAS number

Chemical name

Common name and synonyms

Storage

Disposal

Hazard(s) not otherwise classified (HNOC)

Supplemental information

If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. Collect spillage.

Store locked up. Protect from sunlight. Store in a well-ventilated place. Exposure to high temperature may cause can to burst.

Dispose of contents/container in accordance with local/regional/national regulations.

None known.

When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen fluoride, hydrogen chloride, and possibly phosgene.

3. Composition/information on ingredients

Mixtures

perchloroethylene 127-18-4tetrachloroethylene 80 - 90

156-60-5trans-1,2-dichloroethylene 5 - 10

124-38-9carbon dioxide 1 - 3

HFC 43-10mee 138495-42-8decafluoropentane 1 - 3

Specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation

Skin contact

Eye contact

Ingestion

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed

General information

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse.

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately. Do not induce vomiting.

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of eyes. Exposed individuals may experience eye tearing, redness, and discomfort. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.

5. Fire-fighting measures

Suitable extinguishing media

Unsuitable extinguishing media

Specific hazards arising from the chemical

Special protective equipment and precautions for firefighters

Fire fighting equipment/instructions

General fire hazards

Material name: Heavy Duty Degreaser

No. 03095 (Item# 1003364) Version #: 03 Revision date: 12-19-2017 Issue date: 05-19-2014

Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Do not use water jet as an extinguisher, as this will spread the fire.

Pressurized container may rupture when exposed to heat or flame. During fire, gases hazardous to health may be formed. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen fluoride, hydrogen chloride, and possibly phosgene.

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up.

Contents under pressure. Pressurized container may rupture when exposed to heat or flame.

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6. Accidental release measures

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

US. OSHA Table Z-2 (29 CFR 1910.1000)

US. ACGIH Threshold Limit Values

Personal precautions, protective equipment and emergency procedures

Methods and materials for containment and cleaning up

Environmental precautions

Keep unnecessary personnel away. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch or walk through spilled material. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained.

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Put material in suitable, covered, labeled containers.

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, see the product label.

Level 1 Aerosol.

Contents under pressure. Do not expose to heat or store at temperatures above 120°F/49°C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place.

8. Exposure controls/personal protection

Occupational exposure limits

The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits.

ValueComponents Type

PEL 9000 mg/m3carbon dioxide (CAS

124-38-9)

5000 ppm

PEL 790 mg/m3trans-1,2-dichloroethylene

(CAS 156-60-5)

200 ppm

ValueComponents Type

Ceiling 200 ppmtetrachloroethylene (CAS

127-18-4)

TWA 100 ppm

ValueComponents Type

STEL 30000 ppmcarbon dioxide (CAS

124-38-9)

TWA 5000 ppm STEL 100 ppmtetrachloroethylene (CAS

127-18-4)

TWA 25 ppm TWA 200 ppmtrans-1,2-dichloroethylene

(CAS 156-60-5)

Material name: Heavy Duty Degreaser

No. 03095 (Item# 1003364) Version #: 03 Revision date: 12-19-2017 Issue date: 05-19-2014

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US. NIOSH: Pocket Guide to Chemical Hazards

124-38-9)

ACGIH Biological Exposure Indices

wash fountain and emergency showers are recommended.

(CAS 156-60-5)

Biological limit values

ValueComponents Type

STEL 54000 mg/m3carbon dioxide (CAS

30000 ppm

TWA 9000 mg/m3

5000 ppm

TWA 790 mg/m3trans-1,2-dichloroethylene

200 ppm

ValueComponents Determinant Specimen Sampling Time

tetrachloroethylene (CAS 127-18-4)

0.5 mg/l Tetrachloroethy lene

3 ppm Tetrachloroethy

lene

* - For sampling details, please see the source document.

Exposure guidelines

US - Minnesota Haz Subs: Skin designation applies

tetrachloroethylene (CAS 127-18-4) Skin designation applies.

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye

Individual protection measures, such as personal protective equipment

Eye/face protection

Wear safety glasses with side shields (or goggles).

Skin protection

Hand protection

Other

Respiratory protection

Wear protective gloves such as: Polyvinyl alcohol (PVA). Viton/butyl.

Wear appropriate chemical resistant clothing.

If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.

Thermal hazards

General hygiene considerations

Wear appropriate thermal protective clothing, when necessary.

Observe any medical surveillance requirements. When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace.

Blood

End-exhaled air

9. Physical and chemical properties

Appearance

Physical state

Form

Color

Odor

Odor threshold

Melting point/freezing point

Initial boiling point and boiling range

Flash point

Evaporation rate

Flammability (solid, gas)

Material name: Heavy Duty Degreaser

No. 03095 (Item# 1003364) Version #: 03 Revision date: 12-19-2017 Issue date: 05-19-2014

Liquid.

Aerosol.

Colorless.

Solvent.

Not available.

-119.2 °F (-84 °C) estimated

119.7 °F (48.7 °C) estimated

None (Tag Closed Cup)

Fast.

Not available.

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Upper/lower flammability or explosive limits

Skin contact

Eye contact

Acute toxicity

Flammability limit - lower

6.7 % estimated

(%)

Flammability limit - upper

18 % estimated

(%)

Vapor pressure

Vapor density

Relative density

1429.7 hPa estimated

> 4 (air = 1)

1.58

Solubility(ies)

Solubility (water)

Partition coefficient

Slight.

Not available.

(n-octanol/water)

Auto-ignition temperature

Decomposition temperature

Percent volatile

860 °F (460 °C) estimated

Not available.

97.6 % estimated

10. Stability and reactivity

Reactivity

Chemical stability

Possibility of hazardous reactions

Conditions to avoid

Incompatible materials

Hazardous decomposition products

The product is stable and non-reactive under normal conditions of use, storage and transport.

Material is stable under normal conditions.

No dangerous reaction known under conditions of normal use.

Heat, flames and sparks. Contact with incompatible materials. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen fluoride, hydrogen chloride, and possibly phosgene.

Strong oxidizing agents.

Hydrogen chloride. Hydrogen fluoride. Phosgene. Carbon oxides.

11. Toxicological information

Information on likely routes of exposure

Inhalation

Ingestion

Symptoms related to the physical, chemical and toxicological characteristics

Information on toxicological effects

decafluoropentane (CAS 138495-42-8)

Acute

Dermal

LD50 Rabbit > 5000 mg/kg

Inhalation

LC50 Rat 11058 mg/kg, 4 hours calculated

Oral

LD50 Rat > 5000 mg/kg

tetrachloroethylene (CAS 127-18-4)

Acute

Dermal

LD50 Rabbit > 3228 mg/kg

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful.

Causes skin irritation. May cause an allergic skin reaction.

Causes eye irritation.

Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea.

Not known.

Test ResultsComponents Species

Material name: Heavy Duty Degreaser

No. 03095 (Item# 1003364) Version #: 03 Revision date: 12-19-2017 Issue date: 05-19-2014

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Oral

Respiratory sensitization

Carcinogenicity

Aspiration hazard

Chronic effects

Acute

LD50 Rat 2629 mg/kg

trans-1,2-dichloroethylene (CAS 156-60-5)

Acute

Oral

LD50 Rat 1235 mg/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation

Serious eye damage/eye

Causes skin irritation.

Causes eye irritation.

irritation

Respiratory or skin sensitization

Not a respiratory sensitizer.

Skin sensitization

Germ cell mutagenicity

May cause an allergic skin reaction.

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

May cause cancer.

IARC Monographs. Overall Evaluation of Carcinogenicity

tetrachloroethylene (CAS 127-18-4) 2A Probably carcinogenic to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)

Not regulated.

US. National Toxicology Program (NTP) Report on Carcinogens

tetrachloroethylene (CAS 127-18-4) Reasonably Anticipated to be a Human Carcinogen.

Reproductive toxicity

Specific target organ toxicity -

This product is not expected to cause reproductive or developmental effects.

May cause drowsiness and dizziness.

single exposure

Specific target organ toxicity -

Not classified.

repeated exposure

Based on available data, the classification criteria are not met. May be an aspiration hazard.

Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

Test ResultsComponents Species

12. Ecological information

Ecotoxicity

Components Test ResultsSpecies

decafluoropentane (CAS 138495-42-8)

Aquatic

tetrachloroethylene (CAS 127-18-4)

Aquatic

trans-1,2-dichloroethylene (CAS 156-60-5)

Aquatic

* Estimates for product may be based on additional component data not shown.

Persistence and degradability

Bioaccumulative potential

Toxic to aquatic life with long lasting effects.

EC50Crustacea 11.7 mg/l, 48 hoursWater flea (Daphnia magna)

LC50Fish 13 mg/l, 96 hoursZebra danio (Danio rerio)

LC50Fish 4.73 - 5.27 mg/l, 96 hoursRainbow trout,donaldson trout

(Oncorhynchus mykiss)

LC50Fish 120 - 160 mg/l, 96 hoursBluegill (Lepomis macrochirus)

EC50Crustacea 220 mg/l, 48 hoursWater flea (Daphnia magna)

No data is available on the degradability of this product.

No data available.

Material name: Heavy Duty Degreaser

No. 03095 (Item# 1003364) Version #: 03 Revision date: 12-19-2017 Issue date: 05-19-2014

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Partition coefficient n-octanol / water (log Kow)

decafluoropentane 2.7, Pow at 20 °C tetrachloroethylene 2.88 trans-1,2-dichloroethylene 2.06

Mobility in soil

Other adverse effects

No data available.

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions

Hazardous waste code

Contaminated packaging

This material and its container must be disposed of as hazardous waste. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations.

D039: Waste Tetrachloroethylene F001: Waste Halogenated Solvent - Spent Halogenated Solvent Used in Degreasing F002: Waste Halogenated Solvent - Spent Halogenated Solvent

Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. Transport information

DOT

UN number UN proper shipping name Transport hazard class(es)

Class Subsidiary risk

Label(s) Packing group Special precautions for user Packaging exceptions Packaging non bulk Packaging bulk

IATA

UN number UN proper shipping name Transport hazard class(es)

Class

Subsidiary risk Packing group ERG Code Special precautions for user Other information

Passenger and cargo

aircraft

Cargo aircraft only

IMDG

UN number UN proper shipping name Transport hazard class(es)

Class

Subsidiary risk Packing group Environmental hazards

Marine pollutant EmS Special precautions for user

UN1950 Aerosols, poison, Limited Quantity

2.2

6.1(PGIII)

2.2, 6.1 Not applicable. Read safety instructions, SDS and emergency procedures before handling. 306 None None

UN1950 Aerosols, non-flammable, containing substances in Division 6.1, Packing Group III

2.2

6.1 Not applicable. 2P Read safety instructions, SDS and emergency procedures before handling.

Allowed with restrictions.

UN1950 AEROSOLS

6.1 Not applicable.

No. Not available. Read safety instructions, SDS and emergency procedures before handling.

Material name: Heavy Duty Degreaser

No. 03095 (Item# 1003364) Version #: 03 Revision date: 12-19-2017 Issue date: 05-19-2014

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15. Regulatory information

US federal regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

decafluoropentane (CAS 138495-42-8) 1.0 % One-Time Export Notification only.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)

Not regulated.

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance

tetrachloroethylene (CAS 127-18-4)

CERCLA Hazardous Substance List (40 CFR 302.4)

tetrachloroethylene (CAS 127-18-4) Listed.

trans-1,2-dichloroethylene (CAS 156-60-5) Listed.

CERCLA Hazardous Substances: Reportable quantity

tetrachloroethylene (CAS 127-18-4) 100 LBS

trans-1,2-dichloroethylene (CAS 156-60-5) 1000 LBS

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National

Response Center (800-424-8802) and to your Local Emergency Planning Committee.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

tetrachloroethylene (CAS 127-18-4)

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Safe Drinking Water Act (SDWA)

Food and Drug Administration (FDA)

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Classified hazard

CRC Heavy Duty Degreaser DATA SHEET

Specifications and Main Features

Frequently Asked Questions

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